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公开(公告)号:DE59008346D1
公开(公告)日:1995-03-09
申请号:DE59008346
申请日:1990-10-05
Applicant: HOECHST AG
Inventor: FREYER WALTER DR , MILTENBERGER KARLHEINZ DR , SCHMIDT MANFRED
Abstract: In the conversion of trichloroethene and tetrachloroethene into dichloroacetyl chloride (DAC) or trichloroacetyl chloride (TAC) by means of oxygen, the reaction mixture is passed several times as a thin film through the reaction zone. The reaction time for achieving a certain conversion is in this way reduced. In the preparation of DAC, a constant content of acid chloride is established in the reaction mixture by removing some of the mixture and working this up by distillation, while the circulating reaction mixture is simultaneously topped up with fresh trichloroethene. In this way, side reactions are suppressed and the amount of by-products is reduced.
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公开(公告)号:HUT55743A
公开(公告)日:1991-06-28
申请号:HU711290
申请日:1990-11-13
Applicant: HOECHST AG
Inventor: FREYER WALTER , MILTENBERGER KARLHEINZ , SCHMIDT MANFRED
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公开(公告)号:HU906533D0
公开(公告)日:1991-04-29
申请号:HU653390
申请日:1990-10-24
Applicant: HOECHST AG
Inventor: MILTENBERGER KARLHEINZ , SCHMIDT MANFRED , PETZ KARL
IPC: B01J27/053 , B01J27/125 , B01J31/02 , C07B61/00 , C07C67/08 , C07C67/54 , C07C67/58 , C07C69/02 , C07C69/63
Abstract: In the esterification of aliphatic C2-C6-carboxylic acids with aliphatic C1-C4-alcohols, the ester formed is distilled off azeotropically together with the water of reaction. After being separated from the water of reaction in a separation cooler, the ester phase is freed from entrained acid by scrubbing with water, and water and alcohol are then removed by distilling off a small portion of the ester. In this manner, no salt-containing waste water is formed. The ester is obtained in very good yield and free of acid and alcohol.
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公开(公告)号:HU906346D0
公开(公告)日:1991-04-29
申请号:HU634690
申请日:1990-10-05
Applicant: HOECHST AG
Inventor: FREYER WALTER , MILTENBERGER KARLHEINZ , SCHMIDT MANFRED
Abstract: In the conversion of trichloroethene and tetrachloroethene into dichloroacetyl chloride (DAC) or trichloroacetyl chloride (TAC) by means of oxygen, the reaction mixture is passed several times as a thin film through the reaction zone. The reaction time for achieving a certain conversion is in this way reduced. In the preparation of DAC, a constant content of acid chloride is established in the reaction mixture by removing some of the mixture and working this up by distillation, while the circulating reaction mixture is simultaneously topped up with fresh trichloroethene. In this way, side reactions are suppressed and the amount of by-products is reduced.
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公开(公告)号:NO892785L
公开(公告)日:1990-01-08
申请号:NO892785
申请日:1989-07-05
Applicant: HOECHST AG
Inventor: MILLER DENNIS , SCHMIDT MANFRED , HALASZ SIGMAR-PETER VON , HOLST ARNO , PUSCH GUENTER , ROSENTHAL GERHARD
Abstract: Aqueous surfactant compositions containing a surfactant mixture of a) 55 to 85% by weight of an alkanesulphonate, petroleumsulphonate, olefinsulphonate or alkylbenzenesulphonate having a mean molecular weight of 280-400 and b) 15 to 45% by weight of an ether sulphonate of the formula RO(AO)mA'SO3M where R is C6-C20-alkyl or a phenyl group which is substituted by one to three alkyl groups having a total of 6 to 20 carbon atoms, A is a C2H4 or C3H6 group or a mixture of the two groups, A' is -C2H4- or -C3H6-, m is a number of 3 to 25, and M is an alkali metal atom or ammonium. These surfactant mixtures are suitable for tertiary oil recovery in combination with specific salt-stable copolymers based on polyarylamide. They form stable solutions or dispersions with highly saline water.
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公开(公告)号:NO892785A
公开(公告)日:1990-01-08
申请号:NO892785
申请日:1989-07-05
Applicant: HOECHST AG
Inventor: MILLER DENNIS , SCHMIDT MANFRED , HALASZ SIGMAR-PETER VON , HOLST ARNO , PUSCH GUENTER , ROSENTHAL GERHARD
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公开(公告)号:NO874426D0
公开(公告)日:1987-10-23
申请号:NO874426
申请日:1987-10-23
Applicant: HOECHST AG
Inventor: SCHMIDT MANFRED , RUPP WALTER , SCHEIDER GERHART , KOHN EVA MARIA
IPC: C07C309/04 , C07C309/09 , C09K8/584 , E21B43/22 , C07C , E21B43/00
Abstract: Styrylaryloxy ether sulfonates of the formula in which either R1 denotes styryl and simultaneously R2 and R3 are identical or different and denote hydrogen or styryl, or R1 and R2 are nonidentical and each denote methyl or styryl and simultaneously R3 denotes hydrogen or styryl, x denotes a number from 2 to 20, and M denotes an ammonium or alkali metal cation. These compounds are suitable as surfactant auxiliaries in oil recovery.
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公开(公告)号:DK173690B1
公开(公告)日:2001-06-25
申请号:DK584489
申请日:1989-11-21
Applicant: HOECHST AG
Inventor: FLEMMING HANS-WOLFRAM , RUKWIED MANFRED , SCHMIDT MANFRED
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公开(公告)号:CA1335493C
公开(公告)日:1995-05-09
申请号:CA614545
申请日:1989-09-29
Applicant: HOECHST AG
Inventor: FLEMMING HANS-WOLFRAM , RUKWIED MANFRED , SCHMIDT MANFRED
Abstract: A process for the preparation of tripeptides A process for the preparation of tripeptides of the general formula I U - A - B - C - OH I in which U denotes hydrogen or a urethane protective group and A, B and C denote amino acids, by reaction of a compound of the general formula II U' - B - OH II in which U' is a urethane protective group which can be eliminated by hydrogenolysis, with a compound of the general formula III H - C - OR III in which R denotes alkyl, by the PPA method, elimination of U', reaction of the resulting compound with a compound of the general formula IV H - B - C - OR IV by the PPA method and subsequent enzymatic elimination of R. The tripeptides are intermediates used in the synthesis of bioactive peptides.
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公开(公告)号:DE59008800D1
公开(公告)日:1995-05-04
申请号:DE59008800
申请日:1990-11-10
Applicant: HOECHST AG
Inventor: FREYER WALTER DR , MILTENBERGER KARLHEINZ DR , SCHMIDT MANFRED
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