公开(公告)号：ZA896305B

公开(公告)日：1990-05-30

申请号：ZA896305

申请日：1989-08-18

Applicant: HOECHST AG

Inventor： SCHWAB MICHAEL ,  MICHAEL SCHWAB ,  WALZ GERD ,  GERD WALZ

IPC: C08G18/08 ,  C08G18/12 ,  C08G18/28 ,  C08G18/65 ,  C09D175/00 ,  C09D175/04 ,  C09D ,  B05D

Abstract: Use of a water-dispersible polymer as binder in an aqueous filler composition which may or may not comprise, in addition to other polymeric binders, crosslinking agents and the customary additives, wherein the water-dispersible polymer is a polyurethane resin which contains building blocks derived from (A) polyisocyanates, (B) polyols having an average molecular weight Mn of at least 400, (C) low-molecular polyols if desired and, (D) compounds containing at least two groups reactive toward isocyanate groups and at least one group capable of forming anions, and (E) compounds which are monofunctional or contain active hydrogen of variable reactivity, these building blocks being always positioned at the chain end fo the polyurethane resin, and optionally (F) compounds which are other than (B), (C), (D) and (E) and contain at least two groups reactive toward NCO groups. The crosslinked filler coatings obtainable therefrom are distinguished, inter alia, by improved stone-chip resistance at low temperatures and by good intercoat adhesion.

公开(公告)号：NO308955B1

公开(公告)日：2000-11-20

申请号：NO931090

申请日：1993-03-24

Applicant: HOECHST AG

Inventor： SCHWAB MICHAEL ,  FRANK UDO ,  WALZ GERD

IPC: C09D175/04 ,  C08G18/08 ,  C08G18/10 ,  C08G18/12 ,  C09D5/34 ,  C09D175/00 ,  D21H19/00

Abstract: A water-dilutable (water-thinnable) two-component coating composition containing a) a polyisocyanate component comprising one or more organic polyisocyanates, and b) a polyurethane resin prepared by 1. reacting (A) polyisocyanates with (B) polyols having a mean molecular weight Mn of at least 400, (C) optionally low-molecular-weight polyols and (D) compounds containing at least two groups which are reactive towards isocyanate groups and at least one group which is capable of anion formation, to give a prepolymer containing free NCO groups, and 2. reacting the prepolymer formed in step 1 with at least one of the components: (E) low-molecular-weight polyols carrying no further groups which are reactive towards isocyanate groups, these compounds being employed in excess, (F) compounds which are monofunctional or contain active hydrogen of different reactivity and are different from (E), and optionally (G) compounds which are different from (B), (C), (D), (E) and (F) and contain at least two groups which are reactive with NCO groups. r

公开(公告)号：CZ283991B6

公开(公告)日：1998-07-15

申请号：CS371992

申请日：1992-12-17

Applicant: HOECHST AG

Inventor： EXNER REINER ,  SCHWAB MICHAEL ,  KUHN UTE ,  ZOELLER JOACHIM

IPC: C08L67/00 ,  C08G63/68 ,  C08G63/688 ,  C08G63/692 ,  C09D167/00

Abstract: An aqueous filler composition containing a polyester resin which is built up from the starting materials (a), (b), (c), (d) and (e) or ester-forming derivatives thereof, where the sum of the reactants corresponds to 100 mol% and the ratio between the sum of the hydroxyl equivalents (eq of OH) and the sum of the carboxyl equivalents in the reactants is between 0.5 and 2.0, where (a) is at least one dicarboxylic acid which is not a sulpho or phosphorus monomer, (b) from 0 to 15 mol% of at least one difunctional sulpho or phosphono monomer whose functional groups are carboxyl or hydroxyl groups, containing at least one sulphonate or phosphonate group, (c) at least one difunctional compound which is derived from a glycol containing two -C(R)2-OH groups, (d) up to 40 mol% of a higher-functional compound (functionality > 2) whose functional groups comprise hydroxyl and/or carboxyl groups, and (e) from 0 to 20 mol% of a monofunctional carboxylic acid, where the radicals R in (c) may be, independently of one another, hydrogen, C1-C4-alkyl or C6-C10-aryl, the amounts of free hydroxyl groups are between 30 and 350 milliequivalents of OH/100 g, preferably between 100 and 250 meq of OH/100 g, and the content of free neutralised and/or neutralisable acid groups, in particular sulphonic, phosphonic or carboxyl groups, is between 5 and 350 meq of acid groups/100 g, preferably between 9 and 120 meq of acid groups/100 g.

