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公开(公告)号:AT461176T
公开(公告)日:2010-04-15
申请号:AT01945152
申请日:2001-05-17
Applicant: BASF SE
Inventor: HAFNER ANDREAS , KIRNER HANS , SCHWARZENBACH FRANZ , VAN DER SCHAAF PAUL , NESVADBA PETER
IPC: C07D211/94 , B01J27/122 , C07B61/00 , C07D209/44 , C07D217/26 , C07D241/08 , C07D401/12 , C07D401/14 , C07D405/12 , C08F4/00 , C08K5/3412 , C08K5/3435 , C08L101/00 , C09K15/30 , C09K21/10
Abstract: An amine ether of formula A wherein a is 1 or 2; and when a is 1, E is E'; when a is 2, E is L; E' is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E' is a radical of formula (VII) as explained in claim 1; T' is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)-R 22 ; or T' is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or -NR 18 -; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or -NR 18 -; or T' is -C(G 1 )(G 2 )-T''; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by T'' is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T'' and T' together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.
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公开(公告)号:AT482477T
公开(公告)日:2010-10-15
申请号:AT06754974
申请日:2006-05-03
Applicant: BASF SE
Inventor: BIENEWALD FRANK , SCHMIDHALTER BEAT , BERENS ULRICH , KIRNER HANS
IPC: H01L51/00
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公开(公告)号:AT457972T
公开(公告)日:2010-03-15
申请号:AT02764615
申请日:2002-07-02
Applicant: BASF SE
Inventor: OEHRLEIN REINHOLD , BAISCH GABRIELE , KIRNER HANS , BIENEWALD FRANK , BURKHARDT STEPHAN , STUDER MARTIN
IPC: C07C67/307 , C07C227/32 , C07B53/00 , C07B61/00 , C07C67/31 , C07C69/67 , C07C69/675 , C07C69/708 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/06 , C07C227/16 , C07C229/22 , C07C231/02 , C07C235/04 , C07C235/06 , C07C235/74 , C07C247/12 , C07D207/34 , C12P7/62
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