公开(公告)号：DE2909929A1

公开(公告)日：1980-09-25

申请号：DE2909929

申请日：1979-03-14

Applicant: BASF AG

Inventor： MAROSI LASZLO DIPL CHEM DR ,  STABENOW JOACHIM DIPL PHYS DR ,  SCHWARZMANN MATTHIAS DIPL CHEM

IPC: B01J29/06 ,  B01J29/40 ,  B01J29/86 ,  C01B39/40 ,  C07C1/20 ,  C01B33/26 ,  B01J29/04

公开(公告)号：DE2831611A1

公开(公告)日：1980-02-07

申请号：DE2831611

申请日：1978-07-19

Applicant: BASF AG

Inventor： MAROSI LASZLO DIPL CHEM DR ,  STABENOW JOACHIM DIPL PHYS DR ,  SCHWARZMANN MATTHIAS DIPL CHEM

IPC: C01B39/08 ,  C01B33/20 ,  B01D53/02 ,  B01J1/22 ,  B01J23/74

公开(公告)号：DE2602416A1

公开(公告)日：1977-07-28

申请号：DE2602416

申请日：1976-01-23

Applicant: BASF AG

Inventor： STABENOW JOACHIM DIPL PHYS DR ,  MAROSI LASZLO DIPL CHEM DR ,  SCHWARZMANN MATTHIAS ,  SIEBERT GERHARD DIPL CHEM DR ,  SCHLIMPER HANS-ULRICH DIPL CHE

IPC: C01F7/56 ,  C04B35/63 ,  C04B35/18

Abstract: Zeolite mouldings contg. basic Al chloride binders are produced by mixing zeolite powder with binder, kneading moulding mixt. opt. with addn. of water, and calcining at =500 degrees C. Zeolite powder used is capable of flowing and contains 40-70 wt.% water. Basic Al chloride is prepd. by treating aq. solns. contg. Al and Cl ions with solns. of amines having mol.wt. 250-500 in a water-immiscible organic solvent. The aq. and organic phase are then sepd. from one another. The basic Al chloride is recovered from sepd. aq phase by a standard method, provided that the aq. soln. contains max. 25g/l Al and the organic phase contains max. 0.35 mol/l amine. Amorphous basic Al chloride used in an excellent binder for zeolite moulding prodn. Mouldings obtd. have good absorption and catalytic properties.

公开(公告)号：DE2435716A1

公开(公告)日：1976-02-05

申请号：DE2435716

申请日：1974-07-25

Applicant: BASF AG

Inventor： STABENOW JOACHIM DIPL PHYS DR ,  MARVSI LASZLO DIPL CHEM DR ,  SCHWARZMANN MATTHIAS DIPL CHEM

IPC: B01J20/18 ,  B01J29/08 ,  C01B33/113 ,  C01B33/28

公开(公告)号：DE3209223A1

公开(公告)日：1983-09-15

申请号：DE3209223

申请日：1982-03-13

Applicant: BASF AG

Inventor： LEHNERT RUDI DIPL CHEM DR ,  MAROSI LASZLO DIPL CHEM DR ,  LEUTNER BERND DIPL CHEM DR ,  SCHLIMPER HANS-ULRICH DIPL CHE ,  SCHWARZMANN MATTHIAS DIPL CHEM ,  STABENOW JOACHIM DIPL PHYS DR

