公开(公告)号：WO2012141875A1

公开(公告)日：2012-10-18

申请号：PCT/US2012/030508

申请日：2012-03-26

Applicant: ARKEMA INC. ,  BATTELLE MEMORIAL INSTITUTE ,  SILVERMAN, Gary S. ,  KOROTKOV, Roman Y. ,  SMITH, Ryan C. ,  LIU, Jun ,  GASPAR, Daniel J. ,  PADMAPERUMA, Asanga B. ,  WANG, Liang ,  SCHWENZER, Birgit ,  SWENSEN, James S.

Inventor： SILVERMAN, Gary S. ,  KOROTKOV, Roman Y. ,  SMITH, Ryan C. ,  LIU, Jun ,  GASPAR, Daniel J. ,  PADMAPERUMA, Asanga B. ,  WANG, Liang ,  SCHWENZER, Birgit ,  SWENSEN, James S.

IPC: H01L51/50

CPC classification number: H01L51/5275 ,  H01L51/5268

Abstract: A light-emitting device, which improves the light output of organic light emitting diodes (OLEDs), includes at least one porous metal or metalloid oxide light extraction layer positioned between the substrate and the transparent conducting material layer in the OLED. The index of refraction of the light extraction layer and the light scattering may be tuned by changing the pore size, pore density, doping the metal oxide, adding an insulating, conducting or semiconducting component, or filling the pores, for example. A method for forming the light-emitting device includes forming at least one light extraction layer comprising a porous metal or metalloid oxide on a substrate, for example, using atmospheric pressure chemical vapor deposition (APCVD), and subsequently, forming a transparent conducting material on the light extraction layer.

Abstract translation: 改善有机发光二极管（OLED）的光输出的发光器件包括位于OLED中的衬底和透明导电材料层之间的至少一个多孔金属或准金属氧化物光提取层。 可以通过改变孔径，孔密度，掺杂金属氧化物，添加绝缘，导电或半导体组分或填充孔，来调节光提取层的折射率和光散射。 用于形成发光器件的方法包括在基底上形成至少一个包含多孔金属或准金属氧化物的光提取层，例如使用大气压化学气相沉积（APCVD），然后形成透明导电材料 光提取层。

公开(公告)号：WO2012047372A1

公开(公告)日：2012-04-12

申请号：PCT/US2011/047144

申请日：2011-08-09

Applicant: BATTELLE MEMORIAL INSTITUTE ,  LIU, Jun ,  CHOI, Daiwon ,  BENNETT, Wendy ,  GRAFF, Gordon, L. ,  SHIN, Yongsoon

Inventor： LIU, Jun ,  CHOI, Daiwon ,  BENNETT, Wendy ,  GRAFF, Gordon, L. ,  SHIN, Yongsoon

IPC: H01M4/04 ,  H01M4/583 ,  H01M4/48 ,  H01M4/62 ,  H01M10/0525

CPC classification number: H01M4/0457 ,  H01M4/0404 ,  H01M4/13 ,  H01M4/139 ,  H01M4/362 ,  H01M4/366 ,  H01M4/483 ,  H01M4/587 ,  Y02E60/122 ,  Y10T29/49115

Abstract: A method for forming a nanocomposite material, the nanocomposite material formed thereby, and a battery made using the nanocomposite material. Metal oxide and graphene are placed in a solvent to form a suspension. The suspension is then applied to a current collector. The solvent is then evaporated to form a nanocomposite material. The nanocomposite material is then electrochemically cycled to form a nanocomposite material of at least one metal oxide in electrical communication with at least one graphene layer.

Abstract translation: 形成纳米复合材料的方法，由此形成的纳米复合材料和使用纳米复合材料制成的电池。 将金属氧化物和石墨烯置于溶剂中以形成悬浮液。 然后将悬浮液施加到集电器。 然后将溶剂蒸发以形成纳米复合材料。 然后将纳米复合材料电化学循环以形成与至少一个石墨烯层电连通的至少一个金属氧化物的纳米复合材料。

公开(公告)号：WO2011019765A1

公开(公告)日：2011-02-17

申请号：PCT/US2010/045089

申请日：2010-08-10

Applicant: BATTELLE MEMORIAL INSTITUTE ,  LIU, Jun ,  CHOI, Daiwon ,  KOU, Rong ,  NIE, Zimin ,  WANG, Donghai ,  YANG, Zhenguo ,  AKSAY, Ilhan, A.

