Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, and R3 independently from one another stand for alkyl, wherein R4 stands for cycloalkyl, and wherein the mixture provided in step (1) does not contain any substantial amount of a source for Z2O5, wherein Z is P, as well as to zeolitic materials which may be obtained ac- cording to the inventive process and to their use.
Abstract:
The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a methanol active component and an acid component comprising a zeolitic material being crystallized by means of one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for the preparation of dimethyl ether from synthesis gas.
Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, and R3 independently from one another stand for alkyl, wherein R4 stands for cycloalkyl, and wherein the mixture provided in step (1) does not contain any substantial amount of a source for Z2O5, wherein Z is P, as well as to zeolitic materials which may be obtained ac- cording to the inventive process and to their use.
Abstract translation:本发明涉及一种用于具有CHA型骨架结构包含YO 2和X 2 O 3的沸石材料的制备方法,worin所述方法包括以下步骤:(1)提供包括用于YO 2的一个或多个源,一种或混合物 多个源为X 2 O 3,以及一种或多种四烷基铵阳离子R.sup.1R.sup.2R.sup.3R.sup.4N.sup +含化合物作为结构导向剂; (2)结晶化获得具有CHA骨架型结构的沸石材料在步骤(1)中获得的混合物; worin Y是四价元素,X是三价元素,worin R1,R2和R3彼此独立地立场烷基,worin R 4代表环烷基和worin在步骤提供的混合物(1)不包含任何显着量的 为Z 2 O 5源的,worin Z是P,以及到可能用最上端本发明的方法以及它们的用途而获得的沸石材料。
Title translation:BIMETALL-AUSGETAUSCHTER ZEOLITH-BETA AUS ORGANOTEMPLATE-FREIER SYNTHESE UND VERWENDUNG DAVON IN DER SELKKTIVEN KATALYTISCHEN NOX-REDUKTION
Abstract:
The present invention relates to a process for the production of a zeolitic material having a BEA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising one or more sources for YO2 and one or more sources for X2O3; (2) crystallizing the mixture obtained in step (1); (3) subjecting the zeolitic material having a BEA-type framework structure obtained in step (2) to an ion-exchange procedure with Cu; and (4) subjecting the Cu ion-exchanged zeolitic material obtained in step (3) to an ion-exchange procedure with Fe; wherein Y is a tetravalent element, and X is a trivalent element, wherein the mixture provided in step (1) and crystallized in step (2) further comprises seed crystals comprising one or more zeolitic materials having a BEA-type framework structure, and wherein the mixture provided in step (1) and crystallized in step (2) does not contain an organotemplate as a structure-directing agent, as well as to the zeolitic material having a BEA frame work structure per se, and to its use, in particular in a method for the treatment of NOx by selective catalytic reduction (SCR).
Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R4, R5, R6, and R7 independently from one another stand for alkyl, and wherein R8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
Abstract:
The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use. (no suitable figure)
Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R4, R5, R6, and R7 independently from one another stand for alkyl, and wherein R8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
Abstract:
Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Acrylsäure umfassend (i) Bereitstellen eines Stoffstroms enthaltend eine Formaldehyd-Quelle und Essigsäure und (ii) Inkontaktbringen dieses Stoffstroms mit einem Aldolkondensationskatalysator enthaltend ein zeolithisches Material, wobei die Gerüststruktur des zeolithischen Materials gemäß (ii) Si, O, und ein molares Verhältnis Al:Si von von 0:1 bis 0,001:1 aufweist; und wobei die Gerüststruktur des zeolithischen Materials gemäß (ii), zusätzlich zu Si und gegebenenfalls Al, ein oder mehrere Elemente, ausgewählt aus der Gruppe bestehend aus von Si verschiedenen tetravalenten Elementen Y und von Al verschiedenen trivalenten Elementen X, enthält.
Abstract:
La presente invención se refiere a un procedimiento para la preparación de un material zeolítico que comprende los pasos de: (1) proporcionar una mezcla que comprende una o más fuentes para YO2 y uno o más compuestos conteniendo un catión de alqueniltrialquilamonio, R1R2R3R4N+ como agente de dirección de estructura; y (2) cristalizar la mezcla obtenida en el paso (1) para obtener un material zeolítico; en donde Y es un elemento tetravalente, y en donde R1, R2, y R3 independientemente uno del otro representan alquilo; y R4 representa alquenilo, así como los materiales zeolíticos que pueden ser obtenidos de acuerdo con el procedimiento de la invención y a su uso.
Abstract:
The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, wherein the catalyst displays a water uptake of 9.0 wt.-% or less, as well as to a process for the production thereof and to its use, in particular in a process for converting oxygenates to olefins.