公开(公告)号：DE3810379A1

公开(公告)日：1989-10-12

申请号：DE3810379

申请日：1988-03-26

Applicant: HOECHST AG

Inventor： SCHUBERT HANS HERBERT DR ,  SALBECK GERHARD DR ,  KRAUSE HANS-PETER DR ,  KNAUF WERNER DR ,  WALTERSDORFER ANNA DR ,  KERN MANFRED DR

IPC: C07D253/06 ,  A01N43/40 ,  A01N55/00 ,  A01N55/10 ,  C07D213/32 ,  C07D213/61 ,  C07D213/64 ,  C07D213/643 ,  C07D213/70 ,  C07D237/12 ,  C07D237/14 ,  C07D237/18 ,  C07D239/26 ,  C07D239/32 ,  C07D239/34 ,  C07D241/16 ,  C07D241/18 ,  C07D257/08 ,  C07D401/12 ,  C07D409/12 ,  C07D491/056 ,  C07F7/10

Abstract: Compounds of the formula I, their optical isomers and mixtures thereof … … in which… M represents C or Si,… R represents unsubstituted or substituted pyridyl, unsubstituted or substituted pyrimidyl, and - when M = C - unsubstituted or substituted pyridazinyl, unsubstituted or substituted pyrazinyl, unsubstituted or substituted 1,2,4-triazinyl, unsubstituted or substituted 1,2,4,5-tetrazinyl,… R , R independently of one another represent alkyl, alkenyl, haloalkyl, phenyl, or R and R represent an alkylene chain which - together with the quaternary central atom (M)- forms an unsubstituted or fluorine-substituted ring having four to six ring members (when M = Si) or having three to six ring members (when M = C),… R represents H, F, -CN, -CCl3, -C IDENTICAL CH, (C1-C4)alkyl, - @ -NH2,… R represents pyridyl, furyl, thienyl, all of which can be substituted, phthalimidyl, dialkylmaleimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl, substituted phenyl,… or R and R - together with the carbon atom linking them - form an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical,… and their salts and quaternisation products have advantageous insecticidal, acaricidal or nematocidal properties.

公开(公告)号：DE3712752A1

公开(公告)日：1988-11-03

申请号：DE3712752

申请日：1987-04-15

Applicant: HOECHST AG

Inventor： SCHUBERT HANS HERBERT DR ,  SALBECK GERHARD DR ,  KRAUSE HANS-PETER DR ,  LUEDERS WALTER DR ,  KNAUF WERNER DR ,  WALTERSDORFER ANNA DR ,  KERN MANFRED DR

IPC: C07D253/06 ,  A01N43/40 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N55/10 ,  A01P7/02 ,  A01P7/04 ,  C07D213/61 ,  C07D213/63 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/70 ,  C07D237/12 ,  C07D237/14 ,  C07D237/18 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D241/16 ,  C07D241/18 ,  C07D253/07 ,  C07D253/08 ,  C07D257/08 ,  C07D401/06 ,  C07D401/08 ,  C07D401/12 ,  C07D409/06 ,  C07D409/08 ,  C07D491/04 ,  C07D491/056 ,  C07D213/60 ,  C07D247/00 ,  A01N43/48 ,  A01N43/707 ,  A01N43/713 ,  A01N43/90 ,  C07F7/08

Abstract: Compounds of the formula (I) and their stereoisomers (I) wherein A, B, C' and D independently of one another denote CH or N, in which at least one of the symbols A, B, C' or D must correspond to a nitrogen atom, X denotes CH2 or oxygen, R1 denotes a radical bonded to a carbon atom from the series comprising H, trialkylsilyl, halogen, nitro, cyano, alkenyl, alkynyl, amino, cycloalkyl, phenyl, phenxy, alkoxy, alkenyloxy, alkynyloxy, hydroxycarbonyl, alkylthio, cycloalkyloxy, alkylcarbonyl, alkoxycarbonyl, alkenyloxycarbonyl, alkynyloxycarbonyl, halogenoalkyl, alkoxyalkyl, halogenoalkoxy, halogenoalkylthio, halogenoalkoxyalkyl, alkylthioalkyl, alkoxyalkoxy, halogenoalkoxyalkoxy, alkenyloxyalkoxy, halogenoalkenyloxy, alkoxyalkylthio, alkylthioalkoxy, alkylthioalkylthio, halogenoalkoxycarbonyl, halogenoalkenyloxycarbonyl or dialkylamino or two radicals R1 when they are positioned ortho to one another together denote a methylenedioxy, ethylenedioxy or alkylene radical, R2 and R3 independently of one another denote alkyl, alkenyl or phenyl, or R2 and R3 denote an alkylene chain which-together with the quaternary carbon atom-forms an unsubstituted or fluorinesubstituted ring having three to six ring members, R4 denotes -H, F, -CN, -CCl3, -C 3BOND CH, (C1-C4)alkyl, -C-NH2, S R5 denotes pyridyl, furyl or thienyl which can all be substituted, phthalimidyl, dialkylmaleimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl or substituted phenyl, or R4 and R5-together with the carbon atom bridging them-denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical and n denotes 0, 1 or 2, possess advantageous properties for combating pests, in particular insects and acarids. Furthermore, processes for the preparation of compounds of the formula I are described.