Inventor： LIU, Jun ,  CHOI, Daiwon ,  KOU, Rong ,  NIE, Zimin ,  WANG, Donghai ,  YANG, Zhenguo ,  AKSAY, Ilhan, A.

IPC: H01M4/62 ,  H01M4/66 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525

CPC classification number: H01M4/624 ,  H01M4/366 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/663 ,  H01M10/0525 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49 ,  Y10T156/10 ,  Y10T428/30

Abstract: Nanocomposite materials having at least two layers, each layer consisting of one metal oxide bonded to at least one graphene layer were developed. The nanocomposite materials will typically have many alternating layers of metal oxides and graphene layers, bonded in a sandwich type construction and will be incorporated into an electrochemical or energy storage device.

Abstract translation: 开发了具有至少两层的纳米复合材料，每层由结合到至少一个石墨烯层的一种金属氧化物组成。 纳米复合材料通常将具有许多金属氧化物和石墨烯层的交替层，以三明治式结构结合并且将被结合到电化学或能量存储装置中。

公开(公告)号：WO1998024724A1

公开(公告)日：1998-06-11

申请号：PCT/US1997021754

申请日：1997-11-25

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： BATTELLE MEMORIAL INSTITUTE ,  BRUINSMA, Paul, J. ,  BASKARAN, Suresh ,  BONTHA, Jagannadha, R. ,  LIU, Jun

IPC: C01B37/00

CPC classification number: C04B41/4582 ,  B01J20/103 ,  B01J21/08 ,  B01J37/0236 ,  B01J37/033 ,  C01B37/005 ,  C01B37/02 ,  C04B20/0056 ,  C04B35/14 ,  C04B35/62218 ,  C04B38/0022 ,  C04B41/009 ,  C04B41/81 ,  C04B38/009 ,  C04B38/02 ,  C04B38/10 ,  C04B14/4631 ,  C04B20/006

Abstract: This invention pertains to surfactant-templated nanometer-scale porosity of a silicia precursor solution and forming a mesoporous material by first forming the silicia precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silicia precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof.

Abstract translation: 本发明涉及二氧化硅前体溶液的表面活性剂模板纳米级孔隙度并形成介孔材料，首先将硅石前体溶液形成具有高表面积与体积比的预成型体，然后快速干燥或蒸发硅溶胶 前体溶液。 介孔材料可以是任何几何形式，但优选为薄膜，纤维，粉末或其组合的形式。

公开(公告)号：WO2012134553A2

公开(公告)日：2012-10-04

申请号：PCT/US2011/063404

申请日：2011-12-06

Applicant: BATTELLE MEMORIAL INSTITUTE ,  XIA, Guanguang ,  YANG, Zhenguo ,  LI, Liyu ,  KIM, Soowhan ,  LIU, Jun ,  GRAFF, Gordon, L.

Inventor： XIA, Guanguang ,  YANG, Zhenguo ,  LI, Liyu ,  KIM, Soowhan ,  LIU, Jun ,  GRAFF, Gordon, L.

IPC: H01M8/18 ,  H01M8/02

CPC classification number: H01M8/188 ,  H01M2/1653 ,  H01M4/9083 ,  H01M4/926 ,  H01M4/96 ,  H01M8/18 ,  H01M8/20 ,  Y02E60/528

Abstract: Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S 2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

Abstract translation: 硫化铁氧化还原液流电池（RFB）系统对于储能可能是有利的，特别是当电解质的pH值大于6时，这种系统可表现出优异的能量转换效率和稳定性，并且可以利用相对更安全的低成本材料， 更环保。 硫化铁RFB的一个实例的特征在于在正电解质支持溶液中包含Fe（III）和/或Fe（II）的正电解质，负电解质，其包含负电解质支持中的S2-和/或S 溶液以及将正电解质和电极与负电解质和电极分离的膜或隔膜。

公开(公告)号：WO2012091827A2

公开(公告)日：2012-07-05

申请号：PCT/US2011/062016

申请日：2011-11-23

Applicant: BATTELLE MEMORIAL INSTITUTE ,  CHOI, Daiwon ,  LIU, Jun ,  YANG, Zhenguo ,  WANG, Wei ,  GRAFF, Gordon, L.

