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公开(公告)号:AT98662T
公开(公告)日:1994-01-15
申请号:AT90125475
申请日:1990-12-24
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED DR , GOERL UDO DR , DEUSSER HANS DR
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公开(公告)号:DE4100217A1
公开(公告)日:1992-07-09
申请号:DE4100217
申请日:1991-01-07
Applicant: DEGUSSA
Inventor: GOERL UDO DR , WOLFF SIEGFRIED DR
Abstract: The invention relates to moulding compositions which can be vulcanised with peroxides by the action of heat and contain a thiocyanatopropyltrialkoxysilane, and to a process for their preparation.
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公开(公告)号:DE3820969A1
公开(公告)日:1989-12-28
申请号:DE3820969
申请日:1988-06-22
Applicant: DEGUSSA
Inventor: HELLWIG GEORG DR , STOBER REINHARD DR , KLATTE CHRISTOPH , DESCHLER ULRICH DR , WOLFF SIEGFRIED DR , GOERL UDO DR
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公开(公告)号:HU227776B1
公开(公告)日:2012-02-28
申请号:HU0203554
申请日:2002-10-17
Applicant: EVONIK DEGUSSA GMBH
Inventor: GOERL UDO DR , STOBER REINHARD DR , SCHMITT MATTHIAS
IPC: C08J3/09 , C08J3/12 , C08J3/16 , C08J3/215 , C08K3/00 , C08K3/34 , C08K3/36 , C08K5/00 , C08K9/06 , C08L7/00 , C08L15/00 , C08L21/00 , C08L21/02
Abstract: Preparation of silicate and/or oxygenic filler-containing rubber powder or granulate, based on aqueous rubber emulsion or latex, involves suspension of silicate and/or filler, polysiloxane hydrophobizing agent and nonionic surfactant in water, adjustment of the pH to 2.5-7, separation of the deposited rubber powder from the solid particles, and drying the powdered or granulated product to a moisture content of less than 3%. A process for preparation of silicate and/or oxygenic filler-containing rubber powder or granulate based on aqueous rubber emulsion or latexes involves: (a) suspension of a silicate and/or oxygenic filler, polysiloxane hydrophobizing agent(s) (in amount 0.5-7% relative to the filler) and nonionic surfactant(s) (in amount 0.1-2% relative to the filler) at 10-60 degrees C in water, giving a suspension of density 0.5-5%, (b) addition of the rubber latex emulsion to the filler suspension with stirring, (c) adjustment of the pH of the aqueous mixture with an acid, preferably sulfuric acid or aluminum sulfate to a pH of 2.5-7, (d) separation of the deposited rubber powder from the process water by, for example, solid/liquid separation of the solid particles, (e) molding of the filter cake, and (f) drying of the powdered or granulated product to an end moisture content of less than 3%.
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公开(公告)号:DE50306835D1
公开(公告)日:2007-05-03
申请号:DE50306835
申请日:2003-10-15
Applicant: DEGUSSA
Inventor: SCHMITT MATTHIAS , GOERL UDO DR , STOBER REINHARD DR
Abstract: Continuous production of filled rubber granules comprises introducing an aqueous filler composition and a rubber latex through separate inlets into a reactor with a high-speed stirrer and coagulating the latex by lowering the pH and/or adding a water-soluble Group IIa, IIb, IIIa or VIII metal salt.
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26.
公开(公告)号:SI0819694T1
公开(公告)日:2003-04-30
申请号:SI9730420
申请日:1997-07-02
Applicant: DEGUSSA
Inventor: GOERL UDO DR , LAMBERTZ HORST
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公开(公告)号:DE19544469A1
公开(公告)日:1997-03-27
申请号:DE19544469
申请日:1995-11-29
Applicant: DEGUSSA
Inventor: GOERL UDO DR , LAMBERTZ HORST , WOLFF WILHELM DR
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28.
公开(公告)号:CA2186060A1
公开(公告)日:1997-03-24
申请号:CA2186060
申请日:1996-09-20
Applicant: DEGUSSA
Inventor: GOERL UDO DR , LAMBERTZ HORST , WOLFF WILHELM DR
IPC: B60C1/00 , C08K3/00 , C08K3/04 , C08K3/34 , C08K3/36 , C08K5/00 , C08K5/548 , C08L9/06 , C08K9/06
Abstract: The invention provides a method for the preparation of vulcanisable rubber mixtures containing silicas and organosilane compounds, and these mixtures. The organosilane compounds are of the general formula: (C1-8 alkly -O) 3Si (CH2)3SCN. The mixtures when vulcanised provide mouldings and structural components for tyres having decreased abrasion.
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公开(公告)号:DE19519364A1
公开(公告)日:1996-11-28
申请号:DE19519364
申请日:1995-05-26
Applicant: DEGUSSA
Inventor: DESCHLER ULRICH DR , GOEBEL THOMAS DR , GOERL UDO DR , LAMBERTZ HORST
IPC: C08J5/10 , C07F7/18 , C08K5/54 , C08K5/5419 , C08K5/548 , C08K9/06 , C08L21/00 , C08K3/04 , C08K3/34 , B60C1/00
Abstract: Mixts. of organosilane cpds. of formula (I) and (II) are claimed (M): Ä(RO)3Si(CH2)3SxÜ2 (I) and Ä(R'O)3Si(CH2)y-CH3 (II), where R, R' = 1-8C alkyl (same or different); x = 1-4; and y = 1-19; in amts. of 40-95 wt% (I) and 5-60 wt% (II). Also claimed are vulcanisable moulding materials and rubber mixts. contg. 10-250 pts. silicate filler and 0-150 pts. carbon black to 100 pts. rubber, plus 0.1-20 pts. mixt. (M) to 100 pts. silicate filler.
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公开(公告)号:DE59400068D1
公开(公告)日:1996-02-01
申请号:DE59400068
申请日:1994-09-27
Applicant: DEGUSSA
Inventor: ESCH HEINZ , GOERL UDO DR , KUHLMANN ROBERT , RAUSCH RALF DR
IPC: C01B33/12 , C01B33/187 , C01B33/193 , C08J3/24 , C08K3/00 , C08K3/36 , C08L21/00 , C08L83/04
Abstract: A precipitate of silica having the following physicochemical parameters: BET surface area: from 35 to 350 m /g Ratio of BET/CTAB surface area: from 0.8 to 1.1 Pore volume PV: from 1.6 to 3.4 ml/g Silanol group density (V2 = consumption of NaOH): from 6 to 20 ml Mean aggregate size: from 250 to 1500 nm CTAB surface area: from 30 to 350 m /g DBP number: from 150 to 300 ml/100 g V2/V1 according to Hg porosimetry: from 0.19 to 0.46 DBP/CTAB: from 1.2 to 2.4 is prepared by reacting alkali metal silicate with mineral acids at temperatures of from 60 to 95 DEG C while maintaining a pH of from 7.5 to 10.5 with continuous stirring, continuing the reaction to a solids concentration in the precipitate suspension of from 80 to 120 g/l, adjusting the pH to a value equal to or less than 5, filtering off, washing, drying and, if desired, milling or granulating the precipitated silica. The precipitated silica is used as filler in vulcanisable rubber mixtures and vulcanisates.
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