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公开(公告)号：WO2015049360A1
公开(公告)日：2015-04-09
申请号：PCT/EP2014/071210
申请日：2014-10-02
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , CORTES, David , SCHMELEBECK, Gerald , JI, Junmin
CPC classification number: C07C51/377 , C07C37/02 , C07C41/16 , C07C67/297 , C07F1/005 , C07F1/04 , C07C39/30 , C07C43/225
Abstract: The present invention relates to a process for providing a compound of formula (I):, wherein R is hydrogen or R', wherein R' is –(C 1 -C 4 )alkyl, and Hal is a halogen, the process comprising the step of: reacting a compound of formula (II) wherein Hal is defined as above, with an alkali metal alkoxide of the formula XOR', wherein X is an alkali metal, and R' is defined as above.
Abstract translation: 本发明涉及提供式（I）化合物的方法：其中R是氢或R'，其中R'是 - （C 1 -C 4）烷基，而Hal是卤素，该方法包括以下步骤： ：将其中Hal如上定义的式（II）化合物与式XOR'的碱金属醇盐反应，其中X为碱金属，R'如上定义。
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公开(公告)号：WO2015082415A1
公开(公告)日：2015-06-11
申请号：PCT/EP2014/076140
申请日：2014-12-01
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , WLOCH, Sebastian , HOLUB, Nicole , DUDENHOEFFER, Stefan , SCHMELEBECK, Gerald , JI, Junmin , CORTES, David
Abstract: A process for purifying 2,5-dichlorophenol, the process comprising the steps of distillation and subsequent crystallization.
Abstract translation: 一种纯化2,5-二氯苯酚的方法，该方法包括蒸馏和随后结晶的步骤。
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公开(公告)号：WO2015124651A1
公开(公告)日：2015-08-27
申请号：PCT/EP2015/053453
申请日：2015-02-19
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , SCHMELEBECK, Gerald , JI, Junmin , CORTES, David
CPC classification number: C07C41/16 , C07C37/02 , C07C37/62 , C07C51/16 , C07C51/285 , C07C65/21 , C07C43/225 , C07C39/30 , C07C39/28
Abstract: The present invention relates to a process for providing a compound of formula (IV):wherein R 1 and R 2 are each independently C 1 -C 4 alkyl, and Hal is independently Cl or Br, the process comprising the steps of: (i) reacting a compound of formula (II) wherein R 1 and Hal is defined as above, to obtain a compound of formula (III) wherein R 1 and Hal is defined as above, and (ii) reacting the compound of formula (III) to obtain the compound of formula (IV).
Abstract translation: 本发明涉及一种提供式（Ⅳ）化合物的方法：其中R 1和R 2各自独立地为C 1 -C 4烷基，Hal独立地为Cl或Br，该方法包括以下步骤：（ⅰ）使化合物 其中R 1和Hal定义如上，得到其中R 1和Hal如上定义的式（III）化合物，和（ⅱ）使式（Ⅳ）化合物与式（Ⅳ）化合物反应得到式 （IV）。
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公开(公告)号：WO2015049160A1
公开(公告)日：2015-04-09
申请号：PCT/EP2014/070509
申请日：2014-09-25
Applicant: BASF SE
Inventor： SCHMELEBECK, Gerald , JI, Junmin , KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , CORTES, David
IPC: C07C37/02
CPC classification number: C07C51/09 , A01N37/40 , C07C37/02 , C07C51/15 , C07C51/367 , C07C67/00 , C07F1/005 , C07C39/30 , C07C65/05 , C07C65/21
Abstract: The present invention relates to a process for providing a compound of formula (I): wherein Hal is a halogen, the process comprising the step of: reacting a compound of formula (II) wherein Hal is defined as above, with an alkali metal sulfite of the formula X 2 SO 3 and an alkali metal hydroxide of the formula YOH, wherein X and Y are independently selected from an alkali metal.
Abstract translation: 本发明涉及提供式（I）化合物的方法：其中Hal是卤素，该方法包括以下步骤：使其中Hal如上定义的式（II）化合物与碱金属亚硫酸盐反应 的式X 2 SO 3和式YOH的碱金属氢氧化物，其中X和Y独立地选自碱金属。
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5.发明申请
公开(公告)号：WO2015086698A1
公开(公告)日：2015-06-18
申请号：PCT/EP2014/077266
申请日：2014-12-10
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , CORTES, David , SCHMELEBECK, Gerald , JI, Junmin
IPC: C07C45/64 , C07C49/825 , C07C51/367 , C07C65/05 , C07C67/31 , C07C69/84 , C07C253/30 , C07C255/54
CPC classification number: C07C51/367 , C07C45/64 , C07C51/08 , C07C67/31 , C07C253/30 , C07C255/54 , C07C65/05 , C07C69/84 , C07C49/825
Abstract: The present invention relates to a process for providing dihalogen substituted salicylic acid derivativesof formula (II).
