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    PROCESS FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL
    23.
    发明专利
    PROCESS FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL 未知

    公开(公告)号：CA2198937A1

    公开(公告)日：1996-03-14

    申请号：CA2198937

    申请日：1995-08-24

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: C07C27/00 ,  C07B61/00 ,  C07C29/00 ,  C07C29/09 ,  C07C29/17 ,  C07C31/12 ,  C07C45/51 ,  C07C45/56 ,  C07C47/02 ,  C07D295/023 ,  C07C31/125

    Abstract: The proposed process for producing n-butyraldehyde and/or n-butanol involves the following steps: (a) 1,3-butadiene is allowed to react with an amine of formula (I) R1R2NH, in which the groups independently of one another represent hydrogen, optionally substituted aliphatic or cyclo-aliphatic groups, or aryl or aralkyl groups, or are connected to a bridging unit which can contain heteroatoms, at high temperature and pressure and in the presence of a compound of a group VIIIb element, in the presence of an alkali metal amide, or in the presence of a basic metal oxide, to form a mixture of addition compounds of formula (II) and (III); (b) addition compound (III) is isomerised to addition compound (II); (c) addition compound (II) is isomerised in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase or in the presence of a heterogeneous catalyst containing transition metal in the gas phase to produce enamine of formula (IV); and (d) the enamine (IV) is converted, by reaction with hydrogen and water, or water, in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase, in the presence of a heterogenous catalyst containing transition metal in the gas phase, in the presence of an acid or in the presence of one of the above mentioned catalysts and of an acid, to n-butyraldehyde and/or n-butanol, the amine (I) being released and the released amine (I) being led back into sub-reaction (a).

    PREPARACION DE UN CATALIZADOR PARA HIDROGENACION.
    28.
    发明专利
    PREPARACION DE UN CATALIZADOR PARA HIDROGENACION. 未知

    公开(公告)号：MX9802151A

    公开(公告)日：1998-08-30

    申请号：MX9802151

    申请日：1998-03-19

    Applicant: BASF AG

    Inventor： HEINEKE DANIEL ,  RIEKER CHRISTOPHER WILLIAM ,  OOSTVOGELS JOZEF ,  POSTELMANS DANY ,  SCHNEIDER HEINZ-WALTER ,  THOME ALFRED ,  ACHHAMMER GUENTHER

    IPC: B01J23/42 ,  B01J23/96 ,  B01J37/16 ,  B01J38/48 ,  C01B21/14

    Abstract: La presente invencion se refiere a la preparacion de un catalizador de hidrogenacion reduciendo platino en el estado de oxidacion +4 (PL (IV)), con un agente reductor selectivo en un medio acuoso ácido en presencia de un portador que contenga carbono, a platino en el estado de oxidacion +2 (PL (II)), después el envenenamiento del platino resultante con un agente reductor selectivo que contenga azufre y luego reduciendo el platino parcialmente envenenado en esta forma a platino metálico (PL (O)) y después el tratamiento en una forma conocida per se, en donde (a) el (PL (II)) es parcialmente envenenado con un agente reductor selectivo que contiene azufre, el agente reductor se utiliza en una cantidad que corresponde a 15-70% mol de la cantidad de un agente reductor selectivo que contiene azufre, que sería necesario para reducir Pt (IV)) a Pt (II), siempre y cuando la cantidad de Pt (IV) corresponda a la cantidad de Pt (II) utilizado y que se va a envenenar, y el Pt (II) parcialmente envenenado entonces se reduce con un formato de metal alcalino en Pt (0), o (b) El platino en un estado de oxidacion superior a +2 es parcialmente envenenado y se reduce posteriormente o en forma simultánea por medio de un formato de metal alcalino a Pt (0), y el catalizador de hidrogenacion, el uso del catalizador de hidrogenacion para la preparacion de sales de hidroxilamonio, los procesos para la preparacion de las sales de hidroxilamonio y un proceso para regenerar los catalizadores de hidrogenacion que contienen platino.

    29.
    发明专利
    未知

    公开(公告)号：BR9508689A

    公开(公告)日：1997-12-30

    申请号：BR9508689

    申请日：1995-08-24

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: C07C27/00 ,  C07B61/00 ,  C07C29/00 ,  C07C29/09 ,  C07C29/17 ,  C07C31/12 ,  C07C45/51 ,  C07C45/56 ,  C07C47/02 ,  C07D295/023

    Abstract: PCT No. PCT/EP95/03358 Sec. 371 Date Jul. 23, 1997 Sec. 102(e) Date Jul. 23, 1997 PCT Filed Aug. 24, 1995 PCT Pub. No. WO96/07630 PCT Pub. Date Mar. 14, 1996A process for the preparation of n-butyraldehyde and/or n-butanol, in which a) 1,3-butadiene is caused to react with an amine of the formula I R1R2NH, I in which R1 and R2 independently denote hydrogen, optionally substituted aliphatic or cycloaliphatic radicals, or aryl or aralkyl radicals or are linked to form a bridging member which can contain hetero atoms, at elevated temperature and under superatmospheric pressure in the presence of a compound of a Group VIIIb element and in the presence of an alkali metal amide or a basic metal oxide to form a mixture of the adducts of the formulas II II and III III b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous catalyst containing a transition metal element in the gaseous phase to form the enamine of the formula IV IV and d) n-butyraldehyde and/or n-butanol is/are produced from this enamine.

    30.
    发明专利
    未知

    公开(公告)号：DE4431528A1

    公开(公告)日：1996-03-07

    申请号：DE4431528

    申请日：1994-09-03

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: C07C27/00 ,  C07B61/00 ,  C07C29/00 ,  C07C29/09 ,  C07C29/17 ,  C07C31/12 ,  C07C45/51 ,  C07C45/56 ,  C07C47/02 ,  C07D295/023 ,  C07C45/00 ,  C07D295/03

    Abstract: The proposed process for producing n-butyraldehyde and/or n-butanol involves the following steps: (a) 1,3-butadiene is allowed to react with an amine of formula (I) R R NH, in which the groups independently of one another represent hydrogen, optionally substituted aliphatic or cyclo-aliphatic groups, or aryl or aralkyl groups, or are connected to a bridging unit which can contain heteroatoms, at high temperature and pressure and in the presence of a compound of a group VIIIb element, in the presence of an alkali metal amide, or in the presence of a basic metal oxide, to form a mixture of addition compounds of formula (II) and (III); (b) addition compound (III) is isomerised to addition compound (II); (c) addition compound (II) is isomerised in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase or in the presence of a heterogeneous catalyst containing transition metal in the gas phase to produce enamine of formula (IV); and (d) the enamine (IV) is converted, by reaction with hydrogen and water, or water, in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase, in the presence of a heterogenous catalyst containing transition metal in the gas phase, in the presence of an acid or in the presence of one of the above mentioned catalysts and of an acid, to n-butyraldehyde and/or n-butanol, the amine (I) being released and the released amine (I) being led back into sub-reaction (a).

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