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    A PROCESS FOR PREPARING ETHENE OXIDE
    21.
    发明申请
    A PROCESS FOR PREPARING ETHENE OXIDE 审中-公开
    一种制备乙烯氧化物的方法

    公开(公告)号：WO2018011280A1

    公开(公告)日：2018-01-18

    申请号：PCT/EP2017/067576

    申请日：2017-07-12

    Applicant: BASF SE

    Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  TELES, Joaquim Henrique ,  RIEDEL, Dominic ,  WEBER, Markus ,  LI, Yan

    IPC: C07D301/12

    Abstract: A process for preparing ethene oxide comprising providing a liquid feed stream comprising ethene, hydrogen peroxide, and a solvent; passing the liquid feed stream into an epoxidation zone comprising a catalyst comprising a titanium zeolite comprising zinc and having framework type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising ethene oxide, water, and the solvent; removing an effluent stream from the epoxidation zone, the effluent stream comprising ethene oxide, water and the solvent.

    Abstract translation: 一种制备氧化乙烯的方法，包括提供包含乙烯，过氧化氢和溶剂的液体进料物流; 使液体进料流进入包含催化剂的环氧化区，所述催化剂包含含锌沸石并具有骨架类型MWW，并使液体进料流在环氧化区中经受环氧化反应条件，获得包含氧化乙烯，水和 溶剂; 从环氧化区中除去流出物流，所述流出物流包含氧化乙烯，水和溶剂。

    A PROCESS FOR PREPARING PROPYLENE OXIDE
    22.
    发明申请
    A PROCESS FOR PREPARING PROPYLENE OXIDE 审中-公开
    一种制备丙烯氧化物的方法

    公开(公告)号：WO2015010991A1

    公开(公告)日：2015-01-29

    申请号：PCT/EP2014/065244

    申请日：2014-07-16

    Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

    Inventor： TELES, Joaquim Henrique ,  SEELIG, Bianca ,  RIEDEL, Dominic ,  KAMPE, Philip ,  URBANCZYK, Daniel ,  WEBER, Markus ,  MÜLLER, Ulrich ,  PARVULESCU, Andrei-Nicolae ,  GUMLICH, Kai ,  BASSLER, Peter ,  BARTOSCH, Christian ,  JACUBINAS, Richard ,  WEIDENBACH, Meinolf ,  WITZL, Werner

    IPC: B01J29/89 ,  B01J37/02 ,  C07D301/12 ,  B01J27/16

    CPC classification number: C07D301/12 ,  B01J27/18 ,  B01J27/188 ,  B01J29/7038 ,  B01J29/7088 ,  B01J35/002 ,  B01J35/1019 ,  B01J2229/186 ,  Y02P20/52

    Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MVVW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

    Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，任选的丙烷和至少一种溶解的含磷酸钾的液体进料流，其中钾相对的摩尔比 在磷氧基酸的至少一种钾盐中的磷在0.6至1.4的范围内; （ii）将（i）中提供的液体进料流送入包含催化剂的环氧化反应器中，所述催化剂包含含锌的结构型MVVW的钛沸石，并使液体进料流在环氧化反应器中进行环氧化反应条件，得到反应混合物 包括环氧丙烷，乙腈，水，所述至少一种溶解的含磷酸的钾盐，任选的丙烯，以及任选的丙烷; （iii）从环氧化反应器中除去流出物流，所述流出物流包含环氧丙烷，乙腈，水，所述至少一种溶解的含磷酸的钾盐，任选的丙烯和任选的丙烷的至少一部分。

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