公开(公告)号：DE3629269A1

公开(公告)日：1988-03-10

申请号：DE3629269

申请日：1986-08-28

Applicant: HOECHST AG

Inventor： SALBECK GERHARD DR ,  SCHLICHT RAINER

IPC: C07F9/24

Abstract: The invention relates to a process for the preparation of alkylamidothiophosphate salts of the formula I in which R and R denote alkyl and R denotes hydrogen or alkyl, in which process a compound of the formula II is reacted with potassium hydroxide at elevated temperatures.d

公开(公告)号：DE3505432A1

公开(公告)日：1986-08-21

申请号：DE3505432

申请日：1985-02-16

Applicant: HOECHST AG

Inventor： KRATT GUENTER DR ,  SALBECK GERHARD DR ,  BONIN WERNER DR ,  BAUER KLAUS DR ,  BIERINGER HERMANN DR ,  SACHSE BURKHARD DR

IPC: C07D277/32 ,  C07D277/54 ,  A01N43/78 ,  A01N43/84 ,  C07D295/22 ,  C07D417/00

Abstract: The present invention relates to agents for controlling insect pests, fungal pests, acarids and undesired vegetation, which agents contain an effective amount of a compound of the formula I in which R and R independently of one another represent H, (substituted) alkyl, (substituted) alkenyl, (substituted) alkynyl, alkoxy, alkylsulphonyl, alkylcarbonyl, cyano, (substituted) phenylsulphonyl, (substituted) phenylcarbonyl, (substituted) phenyl, a 5- to 6-membered heterocyclic ring which can contain a fused benzene ring, dialkylamino in which the two alkyl radicals can form a 5- to 7-membered ring with the adjacent N atom, which ring can contain, as a ring element, an additional hetero atom selected from the group comprising O, S, NH or N-(C1-C4)alkyl, and X represents halogen, or their salts, with the proviso that, in the event that R = phenyl or a substituted phenyl radical, R must not be tertiary (C4-C12)alkyl, cyano or (C1-C4)alkoxy, and, in the event that R = phenyl or a substituted phenyl radical, R must not be dialkylamino which can be cyclised.

公开(公告)号：DE2740450A1

公开(公告)日：1979-03-22

申请号：DE2740450

申请日：1977-09-08

Applicant: HOECHST AG

Inventor： SALBECK GERHARD DR ,  KOCH MANFRED DR ,  WALTERSDORFER ANNA DR ,  BONIN WERNER DR

IPC: A01N57/06 ,  C07F9/165 ,  C07F9/24 ,  C07F9/40 ,  C07F9/17 ,  A01N9/36

Abstract: Cpds. of formula (I) are new:- (where R = 1-4C alkyl, halo-(1-4C alkyl) and/or halogen; n = 1,2 or 3; R1 =1-4C alkoxy or di (1-4C alkyl)amino; R2 = 1-4C alkyl, 1-2C alkoxy, 1-4C alkylamino, di(1-4C alkyl)amino or 3-5C alkenylamino; R3 = 1-4C alkyl; and X = o or S). When adult female ticks of the species Boophilus microplus are immersed for 5 mins. in a 0.5% or 0.25% dispersion of (I; (R)n =2,4-Cl2, R1 = NMe2, R2 = Et, R3 = Et, X=S), egg-laying is completely inhibited.

