公开(公告)号：US09243754B2

公开(公告)日：2016-01-26

申请号：US14048223

申请日：2013-10-08

Applicant: BASF SE

Inventor： Mathias Weickert ,  Stefan Marx ,  Ulrich Müller ,  Peter Renze ,  Christian-Andreas Winkler

IPC: F17C11/00

CPC classification number: F17C11/005 ,  F17C11/00 ,  F17C11/007

Abstract: Described is a method of charging a sorption store with a gas. The sorption store comprises a closed container which is at least partly filled with an adsorption medium and has an inlet and an outlet which can each be closed by a shut-off element. The method comprises the steps: (a) closing of the outlet shut-off element and opening of the inlet shut-off element, (b) introduction of gas to be stored under a predetermined pressure through the inlet, (c) rapid opening of the outlet shut-off element with the inlet shut-off element open so that a gas flow having a predetermined flow rate is established in the container, (d) reduction of the flow rate as a function of the adsorption rate of the gas adsorbed in the store, and (e) complete closing of the outlet shut-off element.

Abstract translation: 描述了一种用气体对吸附物料进行充电的方法。 吸附储存器包括至少部分地填充有吸附介质的封闭容器，并且具有能够被截止元件封闭的入口和出口。 该方法包括以下步骤：（a）关闭出口关闭元件并打开入口关闭元件，（b）通过入口引入要在预定压力下储存的气体，（c）快速打开 具有入口关闭元件的出口关闭元件打开，使得在容器中建立具有预定流速的气流，（d）作为吸附在吸附剂中的气体的吸附速率的函数的流量的降低 商店，（e）完全关闭出口关闭元件。

公开(公告)号：US08648002B2

公开(公告)日：2014-02-11

申请号：US13734490

申请日：2013-01-04

Applicant: BASF SE

Inventor： Markus Schubert ,  Ulrich Müller ,  Stefan Marx

IPC: B01J31/00

CPC classification number: B01D53/02 ,  B01D2253/204 ,  B01J20/226 ,  B01J20/28014 ,  B01J20/28042 ,  B01J20/28054 ,  B01J31/1691 ,  B01J31/2239 ,  B01J35/1028 ,  B01J2531/31 ,  B01J2531/62 ,  B01J2531/842 ,  C07C51/418 ,  C07C63/28 ,  C07C63/38

Abstract: The present invention relates to a porous metal organic framework comprising a bidentate organic compound coordinated to a metal ion selected from the group of metals consisting of Al, Fe and Cr, with the bidentate organic compound being derived from a dicarboxylic acid, wherein the framework has a structure whose projection along [001] has a pattern in which each side of a hexagon is bounded by a triangle. The present invention further relates to shaped bodies and a process for preparing the porous metal organic framework and its use.

Abstract translation: 本发明涉及多孔金属有机骨架，其包含与选自Al，Fe和Cr的金属组合的金属离子配位的二齿有机化合物，二齿有机化合物衍生自二羧酸，其中骨架具有 沿[001]的投影具有六边形的每一边由三角形界定的图案的结构。 本发明还涉及成型体及其制备多孔金属有机骨架及其用途的方法。

公开(公告)号：US20240309022A1

公开(公告)日：2024-09-19

申请号：US18571305

申请日：2022-06-21

Applicant: BASF SE

Inventor： Barbara Nave ,  Stefan Marx ,  Maarten Staal ,  Stefanie Calde ,  Joachim Dickhaut ,  Uwe Thiel

IPC: C07F3/06 ,  C01B37/00 ,  C05G3/90

CPC classification number: C07F3/06 ,  C01B37/00 ,  C05G3/90

Abstract: The present invention relates to a metal-organic framework comprising (i) at least one metal M selected from the group consisting of Na, K, Ca, Mg, Zn, Fe, Mn, Cu, Al, Ni, and Mo in cationic form; and at least one substituted pyrazolate compound of formula (I). Further, the present invention relates to the use of the metal-organic framework of the invention and methods of applying the metal-organic framework of the invention for reducing nitrification. Moreover, the present invention relates to agrochemical mixtures and compositions comprising the metal-organic framework of the invention as well as to a method of treating a fertilizer comprising the application of a metal-organic framework of the invention.

