HETEROCYCLIC SUBSTITUTED DIHALOISONICOTINICACIDAMIDES FOR PROTECTING PLANTS AGAINST MICROORGANISMS

    公开(公告)号:AU622640B2

    公开(公告)日:1992-04-16

    申请号:AU3114989

    申请日:1989-03-08

    Applicant: CIBA GEIGY AG

    Abstract: Novel substituted isonicotinic acid amides of the general formula in which X in ortho/ortho'-position are equal and represent fluorine, chlorine, bromine or iodine; Q1 is unsubstituted pyridimin-4-yl, or pyrimidin-4-yl substituted by R1, R2 and R3; Q2 is unsubstituted pyrimidin-2-yl, or pyrimidin-2-yl substituted by R1, R2 and R3; Q3 is unsubstituted pyrimidin-5-yl, or pyrimidin-5-yl substituted by R1, R2 and R3; Q4 is pyridin-2-yl, pyridin-3-yl or pyridin-4-yl each of which is unsubstituted or substituted by R1, R2 and R3; Q5 is pyridazin-3-yl or pyridazin-4-yl each of which is unsubstituted or substituted by R1, R2 and R3; Q6 is unsubstituted pyrazin-2-yl, or pyrazin-2-yl substituted by R1, R2 and R3; R1, R2, R3 are hydrogen, halogen, C1-C6alkyl, C1-C6haloalkyl having from 1 to 3 halogen atoms, C1-C6alkoxy, C2-C6alkoxyalkyl, C1-C6thioalkyl, C1-C6haloalkoxy having from 1 to 5 halogen atoms, C3-C6alkenyloxy, C3-C6alkynyloxy, C3-C6thioalkenyl, C3-C6cycloalkyl, C3-C6cycloalkyl substituted by methyl, or nitro, cyano, the radical CH(OR4)2 or COOR4 in which R4 is C1-C4alkyl; also phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl; or phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl each substituted at least once by C1-C3alkyl, C1-C3-alkoxy, C1-C3haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano; and also N(R5)R6 in which R5 and R6, independently of one another, are each C1-C6alkyl; and furthermore piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl, or piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl each substituted by C1-C3alkyl, C1-C3alkoxy, C1-C3haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano. The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

    26.
    发明专利
    未知

    公开(公告)号:BR8901086A

    公开(公告)日:1989-10-31

    申请号:BR8901086

    申请日:1989-03-08

    Applicant: CIBA GEIGY AG

    Abstract: Novel substituted isonicotinic acid amides of the general formula in which X in ortho/ortho'-position are equal and represent fluorine, chlorine, bromine or iodine; Q1 is unsubstituted pyridimin-4-yl, or pyrimidin-4-yl substituted by R1, R2 and R3; Q2 is unsubstituted pyrimidin-2-yl, or pyrimidin-2-yl substituted by R1, R2 and R3; Q3 is unsubstituted pyrimidin-5-yl, or pyrimidin-5-yl substituted by R1, R2 and R3; Q4 is pyridin-2-yl, pyridin-3-yl or pyridin-4-yl each of which is unsubstituted or substituted by R1, R2 and R3; Q5 is pyridazin-3-yl or pyridazin-4-yl each of which is unsubstituted or substituted by R1, R2 and R3; Q6 is unsubstituted pyrazin-2-yl, or pyrazin-2-yl substituted by R1, R2 and R3; R1, R2, R3 are hydrogen, halogen, C1-C6alkyl, C1-C6haloalkyl having from 1 to 3 halogen atoms, C1-C6alkoxy, C2-C6alkoxyalkyl, C1-C6thioalkyl, C1-C6haloalkoxy having from 1 to 5 halogen atoms, C3-C6alkenyloxy, C3-C6alkynyloxy, C3-C6thioalkenyl, C3-C6cycloalkyl, C3-C6cycloalkyl substituted by methyl, or nitro, cyano, the radical CH(OR4)2 or COOR4 in which R4 is C1-C4alkyl; also phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl; or phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl each substituted at least once by C1-C3alkyl, C1-C3-alkoxy, C1-C3haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano; and also N(R5)R6 in which R5 and R6, independently of one another, are each C1-C6alkyl; and furthermore piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl, or piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl each substituted by C1-C3alkyl, C1-C3alkoxy, C1-C3haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano. The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

