公开(公告)号：WO9837124A3

公开(公告)日：1998-11-19

申请号：PCT/EP9800981

申请日：1998-02-20

Applicant: BASF AG ,  BECKER RAINER ,  ELLER KARSTEN ,  LANGENSIEPEN HANS WERNER ,  HESSE MICHAEL

Inventor： BECKER RAINER ,  ELLER KARSTEN ,  LANGENSIEPEN HANS-WERNER ,  HESSE MICHAEL

IPC: C07C211/51 ,  A61K9/12 ,  B01J21/16 ,  C07B61/00 ,  C07C209/54 ,  C07C209/68 ,  C07C209/78 ,  C07C211/50 ,  C07C211/54 ,  C08G73/00

CPC classification number: C07C209/54 ,  B01J21/16 ,  C07C209/78 ,  C07C211/50 ,  C07C211/54

Abstract: A process is disclosed for preparing aromatic polyamine mixtures which contain compounds of general formula (I) H2N-A-CH2-B-NH2, in which A and B stand for 1,4-phenylene radicals which can independently bear 1 to 4 substituents selected among C1-20-alkyl radicals and halogen atoms. A compound of general formula (IV) H-A-NH-CH2-HN-B-H and/or a compound of general formula (V) H-A-NH-CH2-B-NH2, in which A and B are substituted as above, are reacted at a temperature in a range from 20 °C to 200 °C in the presence of a catalyst which is made of one or several oxides of elements of the 3rd to the 10th group of the periodic table of elements and which can be acid activated.

公开(公告)号：WO0043124A8

公开(公告)日：2000-12-07

申请号：PCT/EP0000432

申请日：2000-01-20

Applicant: BASF AG ,  MENGER VOLKMAR ,  ELLER KARSTEN ,  MEIER ANTON ,  HESSE MICHAEL

Inventor： MENGER VOLKMAR ,  ELLER KARSTEN ,  MEIER ANTON ,  HESSE MICHAEL

IPC: B01J21/20 ,  B01J29/90 ,  B01J38/06 ,  C08G65/20 ,  C08G65/26

CPC classification number: C08G65/20 ,  B01J21/20 ,  B01J29/90 ,  B01J38/06 ,  C08G65/2642 ,  Y02P20/584

Abstract: The invention relates to a method for processing at least partly deactivated polymerization catalysts for the polymerization or copolymerization of THF which are contaminated with the polymerization or copolymerization products of THF. The inventive method comprises the following steps: (a) purifying in a first step the polymerization catalyst by treating it with water vapor at a temperature of 80 to 250 DEG C and a pressure of 0.5 to 40 bar and preferably (b) regenerating the purified polymerization catalyst in a second step.

Abstract translation: 过程用于后处理至少部分失活的聚合催化剂为被污染的THF的聚合或共聚合的产物THF的聚合或共聚中在第一步骤中，通过处理在所述聚合催化剂与蒸汽其中（a） 在温度80〜250℃，0.5〜40巴的压力被纯化，并优选为（b）在第二步骤中，将纯化的聚合催化剂进行再生。

公开(公告)号：WO9815589A3

公开(公告)日：1998-06-25

申请号：PCT/EP9705204

申请日：1997-09-23

Applicant: BASF AG ,  SIGWART CHRISTOPH ,  ELLER KARSTEN ,  BECKER RAINER ,  PLITZKO KLAUS DIETER ,  FISCHER ROLF ,  STEIN FRANK ,  MUELLER ULRICH ,  HESSE MICHAEL

Inventor： SIGWART CHRISTOPH ,  ELLER KARSTEN ,  BECKER RAINER ,  PLITZKO KLAUS-DIETER ,  FISCHER ROLF ,  STEIN FRANK ,  MUELLER ULRICH ,  HESSE MICHAEL

