公开(公告)号：US09597669B2

公开(公告)日：2017-03-21

申请号：US13927839

申请日：2013-06-26

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Kerem Bay ,  Manuela Gaab ,  Ekkehard Schwab ,  Michael Hesse

IPC: B01J29/06 ,  C07C1/20 ,  B01J29/40 ,  B01J38/02 ,  B01J23/02 ,  B01J23/10 ,  B01J29/70 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/02 ,  B01J37/28 ,  B01J37/00 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

CPC classification number: B01J29/40 ,  B01J23/02 ,  B01J23/10 ,  B01J29/061 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0215 ,  B01J37/28 ,  B01J38/02 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/20 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C2521/04 ,  C07C2527/173 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/584 ,  C07C11/02

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals, and the particles of the one or more metal oxides comprising phosphorus, the phosphorus being present at least partly in oxidic form, and the one or more alkaline earth metals being selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, to the preparation and use thereof, and to a process for converting oxygenates to olefins using the catalyst.

公开(公告)号：US20160296923A1

公开(公告)日：2016-10-13

申请号：US15183506

申请日：2016-06-15

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Ekkehard Schwab ,  Alexander Weck ,  Kerem Bay

IPC: B01J29/40 ,  B01J38/02 ,  B01J37/08 ,  B01J29/90 ,  C07C1/20 ,  B01J37/02

CPC classification number: B01J29/40 ,  B01J19/2485 ,  B01J23/02 ,  B01J23/10 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/7049 ,  B01J29/7088 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/08 ,  B01J38/02 ,  B01J38/04 ,  B01J2219/2404 ,  B01J2219/2434 ,  B01J2219/2438 ,  B01J2219/2446 ,  C07C1/20 ,  C07C1/22 ,  C07C2523/78 ,  C07C2529/40 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/02

Abstract: The present invention relates to a process for converting oxygenates to olefins, comprising (1) providing a gas stream comprising one or more ethers; (2) contacting the gas stream provided in (1) with a catalyst, the catalyst comprising a support substrate and a layer applied to the substrate, the layer comprising one or more zeolites of the MFI, MEL and/or MWW structure type.

Abstract translation: 本发明涉及将含氧物转化为烯烃的方法，其包括（1）提供包含一种或多种醚的气流; （2）使（1）中提供的气流与催化剂接触，所述催化剂包含支撑衬底和施加到衬底的层，所述层包含MFI，MEL和/或MWW结构类型的一种或多种沸石。

公开(公告)号：US20160145171A1

公开(公告)日：2016-05-26

申请号：US14897379

申请日：2014-06-13

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Andrei-Nicolae Parvulescu ,  Armin Lange de Oliveira ,  Stefan Marx ,  Mathias Feyen ,  Ulrich Müller ,  Ekkehard Schwab

IPC: C07C1/20 ,  B01J29/89 ,  C01B39/08 ,  C07C1/207

CPC classification number: C07C1/20 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/37 ,  B01J2229/62 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01P2006/12 ,  C07C1/2076 ,  C07C2529/70 ,  C07C2529/78 ,  C07C2529/86 ,  C07C2529/89 ,  C07C11/167

Abstract: The present invention relates to a gas-phase process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 comprising ethanol with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene, wherein the catalyst comprises a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, as well as to a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, wherein the zeolitic material displays a specific X-ray powder diffraction pattern, and to its use.

Abstract translation: 本发明涉及用于制备丁二烯的气相方法，其包括（i）提供包含乙醇的气流G-1; （ii）使包含乙醇的气流G-1与催化剂接触，从而获得包含丁二烯的气流G-2，其中所述催化剂包含具有包含YO 2，Y代表一种或多种四价元素的骨架结构的沸石材料， 其中包含在骨架结构中的Y的至少一部分被一种或多种元素X同晶取代，以及具有包含Y 2 O，Y代表一种或多种四价元素的骨架结构的沸石材料，其中至少一部分 包含在骨架结构中的Y由一种或多种元素X同晶取代，其中沸石材料显示特定的X射线粉末衍射图案及其用途。

公开(公告)号：US20140005455A1

公开(公告)日：2014-01-02

申请号：US13927718

申请日：2013-06-26

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Ekkehard Schwab ,  Alexander Weck ,  Kerem Bay

IPC: B01J29/70 ,  C07C1/22

CPC classification number: B01J29/40 ,  B01J19/2485 ,  B01J23/02 ,  B01J23/10 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/7049 ,  B01J29/7088 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/08 ,  B01J38/02 ,  B01J38/04 ,  B01J2219/2404 ,  B01J2219/2434 ,  B01J2219/2438 ,  B01J2219/2446 ,  C07C1/20 ,  C07C1/22 ,  C07C2523/78 ,  C07C2529/40 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/02

Abstract: The present invention relates to a process for converting oxygenates to olefins, comprising (1) providing a gas stream comprising one or more ethers; (2) contacting the gas stream provided in (1) with a catalyst, the catalyst comprising a support substrate and a layer applied to the substrate, the layer comprising one or more zeolites of the MFI, MEL and/or MWW structure type.

Abstract translation: 本发明涉及将含氧物转化为烯烃的方法，其包括（1）提供包含一种或多种醚的气流; （2）使（1）中提供的气流与催化剂接触，所述催化剂包含支撑衬底和施加到衬底的层，所述层包含MFI，MEL和/或MWW结构类型的一种或多种沸石。

公开(公告)号：US20130115707A1

公开(公告)日：2013-05-09

申请号：US13667567

申请日：2012-11-02

Applicant: BASF SE

Inventor： Ekkehard Schwab ,  Heiko Urtel ,  Schaefer Alexander

IPC: G01N21/78

CPC classification number: G01N21/78 ,  B01D53/02 ,  B01D53/04 ,  B01D53/0454 ,  B01D2253/102 ,  B01D2253/108 ,  B01D2256/24 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2259/40084 ,  B01J20/0214 ,  B01J20/0218 ,  B01J20/0222 ,  B01J20/0244 ,  B01J20/08 ,  B01J20/18 ,  B01J20/28042 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3291 ,  C10L3/103 ,  C10L3/12 ,  H01M8/0675 ,  Y02E60/50 ,  Y10T436/18

Abstract: A method for removing sulfur-comprising compounds from a hydrocarbonaceous gas mixture, in which an adsorber material is brought into contact with the hydrocarbonaceous gas mixture, wherein the adsorber material comprises a material that adsorbs sulfur-comprising compounds and, in addition, comprises at least one transition metal compound which changes color thereof by reaction with the sulfur-comprising compounds.

Abstract translation: 一种从烃类气体混合物中除去含硫化合物的方法，其中吸附材料与烃类气体混合物接触，其中吸附材料包括吸附含硫化合物的材料，此外至少包括 一种通过与含硫化合物反应而改变其颜色的过渡金属化合物。