    27.
    发明专利
    未知

    公开(公告)号:DK146889A

    公开(公告)日:1989-09-26

    申请号:DK146889

    申请日:1989-03-22

    Applicant: CIBA GEIGY AG

    Abstract: Novel substituted isonicotinic acid esters of the general formula in which Y is halogen; X is oxygen or sulfur; Q is C1-C3alkylene, propenylene, C1-C3alkylene mono- or di-substituted by R, or propenylene mono- or di-substituted by R; R is C1-C4alkyl, C1-C4haloalkyl having from 1 to 3 halogen atoms, cyano, C2-C5alkoxycarbonyl, C3-C6cycloalkyl, phenyl, or phenyl substituted by C1-C4alkyl, C1-C4alkoxy, halogen, trifluoromethyl, tricholoromethyl, nitro or by cyano, or benzoyl or benzoyl substituted by C1-C4alkyl, C1-C4alkoxy, trifluoromethyl, trichloromethyl, nitro or by cyano; A is phenyl, biphenyl, phenoxyphenyl, naphthyl, pyridyl, furyl, thienyl, imidazolyl or triazolyl, it being possible for each of these radicals to be unsubstituted or substituted by halogen, C1-C4alkyl, C1-C3alkoxy, C1-C3haloalkoxy having from 1 to 3 halogen atoms, trifluoromethyl, nitro or by cyano; with the proviso (1) that if A is imidazolyl or triazolyl R may not be phenyl or benzoyl, and (2) that A and the R substituent in Q may together contain no more than 3 rings. The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms, such as fungi, bacteria and viruses.

    28.
    发明专利
    未知

    公开(公告)号:PT88307A

    公开(公告)日:1989-06-30

    申请号:PT8830788

    申请日:1988-08-19

    Applicant: CIBA GEIGY AG

    Abstract: A method and composition for the immunization of healthy useful plants against plant diseases containing as active ingredients compounds of formula ydroxy, methyl, methoxy, HOOC or MOOC; Y is hydrogen, halogen, SO3H, SO3M, nitro, hydroxy or amino, M being the molar equivalent of an alkali metal or alkaline earth metal ion that is formed from a corresponding base or basic compound; and Z is cyano or -CO-A; A represents either -OH or -SH, the hydrogen atom of which may also be replaced by the molar equivalent of an inorganic or organic cationic residue, or wherein A represents any other organic residue which has a molecular weight of less than 900 and which may also contain one, or more than one, hetero atom, including the salts of the phytophysiologically tolerable 7-carboxylic acid or 7-thiocarboxylic acid with primary, secondary or tertiary amines or with inorganic bases.

    30.
    发明专利
    未知

    公开(公告)号:BR8802063A

    公开(公告)日:1988-11-29

    申请号:BR8802063

    申请日:1988-04-28

    Applicant: CIBA GEIGY AG

    Inventor: KUNZ WALTER

    Abstract: Novel substituted isonicotinoyl-pyridinyl-hydrazine derivatives of the general formula in which Hal is halogen; R1 is hydrogen, methyl or the radical COR5; R2 is hydrogen, C1-C4-alkyl or one of the radicals COR5 or CO-Z-R6; R3 is hydrogen, halogen, trifluoromethyl, trichloromethyl, COOH, COOCH3, OH or nitro; R4 is hydrogen, halogen, methoxy or methyl; R5 is C1-C6-alkyl, C1-C6-alkyl which is monosubstituted or polysubstituted by halogen, C1-C6-alkyl which is interrupted by oxygen or sulphur, C1-C6-alkyl which is monosubstituted or polysubstituted by halogen and interrupted by oxygen or sulphur, or is C2-C4-alkenyl, C2-C4-alkenyl which is monosubstituted or polysubstituted by halogen, or phenyl, phenyl which is substituted by halogen, methyl, trifluoromethyl or trichloromethyl, benzyl, benzyl which is substituted by halogen, methyl, trifluoromethyl or trichloromethyl, a 5- or 6-membered heterocycle with nitrogen, oxygen or sulphur as hetero atoms, a 3- to 6-membered cycloalkyl or a cycloalkyl which is monosubstituted or polysubstituted by halogen or methyl; R6 is C1-C5-alkyl, phenyl, or, if Z represents the CO group, is OC1-C2-alkyl; and Z is oxygen, sulphur or the CO group. The novel active substances have plant-protecting properties and are suitable, in particular, for the preventive protection of plants against infection with phytopathogenic microorganisms such as fungi, bacteria and fungi.

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