公开(公告)号：AU663398B2

公开(公告)日：1995-10-05

申请号：AU4467993

申请日：1993-08-18

Applicant: HOECHST AG

Inventor： SCHWAB MICHAEL ,  ZOELLER JOACHIM

IPC: C08G18/42 ,  C08G18/08 ,  C08G18/46 ,  C08G63/06 ,  C08G63/16 ,  C08G63/60 ,  C08G63/688 ,  C08G63/692 ,  C09D5/02 ,  C09D175/04 ,  C09D175/06 ,  C09D175/00 ,  C09D167/03 ,  C09D167/04

Abstract: Water-dilutable (water-thinnable), two-component coating composition containing 1) a polyisocyanate component and 2) a polyester resin built up from the starting materials (a), (b), (c), (d) and (e) or ester-forming derivatives thereof, where the ratio between the total of the hydroxyl equivalents and the total of the carboxyl equivalents in the reactants is between 1:0.5 and 1:2.0, where (a) is at least one dicarboxylic acid which is not a sulphomonomer, (b) is from 0 to 15 mol% of at least one difunctional sulpho or phosphonomonomer whose functional groups are carboxyl and/or hydroxyl groups, containing at least one sulphonate or phosphonate group, (c) is at least one glycol, (d) is from 0 to 40 mol% of a higher-functional compound (functionality > 2) whose functional groups comprise hydroxyl and/or carboxyl groups, and (e) is from 0 to 20 mol% of a monofunctional carboxylic acid, where the amounts of free hydroxyl groups are between 30 and 350 milliequivalents of OH/100 g, and the content of free neutralised and/or neutralisable acid groups is between 5 and 350 meq/100 g. These coating compounds are particularly suitable for the production of primers, fillers, topcoats and single-coat finishes.

公开(公告)号：BR9303417A

公开(公告)日：1994-03-15

申请号：BR9303417

申请日：1993-08-18

Applicant: HOECHST AG

Inventor： SCHWAB MICHAEL ,  ZOELLER JOACHIM

IPC: C08G18/42 ,  C08G18/08 ,  C08G18/46 ,  C08G63/06 ,  C08G63/16 ,  C08G63/60 ,  C08G63/688 ,  C08G63/692 ,  C09D5/02 ,  C09D175/04 ,  C09D175/06 ,  C09D167/00

Abstract: Water-dilutable (water-thinnable), two-component coating composition containing 1) a polyisocyanate component and 2) a polyester resin built up from the starting materials (a), (b), (c), (d) and (e) or ester-forming derivatives thereof, where the ratio between the total of the hydroxyl equivalents and the total of the carboxyl equivalents in the reactants is between 1:0.5 and 1:2.0, where (a) is at least one dicarboxylic acid which is not a sulphomonomer, (b) is from 0 to 15 mol% of at least one difunctional sulpho or phosphonomonomer whose functional groups are carboxyl and/or hydroxyl groups, containing at least one sulphonate or phosphonate group, (c) is at least one glycol, (d) is from 0 to 40 mol% of a higher-functional compound (functionality > 2) whose functional groups comprise hydroxyl and/or carboxyl groups, and (e) is from 0 to 20 mol% of a monofunctional carboxylic acid, where the amounts of free hydroxyl groups are between 30 and 350 milliequivalents of OH/100 g, and the content of free neutralised and/or neutralisable acid groups is between 5 and 350 meq/100 g. These coating compounds are particularly suitable for the production of primers, fillers, topcoats and single-coat finishes.

公开(公告)号：NO932933D0

公开(公告)日：1993-08-18

申请号：NO932933

申请日：1993-08-18

Applicant: HOECHST AG

Inventor： SCHWAB MICHAEL ,  ZOELLER JOACHIM

IPC: C08G18/42 ,  C08G18/08 ,  C08G18/46 ,  C08G63/06 ,  C08G63/16 ,  C08G63/60 ,  C08G63/688 ,  C08G63/692 ,  C09D5/02 ,  C09D175/04 ,  C09D175/06 ,  C09D

Abstract: Water-dilutable (water-thinnable), two-component coating composition containing 1) a polyisocyanate component and 2) a polyester resin built up from the starting materials (a), (b), (c), (d) and (e) or ester-forming derivatives thereof, where the ratio between the total of the hydroxyl equivalents and the total of the carboxyl equivalents in the reactants is between 1:0.5 and 1:2.0, where (a) is at least one dicarboxylic acid which is not a sulphomonomer, (b) is from 0 to 15 mol% of at least one difunctional sulpho or phosphonomonomer whose functional groups are carboxyl and/or hydroxyl groups, containing at least one sulphonate or phosphonate group, (c) is at least one glycol, (d) is from 0 to 40 mol% of a higher-functional compound (functionality > 2) whose functional groups comprise hydroxyl and/or carboxyl groups, and (e) is from 0 to 20 mol% of a monofunctional carboxylic acid, where the amounts of free hydroxyl groups are between 30 and 350 milliequivalents of OH/100 g, and the content of free neutralised and/or neutralisable acid groups is between 5 and 350 meq/100 g. These coating compounds are particularly suitable for the production of primers, fillers, topcoats and single-coat finishes.