Inventor： CHOI, Daiwon ,  LIU, Jun ,  YANG, Zhenguo ,  WANG, Wei ,  GRAFF, Gordon, L.

IPC: H01M4/583 ,  H01M4/86 ,  B82Y30/00

CPC classification number: H01M4/5825 ,  B82Y30/00 ,  H01M4/583

Abstract: A lithium ion battery having an anode, an electrolyte, and a cathode comprising nano-structured carbon in electrical communication with LiFePO 4 . The cathode of the lithium ion battery of the present invention has sufficient structural stability to maintain at least 90-99 percent of the specific capacity of the cathode over 500 charge/discharge cycles.

Abstract translation: 一种具有阳极，电解质和阴极的锂离子电池，其包含与LiFePO 4电连通的纳米结构碳。 本发明的锂离子电池的阴极具有足够的结构稳定性，以在500次充电/放电循环中保持阴极的比容量的至少90-99％。

公开(公告)号：WO2010093500A1

公开(公告)日：2010-08-19

申请号：PCT/US2010/021450

申请日：2010-01-20

Applicant: BATTELLE MEMORIAL INSTITUTE ,  ZHANG, Jiguang ,  LIU, Jun ,  YANG, Zhenguo ,  XIA, Guanguang ,  FIFIELD, Leonard, S. ,  WANG, Donghai ,  CHOI, Daiwon ,  GRAFF, Gordon, L. ,  PEDERSON, Larry, R.

Inventor： ZHANG, Jiguang ,  LIU, Jun ,  YANG, Zhenguo ,  XIA, Guanguang ,  FIFIELD, Leonard, S. ,  WANG, Donghai ,  CHOI, Daiwon ,  GRAFF, Gordon, L. ,  PEDERSON, Larry, R.

IPC: H01M4/38 ,  H01M4/58 ,  H01M4/134

CPC classification number: H01M4/134 ,  B82Y30/00 ,  B82Y40/00 ,  C01B33/02 ,  C01B33/113 ,  H01M4/386 ,  H01M4/485 ,  H01M4/58 ,  H01M10/052 ,  H01M2004/021 ,  Y10S977/721 ,  Y10S977/722 ,  Y10S977/762 ,  Y10S977/775 ,  Y10S977/843

Abstract: Methods of the present invention can be used to synthesize nanowires with controllable compositions and/or with, multiple elements. The methods include coating solid powder granules, which comprise a first element, with a catalyst. The catalyst and the first element form when heated a liquid, mixed phase having a eutectic or peritectic point. The granules, which have been coated with the catalyst, are then heated to a temperature greater than or equal to the eutectic or peritectic point. During heating, a vapor source comprising the second element is introduced. The vapor source chemically interacts with the liquid, mixed phase to consume the first element and to induce condensation of a product that comprises the first and second elements in the form of a nanowire. The invention further relates to an energy storage device comprising Si-containing nanowires.

Abstract translation: 本发明的方法可用于合成具有可控组合物和/或多个元素的纳米线。 所述方法包括用催化剂涂覆包含第一元素的固体粉末颗粒。 当加热液体，具有共晶或包晶点的混合相时，催化剂和第一元素形式。 已经涂覆有催化剂的颗粒然后被加热到高于或等于共晶或包晶点的温度。 在加热期间，引入包括第二元件的蒸气源。 蒸汽源与液体，混合相化学相互作用以消耗第一元素并诱导包含纳米线形式的第一和第二元素的产物的冷凝。 本发明还涉及包含含Si纳米线的储能装置。

公开(公告)号：WO2016069934A1

公开(公告)日：2016-05-06

申请号：PCT/US2015/058131

申请日：2015-10-29

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： XIAO, Jie ,  LIU, Jun ,  PAN, Huilin ,  HENDERSON, Wesley, A.