公开(公告)号：US10737239B2

公开(公告)日：2020-08-11

申请号：US15779314

申请日：2016-11-23

Applicant: BASF SE

Inventor： Julia Burckhart ,  Stefan Marx ,  Lena Arnold ,  Claus Hofmann ,  Ulrich Müller

IPC: C07F1/08 ,  B01J20/22 ,  B01J20/30 ,  B01J20/28 ,  C07F3/06 ,  C07F5/06

Abstract: The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.

公开(公告)号：US10422480B2

公开(公告)日：2019-09-24

申请号：US15524484

申请日：2015-11-10

Applicant: BASF SE

Inventor： Matthias Weickert ,  Stefan Marx ,  Ulrich Müller ,  Lena Arnold ,  Adam Lack ,  Joseph Lynch ,  William Dolan ,  Michael Santamaria

IPC: F17C1/00 ,  F17C11/00 ,  B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  F17C5/00

Abstract: The invention is related to a storage vessel (1) comprising a shaped body (3) of a porous solid, wherein the storage vessel (1) comprises a wall (5) with a section (7) comprising at least one inlet (9), wherein the storage vessel (1) has a central axis (11) and the central axis (11) is a longitudinal axis of the storage vessel (1) and/or perpendicular to a cross-sectional area of the at least one inlet (9), wherein the shaped body (3) covers at least 85% of an inner volume (13) of the storage vessel (1) and the shaped body (3) comprises an opening (19) in an axial direction (17), axial referring to the central axis (11) of the storage vessel (1), wherein the opening (19) extends from a first end (21) of the shaped body (3) to an opposing second end (23) of the shaped body (3) and wherein the storage vessel (1) comprises exactly one shaped body (3), which is formed in one piece. The invention is further related to a shaped body and use of the shaped body.

公开(公告)号：US20140097100A1

公开(公告)日：2014-04-10

申请号：US14048358

申请日：2013-10-08

Applicant: BASF SE

Inventor： Mathias Weickert ,  Stefan Marx ,  Ulrich Müller ,  Peter Renze

IPC: F17C11/00

CPC classification number: F17C11/005 ,  F17C11/00 ,  F17C11/007

Abstract: Described is a method of charging a sorption store with a gas. The sorption store comprises a closed container and a feed device which has a passage through the container wall, through which the gas can flow into the container, and the container has at least two parallel, channel-shaped subchambers which are located in its interior and are each at least partly filled with an adsorption medium and whose channel walls are coolable. The method comprises, in a first step, feeding in a gas in such an amount that a pressure in the store of at least 30% of a predetermined final pressure is reached as quickly as possible and, in a second step, subsequently varying the amount of gas fed in in such a way that the course of the pressure in the store approximates the adsorption kinetics of the adsorption medium until the predetermined final pressure in the store is reached after a predetermined period of time.

Abstract translation: 描述了一种用气体对吸附物料进行充电的方法。 吸附储存器包括密封容器和进料装置，其具有通过容器壁的通道，气体可以通过该通道流入容器中，并且容器具有位于其内部的至少两个平行的通道形子室， 各自至少部分地填充有吸附介质，并且其通道壁是可冷却的。 该方法包括在第一步骤中，将气体供给量使得储存器中的压力达到尽可能快的至少30％的预定最终压力，并且在第二步骤中随后改变量 以这样的方式供给气体，使得商店中的压力过程接近吸附介质的吸附动力学，直到在预定时间段之后达到储存器中的预定最终压力。

公开(公告)号：US11046587B2

公开(公告)日：2021-06-29

申请号：US16308928

申请日：2017-06-14

Applicant: BASF SE

Inventor： Stefan Marx ,  Stefanie Clade ,  Lena Arnold ,  Uwe Diehlmann ,  Ulrich Mueller

IPC: C01B39/02 ,  C01B39/48 ,  B01D53/94 ,  B01J29/06 ,  B01J29/70 ,  B01J29/76 ,  C01B39/04 ,  B01J29/072 ,  B01J19/00 ,  B01J19/18 ,  B01J37/32 ,  B01J37/00 ,  B01J29/86 ,  B01J29/87

