公开(公告)号：EP2373623B1

公开(公告)日：2017-03-29

申请号：EP09764529.5

申请日：2009-12-07

Applicant: BASF SE

Inventor： CORTES, David

IPC: C07D213/80

CPC classification number: C07D213/80

公开(公告)号：EP3077353A1

公开(公告)日：2016-10-12

申请号：EP14805905.8

申请日：2014-12-01

Applicant: BASF SE

Inventor： KLAUBER, Eric George ,  RACK, Michael ,  ZIERKE, Thomas ,  WLOCH, Sebastian ,  HOLUB, Nicole ,  DUDENHOEFFER, Stefan ,  SCHMELEBECK, Gerald ,  JI, Junmin ,  CORTES, David

IPC: C07C37/74 ,  C07C37/84 ,  C07C39/30

CPC classification number: C07C37/74 ,  C07C37/84 ,  C07C39/30

Abstract: A process for purifying 2,5-dichlorophenol, the process comprising the steps of distillation and subsequent crystallization.

Abstract translation: 纯化2,5-二氯苯酚的方法，该方法包括蒸馏和随后结晶的步骤。

公开(公告)号：EP3052463B1

公开(公告)日：2017-03-01

申请号：EP14784411.2

申请日：2014-09-25

Applicant: BASF SE

Inventor： SCHMELEBECK, Gerald ,  JI, Junmin ,  KLAUBER, Eric George ,  RACK, Michael ,  ZIERKE, Thomas ,  HOLUB, Nicole ,  CORTES, David

IPC: C07C37/02

CPC classification number: C07C51/09 ,  A01N37/40 ,  C07C37/02 ,  C07C51/15 ,  C07C51/367 ,  C07C67/00 ,  C07F1/005 ,  C07C39/30 ,  C07C65/05 ,  C07C65/21

公开(公告)号：EP2376472B1

公开(公告)日：2015-08-19

申请号：EP09764528.7

申请日：2009-12-07

Applicant: BASF SE

Inventor： RACK, Michael ,  GEBHARDT, Joachim ,  MENGES, Frederik ,  KEIL, Michael ,  KLIMA, Rodney F. ,  CORTES, David ,  LEICHT, Robert ,  ZECH, Helmut ,  SCHRÖDER, Jochen

IPC: C07D401/04 ,  C07D213/80

CPC classification number: C07D213/80

公开(公告)号：EP2376472A1

公开(公告)日：2011-10-19

申请号：EP09764528.7

申请日：2009-12-07

Applicant: BASF SE

Inventor： RACK, Michael ,  GEBHARDT, Joachim ,  MENGES, Frederik ,  KEIL, Michael ,  KLIMA, Rodney F. ,  CORTES, David ,  LEICHT, Robert ,  ZECH, Helmut ,  SCHRÖDER, Jochen

IPC: C07D401/04 ,  C07D213/80

CPC classification number: C07D213/80

Abstract: A process for manufacturing a 5-formyl-pyridine-2,3-dicarboxylic acid ester (I) wherein Z is hydrogen or halogen; Z
1 is hydrogen, halogen, cyano or nitro and R
1 , R
2 are independently C
1 -C
10 -alkyl, comprising the steps of (i) reacting a compound of formula (II), wherein the symbols are as in formula (I), with a nitrosation agent (III) R
3 -O-N=O (III) wherein R
3 is C
1 -C
8 -alkyl, in the presence of an alkali metal or alkaline earth metal alcoholates or carbonates in a polar aprotic solvent at a temperature of from -45 to 40°C, to obtain an oxime compound (IV) where Z, Z
1 , R
1 and R
2 are as in formula (I), and (ii) reacting oxime compound (IV) with an aliphatic C
1 -C
10 -aldehyde in the presence of a Lewis acid at a temperature in the range of from 0 to 100°C. The compounds of formula (I) are useful intermediates in the synthesis of herbicidal imidazolinones, like imazamox.

公开(公告)号：EP2370410A1

公开(公告)日：2011-10-05

申请号：EP09745045.6

申请日：2009-11-03

Applicant: BASF SE

Inventor： MENGES, Frederik ,  GEBHARDT, Joachim ,  RACK, Michael ,  KEIL, Michael ,  KLIMA, Rodney F. ,  CORTES, David ,  LEICHT, Robert ,  ZECH, Helmut ,  SCHRÖDER, Jochen

IPC: C07D213/81 ,  C07D401/04

CPC classification number: C07D401/04 ,  C07D213/81

Abstract: 2-[(1-cyanopropyl)carbamoyl]-5-chloromethyl nicotinic acids of formula (I) where Z is hydrogen or halogen; Z
1 is hydrogen, halogen, cyano or nitro; R
1 is C
1 -C
4 alkyl; R
2 is C
1 -C
4 alkyl, C
3 -C
6 cycloalkyl or R
1 and R
2 , when taken together with the atom to which they are attached, represent a C
3 -C
6 cycloalkyl group optionally substituted with methyl, and R
3 is hydrogen or a cation preferably selected from the group consisting of alkali metals, alkaline earth metals, manganese, copper, iron, zinc, cobalt, lead, silver, nickel, ammonium and organic ammonium; are useful intermediates for the synthesis of herbicidal imidazolinones.