IPC: C07C1/20 ,  C07C11/02 ,  C07C1/24 ,  C07C11/04 ,  C07C11/06

公开(公告)号：DE2831631A1

公开(公告)日：1980-02-07

申请号：DE2831631

申请日：1978-07-19

Applicant: BASF AG

Inventor： MAROSI LASZLO DIPL CHEM DR ,  STABENOW JOACHIM DIPL PHYS DR ,  SCHWARZMANN MATTHIAS DIPL CHEM

IPC: B01J29/04 ,  C01B39/08 ,  C01B39/50 ,  C01B33/20 ,  B01D53/02 ,  B01J1/22

Abstract: V Silicate with zeolite structure is prepd. by crystallisation from a mixt. of water glass and an aq. soln. of amine at 100-200 degrees C under soln. pressure and in the presence of V oxide and/or V oxide cpd., pref. V chloride. The zeolite is prepd. using a mixt. of water glass (8wt.% Na2O, 25-30wt.% SiO2, small amt. of Al2O3) and V chloride in an aq. soln. contg. 5-50wt.% (10-25wt.%) hexamethylenediamine. The mixt. is heated for 1-5 days respectively, 2-4 days at 140-160 degrees C under soln. pressure. The resultant zeolite has a structure of ZSM-5 type and contains only a small amt. of Al. Its V oxide content is 0.5-3wt.%. Crystalline V silicate has a ZSM-5 type zeolite structure and is suitable as catalyst, after activation, in cracking and hydrocracking processes, and in the conversion of methanol to unsatd. hydrocarbon.

公开(公告)号：DE2510700A1

公开(公告)日：1976-09-23

申请号：DE2510700

申请日：1975-03-12

Applicant: BASF AG

Inventor： STABENOW JOACHIM DIPL PHYS DR ,  MAROSI LASZLO DIPL CHEM DR ,  SCHWARZMANN MATTHIAS DIPL CHEM

IPC: B01J20/18 ,  C01B37/02 ,  C01B33/28

公开(公告)号：DE2451217A1

公开(公告)日：1976-05-13

申请号：DE2451217

申请日：1974-10-29

Applicant: BASF AG

Inventor： STABENOW JOACHIM DIPL PHYS DR ,  WUNSCH GERD DIPL CHEM DR ,  DEIGNER PAUL DR ,  MUELLER FRANZ-JOSEF DIPL CHEM ,  LOESER WERNER DIPL ING DR ,  STECK WERNER DIPL CHEM DR

IPC: C07F15/00 ,  C23C18/30 ,  C23C17/02 ,  C23C3/02

Abstract: A process for metallizing substrates by activation of the substrate by deposition of palladium from a palladium complex, followed by electroless metallization. The palladium is deposited on the substrate by dipping the substrate into a solution of a palladium(O) complex and decomposing this complex at from 100 DEG to 300 DEG C.

公开(公告)号：DE3037415A1

公开(公告)日：1982-05-27

申请号：DE3037415

申请日：1980-10-03

Applicant: BASF AG

Inventor： MAROSI LASZLO DIPL CHEM DR ,  SCHWARZMANN MATTHIAS DIPL CHEM ,  STABENOW JOACHIM DIPL PHYS DR

IPC: C01B37/00 ,  C01B33/26 ,  B01J29/06

公开(公告)号：DE3021580A1

公开(公告)日：1981-12-24

申请号：DE3021580

申请日：1980-06-07

Applicant: BASF AG

Inventor： MAROSI LASZLO DIPL CHEM DR ,  SCHLIMPER HANS-ULRICH DIPL CHE ,  SCHWARZMANN MATTHIAS DIPL CHEM ,  STABENOW JOACHIM DIPL PHYS DR

IPC: B01J29/04 ,  B01J29/40 ,  C01B39/40 ,  C07C1/20 ,  C01B33/26 ,  B01J29/08

Abstract: A process for the preparation of zeolites of the ZSM-5 structural type from a mixture of SiO2 and Al(OH)3 by hydrothermal crystallization in an aqueous amine solution, in the absence of alkali, at from 100 DEG to 200 DEG C., wherein the crystallization is carried out in the presence of a triamine, tetraamine and/or higher amine and the reaction mixture is formulated to have an SiO2/Al2O3 molar ratio defined by an equation which involves the chain length and number of amine groups of the amine employed, as well as to have certain molar ratios of H2O/amine and amine/Al2O3, and the use of these zeolites as catalysts for the conversion of alcohols and/or dialkyl ethers to olefins and/or aromatics.