Abstract: A continuous process for preparing a zeolitic material comprising (i) preparing a mixture comprising a source of YO2, optionally a source of X2O3, and a liquid solvent system; (ii) continuously feeding the mixture prepared in (i) into a continuous flow reactor at a liquid hourly space velocity in the range of from 0.3 to 20 h−1 for a duration of at least 1 h; and (iii) crystallizing the zeolitic material from the mixture in the continuous flow reactor, wherein the mixture is heated to a temperature in the range of from 100 to 300° C.; wherein the volume of the continuous flow reactor is in the range of from 150 cm3 to 75 m3, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

公开(公告)号：US20140150485A1

公开(公告)日：2014-06-05

申请号：US14090231

申请日：2013-11-26

Applicant: BASF SE

Inventor： Mathias Weickert ,  Stefan Marx ,  Ulrich Müller ,  Christian-Andreas Winkler

IPC: H01M10/50

CPC classification number: H01M10/6568 ,  B60L58/26 ,  H01M8/04201 ,  H01M10/613 ,  H01M10/625 ,  H01M10/66 ,  Y02T10/7005 ,  Y02T10/705

Abstract: Described is a storage unit for a drive system in a vehicle. The storage unit has at least one sorption store, at least one battery, and at least one cooling circuit. The sorption store is coupled via the cooling circuit to the battery. Further described is a method of operating the storage unit and also a drive system and a vehicle equipped with such a storage unit.

Abstract translation: 描述了一种用于车辆中的驱动系统的存储单元。 存储单元具有至少一个吸附储存器，至少一个电池和至少一个冷却回路。 吸附存储器通过冷却回路耦合到电池。 进一步描述了操作存储单元以及配备有这种存储单元的驱动系统和车辆的方法。

公开(公告)号：US09878965B2

公开(公告)日：2018-01-30

申请号：US14897379

申请日：2014-06-13

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Andrei-Nicolae Parvulescu ,  Armin Lange de Oliveira ,  Stefan Marx ,  Mathias Feyen ,  Ulrich Müller ,  Ekkehard Schwab

IPC: C07C1/24 ,  C07C1/20 ,  B01J29/89 ,  B01J37/00 ,  C01B39/02 ,  C01B39/08 ,  C01B39/12 ,  C07C1/207

CPC classification number: C07C1/20 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/37 ,  B01J2229/62 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01P2006/12 ,  C07C1/2076 ,  C07C2529/70 ,  C07C2529/78 ,  C07C2529/86 ,  C07C2529/89 ,  C07C11/167

Abstract: The present invention relates to a gas-phase process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 comprising ethanol with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene, wherein the catalyst comprises a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, as well as to a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, wherein the zeolitic material displays a specific X-ray powder diffraction pattern, and to its use.

公开(公告)号：US09322510B2

公开(公告)日：2016-04-26

申请号：US14048358

申请日：2013-10-08

Applicant: BASF SE

Inventor： Mathias Weickert ,  Stefan Marx ,  Ulrich Müller ,  Peter Renze

IPC: F17C11/00

CPC classification number: F17C11/005 ,  F17C11/00 ,  F17C11/007

Abstract: Described is a method of charging a sorption store with a gas. The sorption store comprises a closed container and a feed device which has a passage through the container wall, through which the gas can flow into the container, and the container has at least two parallel, channel-shaped subchambers which are located in its interior and are each at least partly filled with an adsorption medium and whose channel walls are coolable. The method comprises, in a first step, feeding in a gas in such an amount that a pressure in the store of at least 30% of a predetermined final pressure is reached as quickly as possible and, in a second step, subsequently varying the amount of gas fed in in such a way that the course of the pressure in the store approximates the adsorption kinetics of the adsorption medium until the predetermined final pressure in the store is reached after a predetermined period of time.

Abstract translation: 描述了一种用气体对吸附物料进行充电的方法。 吸附储存器包括密封容器和进料装置，其具有通过容器壁的通道，气体可以通过该通道流入容器中，并且容器具有位于其内部的至少两个平行的通道形子室， 各自至少部分地填充有吸附介质，并且其通道壁是可冷却的。 该方法包括在第一步骤中，将气体供给量使得储存器中的压力达到尽可能快的至少30％的预定最终压力，并且在第二步骤中随后改变量 以这样的方式供给气体，使得商店中的压力过程接近吸附介质的吸附动力学，直到在预定时间段之后达到储存器中的预定最终压力。