公开(公告)号：CA2084737A1

公开(公告)日：1993-06-22

申请号：CA2084737

申请日：1992-12-07

Applicant: HOECHST AG

Inventor： EXNER REINER ,  KLEIN HEINZ-PETER ,  SCHWAB MICHAEL ,  WALZ GERD ,  FRANK UDO

IPC: C08G18/08 ,  C08G18/42 ,  C08G18/46 ,  C08G18/80 ,  C09D167/00 ,  C09D175/00 ,  C09D175/06 ,  C09J175/06 ,  C08L75/06

Abstract: 91/F 397 Water-dilutable, urethane-modified and hydroxyl groupcontaining self-crosslinking binder and formulations thereof Water-dilutable, urethane-modified and hydroxyl groupcontaining binder, prepared by reaction of a polyester containing hydroxyl groups and neutralized and/or neutralizable acid groups with substoichiometric amounts (with respect to the number of free hydroxyl groups) of a partially blocked polyisocyanate. These binders are suitable for the production of coating films and other coatings of this type.

公开(公告)号：MX9207460A

公开(公告)日：1993-06-01

申请号：MX9207460

申请日：1992-12-18

Applicant: HOECHST AG

Inventor： EXNER REINER ,  KLEIN HEINZ-PETER ,  SCHWAB MICHAEL ,  WALZ GERD ,  FRANK UDO

IPC: C08G18/08 ,  C08G18/42 ,  C08G18/46 ,  C08G18/80 ,  C09D167/00 ,  C09D175/00 ,  C09D175/06 ,  C09J175/06

公开(公告)号：NO924924D0

公开(公告)日：1992-12-18

申请号：NO924924

申请日：1992-12-18

Applicant: HOECHST AG

Inventor： EXNER REINER ,  SCHWAB MICHAEL ,  KUHN UTE ,  ZOELLER JOACHIM

IPC: C08L67/00 ,  C08G63/68 ,  C08G63/688 ,  C08G63/692 ,  C09D167/00 ,  C09D

Abstract: An aqueous filler composition containing a polyester resin which is built up from the starting materials (a), (b), (c), (d) and (e) or ester-forming derivatives thereof, where the sum of the reactants corresponds to 100 mol% and the ratio between the sum of the hydroxyl equivalents (eq of OH) and the sum of the carboxyl equivalents in the reactants is between 0.5 and 2.0, where (a) is at least one dicarboxylic acid which is not a sulpho or phosphorus monomer, (b) from 0 to 15 mol% of at least one difunctional sulpho or phosphono monomer whose functional groups are carboxyl or hydroxyl groups, containing at least one sulphonate or phosphonate group, (c) at least one difunctional compound which is derived from a glycol containing two -C(R)2-OH groups, (d) up to 40 mol% of a higher-functional compound (functionality > 2) whose functional groups comprise hydroxyl and/or carboxyl groups, and (e) from 0 to 20 mol% of a monofunctional carboxylic acid, where the radicals R in (c) may be, independently of one another, hydrogen, C1-C4-alkyl or C6-C10-aryl, the amounts of free hydroxyl groups are between 30 and 350 milliequivalents of OH/100 g, preferably between 100 and 250 meq of OH/100 g, and the content of free neutralised and/or neutralisable acid groups, in particular sulphonic, phosphonic or carboxyl groups, is between 5 and 350 meq of acid groups/100 g, preferably between 9 and 120 meq of acid groups/100 g.

公开(公告)号：NO923263D0

公开(公告)日：1992-08-20

申请号：NO923263

申请日：1992-08-20

Applicant: HOECHST AG

Inventor： BRINDOEPKE GERHARD ,  KURTH INGE ,  SCHWAB MICHAEL ,  WALZ GERD

IPC: C08F290/00 ,  C08F299/02 ,  C08G18/67 ,  C09D4/02 ,  C09D11/10 ,  C09D161/20 ,  C09D175/14 ,  C09D175/16 ,  C08G

Abstract: Curable binders obtained by simultaneous reaction of A) urethanes or ureas, B) acrylic or methacrylic compounds containing hydroxyl groups, C) paraformaldehyde and D) if appropriate, polyols, wherein, in the case where no polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger, and in the case where a polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger or a strong acid. These binders are suitable as coating compositions which can be cured by electron beams or by UV light.