公开(公告)号：DE2725361A1

公开(公告)日：1978-12-14

申请号：DE2725361

申请日：1977-06-04

Applicant: HOECHST AG

Inventor： STUDENEER ADOLF DR ,  SALBECK GERHARD DR ,  KUEBEL BOERRIES DR

IPC: C07D213/80 ,  C07D491/04 ,  C07D491/048

Abstract: Furo(3,2-C)pyridine derivs. of formula (Ia) and their 3-oxoltautomers of formula (Ib) and their salts with strong acids or bases are new. In (I), R1 is 1-3C alkyl, 1-3C alkoxy or phenyl; R2 is CH3; R3 is H, Cl or Br; R4 is H, 1-6C alkyl, 5-7C cycloalkyl, CN, -CO-R5, -COOR6, -CONR7R8, p-NO2,-C6H4-, or benzyl opt. substd. (pref. mono- or disubstd.) in the ring by 1-4C alkyl, halogen, 1-3C alkoxy, methylenedioxy and/or di(1-4C alkyl)amino; R5 is CH3, or phenyl opt. substd. by NO2 and/or Cl; R6 is 1-4C alkyl; R7 is H or 1-3C alkyl; and R8 is H 1-3C alkyl, or phenyl opt. substd. by halogen, CF3 and/or CH3; or R7+R8 is 4-5C methylene chain opt. interrupted by O, S, NH or N-(1-4C alkyl). (I) are useful as intermediates, e.g. for plant protection agents (esp. phosphorus esters obtd. by reacting alkali salts of (Ia, b) with phosphorus halides such as phosphoric acid diester halides).

公开(公告)号：DE2432635A1

公开(公告)日：1976-01-22

申请号：DE2432635

申请日：1974-07-06

Applicant: HOECHST AG

Inventor： STUDENEER ADOLF DR ,  SALBECK GERHARD DR ,  EMMEL LUDWIG DR ,  KNAUF WERNER DR

IPC: A01N47/18 ,  A01P7/04 ,  C07D213/89 ,  C07D215/60 ,  C07D491/056

公开(公告)号：DE2426851A1

公开(公告)日：1976-01-02

申请号：DE2426851

申请日：1974-06-04

Applicant: HOECHST AG

Inventor： SALBECK GERHARD DR

IPC: C07D215/22 ,  C07D215/233 ,  C07D215/38 ,  C07D215/52 ,  C07D215/56 ,  C07D219/06 ,  C07D221/12

Abstract: of formula (I): (where R1 and R2 are H, 1-4C alkyl, COOH, 2-5C alkoxycarbonyl, or together form (CH2)n, where n = 3-5; R3-R6 are H, 1-6 C alkyl, 5-6C cycloalkyl, 1-4C alkoxy, mono- or di-(1-4C alkyl) amino or halomethyl, or R3 + R4 R4 + R5 or R5 + R6 forms (CH2)n) are prepd. by hydrogenating the corresp. quinolin-4(1H)-one of formula (II): (where R1-R6 are as above, or R1 + R2, R3 + R4 or R5 + R6 can form CH:CHCH:CH) at 20-180 degrees C and 30-200 atm. in an inert org. solvent in the presence of an Ni catalyst. Cpds. (I) are useful as inters. for pesticides (see DT 2361438). The process gives high yields (e.g. >90%) of high-purity prods. without the use of expensive Pt catalysts.

公开(公告)号：DE2236118A1

公开(公告)日：1974-02-14

申请号：DE2236118

申请日：1972-07-22

Applicant: HOECHST AG

Inventor： SALBECK GERHARD DR ,  HOERLEIN GERHARD DR ,  EMMEL LUDWIG DR ,  BONIN WERNER DR

IPC: C07F9/6571 ,  C07F9/40

公开(公告)号：DE4213149A1

公开(公告)日：1993-10-28

申请号：DE4213149

申请日：1992-04-22

Applicant: HOECHST AG

Inventor： KUHN BIRGIT DR ,  SALBECK GERHARD DR ,  DOELLER UWE DR ,  SCHNATTERER STEFAN DR ,  SCHUBERT HANS-HERBERT DR ,  KNAUF WERNER DR ,  WALTERSDORFER ANNA DR ,  KERN MANFRED

IPC: C07D239/26 ,  A01N35/10 ,  A01N37/32 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/32 ,  A01N43/36 ,  A01N43/40 ,  A01N43/54 ,  A01N43/74 ,  A01N43/78 ,  A01N43/82 ,  C07C251/48 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07D207/333 ,  C07D207/34 ,  C07D213/53 ,  C07D213/61 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/74 ,  C07D213/76 ,  C07D213/78 ,  C07D261/06 ,  C07D263/08 ,  C07D277/22 ,  C07D277/32 ,  C07D307/42 ,  C07D307/79 ,  C07D317/58 ,  C07D333/22 ,  C07D333/62 ,  C07D401/12 ,  C07D405/12 ,  C07D417/12 ,  C07D213/60 ,  C07D213/24 ,  C07D239/28 ,  C07D409/12 ,  A61K31/505

Abstract: Compounds have the formula (I), in which Ar and Ar stand for aryl or heteroaryl, which may be substituted, and R stands for a possibly substituted aliphatic or alicyclic residue. Also disclosed are a process for preparing the same, an agent containing the same and its use for controlling animal pests.