公开(公告)号：CA582193A

公开(公告)日：1959-08-25

申请号：CA582193D

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

公开(公告)号：CA1004660A

公开(公告)日：1977-02-01

申请号：CA173317

申请日：1973-06-06

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

公开(公告)号：CA806215A

公开(公告)日：1969-02-11

申请号：CA806215D

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

公开(公告)号：CA773578A

公开(公告)日：1967-12-12

申请号：CA773578D

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

公开(公告)号：CA748991A

公开(公告)日：1966-12-20

申请号：CA748991D

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

公开(公告)号：CA652008A

公开(公告)日：1962-11-13

申请号：CA652008D

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

公开(公告)号：CA1084519A

公开(公告)日：1980-08-26

申请号：CA233187

申请日：1975-08-07

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR

IPC: C08K5/00 ,  C08G77/00 ,  C08G77/04 ,  C08G77/06 ,  C08G77/22 ,  C08K5/5419 ,  C08L69/00 ,  C08L83/00 ,  C08L83/04 ,  C07F7/18 ,  C08K5/54

Abstract: Phenyl-containing organopolysiloxane fluids of the formula, wherein Ph is phenyl, r is hydrogen, trimethylsilyl or mixtures thereof and wherein x and y have a value sufficient to provide a phenyl content of from about 7 weight percent to about 80 weight percent as shown. These fluids function as internal mold release additives for thermoplastic polycarbonates.

公开(公告)号：CA995653A

公开(公告)日：1976-08-24

申请号：CA190183

申请日：1974-01-15

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR ,  TRAVER FRANK J

公开(公告)号：CA963911A

公开(公告)日：1975-03-04

申请号：CA116375

申请日：1971-06-23

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR ,  BERGER ABE

IPC: C07F7/02 ,  C07F17/00 ,  C07F17/02 ,  C08G77/22 ,  C08G77/26 ,  C08G77/58 ,  C09B57/00 ,  C10L1/30 ,  G03C5/30

Abstract: 1337311 Organometallocene-polysiloxanes GENERAL ELECTRIC CO 1 July 1971 [20 July 1970] 30824/71 Headings C3S and C3T [Also in Division C5] Novel silylcarbamylorganometallocene polymers having structural units of the formula optionally in admixture with further structural units of the formula wherein R denotes an unsubstituted or halogen-, nitro-, alkoxy- or cyano-substituted monovalent hydrocarbon radical, S denotes an organometallocene radical of the formula W denotes a carbamyl radical, R 11 denotes an alkylene or arylene radical, each Q is chemically bonded to a cyclopentadienyl radical and denotes hydrogen, a monovalent electron-donating organic radical selected from aryl, hydroxyaryl, aliphatic or cycloaliphatic hydrocarbon radicals, nitroaliphatic radicals, carboxyaliphatic radicals and triorganosilyl radicals, or a monovalent electron withdrawing organic radical selected from aliphatic acyl, arylacyl, carboxylic, aldehydic, sulpho, carboxyaryl, nitroaryl, haloaryl and haloaliphatic radicals, provided that at least one Q attached to each cyclopentadienyl radical denotes hydrogen, M denotes a transition metal bonded to two cyclopentadienyl radicals and is Ti, V, Cr, Mn, Fe, Co, Ni, Zr, Cb, Mo, Tc, Ru, Rh, Pd, Hf, Ta, W, Re, Os, Ir or Pt, a denotes 0, 1 or 2 and b denotes 0, 1, 2, or 3, are prepared by hydrolysis of metallocenyl halides of the formula S-W-R 11 -Si(R) a X 3-a optionally in admixture with halosilanes of the formula (R) b -SiX 4-b (wherein X denotes halogen). The metallocenyl halides may themselves be obtained by reacting an organometallocene of the formula SH with an isocyanate halide of the formula OCN-R 11 (R) a SiX) 3-a in the presence of a Lewis acid catalyst. Uses.-As high temperature antioxidants for polysiloxane fluids, particularly dimethylpolysiloxanes used as clutch fluids.

公开(公告)号：CA855789A

公开(公告)日：1970-11-10

申请号：CA855789D

Applicant: GEN ELECTRIC

Inventor： BROWN EDGAR D JR