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公开(公告)号:CA2862041C
公开(公告)日:2016-11-15
申请号:CA2862041
申请日:2012-12-28
Applicant: BASF SE
Inventor: BERENS ULRICH , GANZ HOLGER , WINDLIN FRANZ NIKLAUS , AL-AKHDAR WALID
IPC: C07F9/6574
Abstract: The present disclosure relates to methods of purifying organic diphosphites of the general formula (l) (See Formula I) wherein a crude organic diphosphite of the general formula (l) which is at least partly dissolved in a first solvent (L1) selected from among the group consisting of alkylbenzenes, aryl alkyl ethers, chlorobenzene and mixtures thereof is precipitated by admixing with a second solvent (L2) selected from among the group consisting of linear C1-C4-alkanols, ethylene glycol di(C1-C4-alkyl) ethers and mixtures thereof. Also provided are uses a transition metal catalyst comprising at least one organic diphosphite (l) obtained by the aforementioned purification method as ligand for hydroformylation, hydrocyanation or hydrogenation.
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公开(公告)号:ES2589461T3
公开(公告)日:2016-11-14
申请号:ES12810314
申请日:2012-12-28
Applicant: BASF SE , BERENS ULRICH , GANZ HOLGER , WINDLIN FRANZ NIKLAUS , TISHKOV ALEXANDER
Inventor: BERENS ULRICH , GANZ HOLGER , WINDLIN FRANZ NIKLAUS , TISHKOV ALEXANDER
IPC: C07F9/6574
Abstract: Procedimiento para producir 6-clorodibenzo[d,f][1,3,2]dioxafosfepina (I)**Fórmula** en el cual se hace reaccionar 2,2'-dihidroxibifenilo (A1)**Fórmula** con PCl3 en presencia de una cantidad catalítica de una sal ácida de una base nitrogenada, en cuyo caso la sal ácida se deriva de una base nitrogenada que se selecciona entre imidazoles, piridinas, 1H-pirazoles, 4H-pirazoles, 1-pirazolines, 3-pirazolinas, imidazolinas, tiazoles, oxazoles, 1,2,4-triazoles y 1,2,3-triazoles, respectivamente sustituidos o no sustituidos, y la reacción se efectúa en ausencia de solventes orgánicos externos.
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公开(公告)号:MX2014007820A
公开(公告)日:2014-09-25
申请号:MX2014007820
申请日:2012-12-28
Applicant: BASF SE
Inventor: BERENS ULRICH , GANZ HOLGER , WINDLIN FRANZ NIKLAUS , AL-AKHDAR WALID
IPC: C07F9/6574
Abstract: La invención se refiere a un método para purificar compuestos de difosfitos orgánicos.
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公开(公告)号:CA2862143A1
公开(公告)日:2013-07-04
申请号:CA2862143
申请日:2012-12-28
Applicant: BASF SE
Inventor: BERENS ULRICH , GANZ HOLGER , WINDLIN FRANZ NIKLAUS , TISHKOV ALEXANDER
IPC: C07F9/6574
Abstract: The present invention relates to a method for producing 6-chlorodibenzo [d,f] [1,3,2]dioxaphosphepin (I) in which 2,2'-dihydroxybiphenyl is reacted with PCl3 in the presence of a catalytic quantity of an acid salt of a nitrogenous base, the reaction taking place in the absence of external organic solvents.
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公开(公告)号:CA2862100A1
公开(公告)日:2013-07-04
申请号:CA2862100
申请日:2012-12-28
Applicant: BASF SE
Inventor: BERENS ULRICH , GANZ HOLGER , CHIODO TIZIANA
IPC: C07F9/141
Abstract: The present invention relates to a crystalline non-solvated form of 6,6'-[[3,3',5,5'-tetrakis(1,1-dimethylethyl)-[1,1'-biphenyl]-2,2'-diyl]bis(oxy)]bis-dibenzo [d,f] [1,3,2]-dioxaphosphepine (compound I) and toluene-solvates and acetone-solvates thereof.
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公开(公告)号:AT482477T
公开(公告)日:2010-10-15
申请号:AT06754974
申请日:2006-05-03
Applicant: BASF SE
Inventor: BIENEWALD FRANK , SCHMIDHALTER BEAT , BERENS ULRICH , KIRNER HANS
IPC: H01L51/00
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