Abstract translation: 本发明涉及提供式（II）的二卤代替水杨酸衍生物的方法。
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Patent Agency Ranking
公开(公告)号：WO2015082422A2
公开(公告)日：2015-06-11
申请号：PCT/EP2014/076149
申请日：2014-12-01
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , SCHMELEBECK, Gerald , JI, Junmin , CORTES, David
IPC: C07C67/11
CPC classification number: C07C67/42 , C07C37/0555 , C07C45/46 , C07C51/02 , C07C51/09 , C07C51/12 , C07C51/41 , C07C67/11 , C07C69/63 , C07C39/30 , C07C49/807 , C07C65/05 , C07C65/21 , C07C69/92
Abstract: A process for reacting chemical compounds comprising the step of oxidizing a compound of formula (II) wherein R 1 and R 2 are halogen, and R 3 is -(C 1 -C 4 ) alkyl, in the presence of a peroxy reagent to obtain a compound of formula (III).
Abstract translation: 一种使化学化合物反应的方法，包括在过氧化试剂存在下氧化式（II）化合物（其中R 1和R 2是卤素）和R 3是 - （C 1 -C 4）烷基）的步骤，得到式（ III）。
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公开(公告)号：WO2015075087A1
公开(公告)日：2015-05-28
申请号：PCT/EP2014/075053
申请日：2014-11-19
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , KORDES, Markus , SCHMELEBECK, Gerald , JI, Junmin , CORTES, David
IPC: C07C67/307 , C07C67/11 , C07C51/15
CPC classification number: C07C67/307 , C07C51/09 , C07C51/15 , C07C67/11 , C07C69/92 , C07C65/05 , C07C65/21
Abstract: The present invention relates to a process for providing a compound of formula (IV), wherein R is - (C 1 -C 4 )alkyl, the process comprising the step of: reacting a compound of formula (III), wherein R is defined as above, in the presence of a Pd(ll) catalyst, a chlorine-containing reagent, a co-oxidant, and an acid.
Abstract translation: 本发明涉及提供其中R为 - （C 1 -C 4）烷基的式（Ⅳ）化合物的方法，该方法包括以下步骤：使式（Ⅳ）化合物（其中R定义如上） 在Pd（II）催化剂，含氯试剂，助氧化剂和酸的存在下进行。
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8.发明申请
公开(公告)号：WO2015067494A1
公开(公告)日：2015-05-14
申请号：PCT/EP2014/072990
申请日：2014-10-27
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , CORTES, David , SCHMELEBECK, Gerald , JI, Junmin
CPC classification number: C07C67/31 , C07C51/367 , C07C69/92 , C07C65/21
Abstract: The present invention relates to a process for providing: a compound of formula (IV): wherein R 1 is hydrogen or -(C 1 -C 4 )alkyl, R 2 is -(C 1 -C 4 )alkyl, and each Hal is an independently selected halogen, the process comprising the step of: Reacting a compound of formula (III) wherein R 1 and Hal are defined as above, and R 3 is an alkali metal, in the presence of a Ag(l) compound, a Cu(ll) compound, and a compound selected from Si(OR 2 ) 4 and B(OR 2 ) 3 .
Abstract translation: 本发明涉及一种提供：式（IV）化合物的方法：其中R 1是氢或 - （C 1 -C 4）烷基，R 2是 - （C 1 -C 4）烷基，每个Hal是独立选择的卤素， 该方法包括以下步骤：在Ag（I）化合物，Cu（II）化合物和Cu（II）化合物存在下，使其中R1和Hal如上定义，R 3为碱金属的式（III）化合物和 选自Si（OR 2）4和B（OR 2）3的化合物。
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9.发明授权
公开(公告)号：EP3052463B1
公开(公告)日：2017-03-01
申请号：EP14784411.2
申请日：2014-09-25
Applicant: BASF SE
Inventor： SCHMELEBECK, Gerald , JI, Junmin , KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , CORTES, David
IPC: C07C37/02
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公开(公告)号：EP3052462B1
公开(公告)日：2018-08-22
申请号：EP14780498.3
申请日：2014-10-02
Applicant: BASF SE
Inventor： KLAUBER, Eric George , RACK, Michael , ZIERKE, Thomas , HOLUB, Nicole , CORTES, David , SCHMELEBECK, Gerald , JI, Junmin
IPC: C07C37/02 , C07C41/16 , C07C39/30 , C07C43/225
CPC classification number: C07C51/377 , C07C37/02 , C07C41/16 , C07C67/297 , C07F1/005 , C07F1/04 , C07C39/30 , C07C43/225
Abstract: The present invention relates to a process for providing a compound of formula (I):, wherein R is hydrogen or R', wherein R' is –(C1-C4)alkyl, and Hal is a halogen, the process comprising the step of: reacting a compound of formula (II) wherein Hal is defined as above, with an alkali metal alkoxide of the formula XOR', wherein X is an alkali metal, and R' is defined as above.
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