IPC: C08G65/10 ,  C08G18/48 ,  C08G65/20 ,  C08G65/28 ,  B01J23/24

CPC classification number: C08G65/20 ,  C08G18/4854

Abstract: The invention concerns a process for preparing polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butin-1,4-diol, diesters of these polymers with C2-C20 monocarboxylic acids or monoesters of these polymers with C1-C10 monocarboxylic acids by polymerizing tetrahydrofuran in the presence of one of the following telogens, water, 1,-4-butane diol, 2-butin-1,4-diol, polytetrahydrofuran with a molecular weight of between 200 and 700 Dalton, or of a C1-C10 monocarboxylic acid or a carboxylic acid anhydride produced from C2-C20 monocarboxylic acids or mixtures of these telogens on a heterogeneous carrier catalyst which contains a catalytically active amount of an oxygenous molybdenum and/or tungsten compound on an oxidic carrier material, and which has been calcined at temperatures of between 500 °C and 1000 °C after application of the precursor compounds of the oxygenous molybdenum and/or tungsten compounds to the carrier material precursors. Before it is used as a polymerization catalyst, the catalyst is activated by treatment with a reducing agent.

公开(公告)号：DE19860489B4

公开(公告)日：2008-05-08

申请号：DE19860489

申请日：1998-12-28

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  WAHL PETER ,  PINKOS ROLF

IPC: C07C31/20 ,  C07B41/02 ,  C07C29/141

公开(公告)号：CZ296971B6

公开(公告)日：2006-08-16

申请号：CZ297899

申请日：1998-02-20

Applicant: BASF AG

Inventor： BECKER RAINER ,  ELLER KARSTEN ,  LENGENSIEPEN HANS-WERNER ,  HESSE MICHAEL

IPC: C07C209/54 ,  C07C211/51 ,  A61K9/12 ,  B01J21/00 ,  B01J21/16 ,  B01J23/00 ,  B01J27/00 ,  C07B61/00 ,  C07C209/68 ,  C07C209/78 ,  C07C211/50 ,  C07C211/54

Abstract: Pri zpusobu výroby smesí aromatických polyaminu, které obsahují slouceniny obecného vzorce I: H.sub.2.n.N-A-CH.sub.2.n.-B-NH.sub.2.n., kde A a B jsou1,4-fenylenové zbytky, které mohou vzdy nezávislena sobe obsahovat 1 az 4 substituenty vybrané z alkylových zbytku s 1 az 20 uhlíkovými atomy a halogenových atomu, reagují slouceniny obecného vzorceIV: H-A-NH-CH.sub.2.n.-HN-B-H a/nebo slouceniny obecného vzorce V: H-A-NH-CH.sub.2.n.-B-NH.sub.2.n., pricemz A a B jsou substituovány jak je uvedeno výse, pri teplote v rozmezí od 20 do 200 .degree.Cv prítomnosti katalyzátoru, který se vybere z jednoho nebo nekolika oxidu prvku 3. az 10. skupiny periodického systému prvku, které mohou být aktivovány kyselinou.

公开(公告)号：CA2273265C

公开(公告)日：2005-06-21

申请号：CA2273265

申请日：1997-11-18

Applicant: BASF AG

Inventor： HESSE MICHAEL ,  STEIN FRANK ,  MULLER ULRICH ,  PLITZKO KLAUS-DIETER ,  BECKER RAINER ,  SIGWART CHRISTOPH ,  ELLER KARSTEN ,  FISCHER ROLF

IPC: B01J23/24 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26 ,  C08G65/28

Abstract: Polytetrahydrofuran, tetrahydrofuran copolymers, diesters or monoesters of these polymers are prepared by polymerizing tetrahydro- furan in the presence of at least one telogen and/or comonomer on a heterogeneous carrier catalyst which contains on an oxidic carrier material as active mass a catalytically active amount of at least one oxygenous molybdenum and/or tungsten compound and, when the precursor compounds of the active mass have been applied to the carrier material precursor, has been calcined at temperatures of between 500 .degree.C and 1000 .degree.C. The catalyst used contains a promotor whic h comprises at least one element or a compound of an element of the 2nd, 3rd including the lanthanides, 5th, 6th, 7th, 8th or 14th group of the periodic system of elements.