IPC: H01M8/18 ,  H01M4/13 ,  C25B15/08

CPC classification number: H01M4/663 ,  H01M8/20 ,  H01M12/08 ,  Y02E60/128

Abstract: A device comprising: a lithium sulfur redox flow battery comprising an electrolyte composition comprising: (i) a dissolved Li 2 S x electroactive salt, wherein x ≥4; (ii) a solvent selected from dimethyl sulfoxide, tetrahydrofuran, or a mixture thereof; and (iii) a supporting salt at a concentration of at least 2 M, as measured by moles of supporting salt divided by the volume of the solvent without considering the volume change of the electrolyte after dissolving the supporting salt.

Abstract translation: 一种装置，其包含：锂硫氧化还原液流电池，其包含电解质组合物，所述电解质组合物包含：（i）溶解的Li 2 S x电活性盐， 其中x≥4; （ii）选自二甲基亚砜，四氢呋喃或其混合物的溶剂; 和（iii）以支持盐的摩尔数除以溶剂体积测量的至少2M浓度的支持盐，而不考虑溶解支持盐后电解质的体积变化。

公开(公告)号：WO2015123033A1

公开(公告)日：2015-08-20

申请号：PCT/US2015/013704

申请日：2015-01-30

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： XIAO, Jie ,  LU, Dongping ,  LIU, Jun ,  ZHANG, Jiguang ,  GRAFF, Gordon L.

IPC: H01M4/136 ,  H01M4/58 ,  H01M4/62

CPC classification number: H01M4/366 ,  B82Y30/00 ,  C01B32/05 ,  H01M4/0404 ,  H01M4/0471 ,  H01M4/139 ,  H01M4/1393 ,  H01M4/1395 ,  H01M4/1397 ,  H01M4/362 ,  H01M4/386 ,  H01M4/485 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/5825 ,  H01M4/587 ,  H01M4/621 ,  H01M4/625 ,  H01M2004/021

Abstract: Electrodes having nanostructure and/or utilizing nanoparticles of active materials and having high mass loadings of the active materials can be made to be physically robust and free of cracks and pinholes. The electrodes include nanoparticles having electroactive material, which nanoparticles are aggregated with carbon into larger secondary particles. The secondary particles can be bound with a binder to form the electrode.

Abstract translation: 具有纳米结构和/或利用活性材料的纳米颗粒并且具有高质量负载的活性材料的电极可以被制成物理上坚固的并且没有裂缝和针孔。 电极包括具有电活性材料的纳米颗粒，其纳米颗粒与碳聚集成较大的二次颗粒。 二次粒子可以用粘合剂结合以形成电极。

公开(公告)号：WO2014003825A1

公开(公告)日：2014-01-03

申请号：PCT/US2013/020620

申请日：2013-01-08

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： LIU, Jun ,  XIAO, Jie ,  HUANG, Cheng

IPC: H01M4/02 ,  H01M4/583 ,  H01M4/38 ,  H01M10/05

CPC classification number: H01M4/38 ,  H01M4/13 ,  H01M4/405 ,  H01M4/485 ,  H01M4/5815 ,  H01M4/587 ,  H01M10/0525

Abstract: Energy storage devices having hybrid anodes can address at least the problems of active material consumption and anode passivation that can be characteristic of traditional batteries. The energy storage devices each have a cathode separated from the hybrid anode by a separator. The hybrid anode includes a carbon electrode connected to a metal electrode, thereby resulting in an equipotential between the carbon and metal electrodes.

Abstract translation: 具有混合阳极的储能装置可以至少解决可能是传统电池特征的活性材料消耗和阳极钝化的问题。 能量存储装置各自具有通过分离器与混合阳极分离的阴极。 混合阳极包括连接到金属电极的碳电极，从而在碳和金属电极之间产生等电位。