公开(公告)号：ES2224062T3

公开(公告)日：2005-03-01

申请号：ES02722181

申请日：2002-03-06

Applicant: BASF AG

Inventor： WEIGL HAGEN ,  EBEL KLAUS ,  HUBER SYLVIA ,  KUSCHE ANDREAS ,  ELLER KARSTEN ,  HESSE MICHAEL

IPC: B01J23/89 ,  B01J27/045 ,  B01J37/02 ,  B01J37/20 ,  C07B61/00 ,  C07C31/20 ,  C07D307/28 ,  C07D309/18 ,  C07D319/12

Abstract: Procedimiento para la obtención de éteres cíclicos e insaturados de la fórmula general I en la cual Z significa ¿(CHR4)q- o ¿(CHR4)q-O-, q significa 0, 1, 2 o 3, y R1, R2, R3 y R4 significan hidrógeno o alquilo con 1 a 4 átomos de carbono, mediante reacción de dioles de la fórmula general II en la cual tienen Z, R1, R2 y R3 los significados anteriormente indicados, en fase líquida a temperaturas desde 150 hasta 300ºC en presencia de un catalizador soportado, que contiene cobalto y que está dotado de azufre y que no está activado antes de su empleo por reducción, que contiene cobalto y un metal precioso aplicado por impregnación de sol ¿del grupo de platino, paladio, rodio, iridio, rutenio, osmio, renio o sus mezclas ¿ sobre un soporte inerte, caracterizado porque se agrega agua.

公开(公告)号：MY118608A

公开(公告)日：2004-12-31

申请号：MYPI9805594

申请日：1998-12-10

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  RUTTER HEINZ ,  HESSE MICHAEL ,  BECKER RAINER

IPC: C08G59/68 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26

Abstract: IN A PROCESS FOR PREPARING POLYTETRAHYDROFURAN, POLYTETRAHYDROFURAN COPOLYMERS ORDIESTERS OR MONOESTERS THEREOF BY POLYMERIZATION OF TETRAHYDROFURAN IN THE PRESENCE OF AT LEAST ONE TELGEN AND/OR COMONOMER OVER ACID- ACTIVATED MONTMORILLONITE CATALYSTS, THE MONTMORILLONITE CATALYST AFTER ACID ACTIVATION HAS A RATIO OF MONTMORILLONITE STRUCTURE TO THE SUM OF MUSCOVITE AND KAOLIN STRUCTURES, DETERMINED FROM THE INTENSITIES OF THE REFLECTIONS AT 20= 5.5o FOR MONTMORILLONITE, 20=9.0o FOR KAOLIN MEASURED IN THE X-RAY POWDER PATTERN, OF AT LEAST 5:1.

公开(公告)号：DE50003718D1

公开(公告)日：2003-10-23

申请号：DE50003718

申请日：2000-01-20

Applicant: BASF AG

Inventor： MENGER VOLKMAR ,  ELLER KARSTEN ,  MEIER ANTON ,  HESSE MICHAEL

IPC: B01J21/20 ,  B01J29/90 ,  B01J38/06 ,  C08G65/20 ,  C08G65/26

Abstract: A process for working up at least partially deactivated polymerization catalysts for the polymerization or copolymerization of THF which are contaminated with the products of the polymerization or copolymerization of THF comprises(a) in a first step, cleaning the polymerization catalyst by treatment with steam at from 80 to 250° C. and a pressure of from 0.5 to 40 bar and, preferably,(b) in a second step, regenerating the clean polymerization catalyst.

公开(公告)号：AT202374T

公开(公告)日：2001-07-15

申请号：AT98951309

申请日：1998-08-21

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  HESSE MICHAEL ,  BECKER RAINER ,  HOEHN ARTHUR ,  RUETTER HEINZ

IPC: B01J21/16 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26

Abstract: A process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers or diesters or monoesters of these polymers comprises polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer over a heterogeneous catalyst comprising hectorite.