公开(公告)号：JPH01268704A

公开(公告)日：1989-10-26

申请号：JP9750688

申请日：1988-04-20

Applicant: KAO CORP

Inventor： MURAI OSAMU ,  RAKUTOKU YUMI ,  YAMADA HIROYUKI

IPC: C08F2/26 ,  B01F17/52 ,  C08F8/36 ,  C08F12/00 ,  C08F12/30

Abstract: PURPOSE:To provide a dispersing agent for emulsion polymerization, composed of a polystyrenesulfonic acid salt having a specific sulfonation degree and produced by the sulfonation of a polystyrene having a specific average molecular weight, and capable of improving the stability of produced latex without obstructing the polymerization reaction. CONSTITUTION:The objective dispersing agent for emulsion polymerization useful in the production of e.g. a synthetic rubber latex or synthetic resin emulsion is composed of a polystyrenesulfonic acid salt having a sulfonation degree of 0.45-0.75 and produced by the sulfonation of a polystyrene having an average molecular weight of 1,000-100,000 determined by GPC method. In the case of using said dispersing agent for emulsion polymerization, for example, 60-500 pts.wt. of water, 0.5-10pts.wt. of a surfactant or seed for emulsion polymerization and 0.5-10pts.wt. of the above dispersing agent for emulsion polymerization are used based on 100pts.wt. of the monomer (e.g. styrene or methyl acrylate).

公开(公告)号：JPS63193943A

公开(公告)日：1988-08-11

申请号：JP2752087

申请日：1987-02-09

Applicant: TAKEDA CHEMICAL INDUSTRIES LTD ,  KAO CORP

Inventor： KAMATANI YOSHIO ,  TSUJI MASAAKI ,  MURAI OSAMU

IPC: C08L21/00 ,  C08L21/02 ,  C08L61/14 ,  C09J121/00 ,  C09J121/02

Abstract: PURPOSE:To obtain a latex composition useful for the production of dipped rubber product, foam rubber artificial leather, carpet, etc., by compounding a specific amount of an alkylene oxide adduct of an alkylphenol-formalin condensate to a synthetic rubber latex. CONSTITUTION:(A) 100pts.wt. of a synthetic rubber latex, e.g. an emulsion of a copolymer containing styrene-butadiene, acrylonitrile-butadiene, etc., is compounded with (B) 0.1-5pts., preferably 0.1-2pts. of an alkylene oxide adduct of an alkylphenol-formalin condensate, preferably a compound produced by adding 50-500mol. of ethylene oxide and propylene oxide in total to a condensation product of formalin and a p-alkylphenol having 3-12C alkyl group. The latex has excellent blister resistance even under severe condition and has excellent age-stability of adhesivity and viscosity when used as a backing adhesive for carpet.

公开(公告)号：JPS6153309A

公开(公告)日：1986-03-17

申请号：JP17444184

申请日：1984-08-22

Applicant: Kao Corp

Inventor： MURAI OSAMU ,  MORIYAMA NOBORU

IPC: C08F2/00 ,  C08F2/22 ,  C08F2/24 ,  C08F2/26 ,  C08F2/28 ,  C08F12/12 ,  C08F212/00 ,  C08F212/12

CPC classification number: C08F12/12

Abstract: PURPOSE: To obtain the titled copolymer having improved heat resistance, being blended with ABS to give a resin useful as parts of cars and light electrical appliances, by using a substituted succinic acid (salt) obtained by reacting an unsaturated dicarboxylic acid (anhydride) with an alkene as a surface active agent.
CONSTITUTION: (A) 4W12C α,β-unsaturated carboxylic acid (anhydride) such a maleic anhydride, fumaric acid, etc. and (B) 8W40C alkene such as an α-olefin, internal olefin, etc. are subjected to addition reaction in a solvent or in the absence of a solvent at normal temperature W 300°C, and, if necessary, hydrogenated, to give a substituted succinic acid (or salt) containing an alkenyl or alkyl group, which is used as a surface active agent. Preferably 0.1W10pts.wt. of the surface active agent is added to (C) 100pts.wt. mixture of copolymerizable monomers such as acrylonitrile, etc. containing 1W50wt% α-methylstyrene, which is subjected to emulsion polymerization by the use of a radical initiator, to give the aimed copolymer.
COPYRIGHT: (C)1986,JPO&Japio

Abstract translation: 目的：为了获得具有改善的耐热性的标题共聚物，与ABS共混以得到可用作汽车和轻型电器零件的树脂，通过使用通过使不饱和二羧酸（酸酐）与 烯烃作为表面活性剂。 构成：（A）将4-12Cα，β-不饱和羧酸（酸酐）如马来酸酐，富马酸等和（B）8-40C烯如α-烯烃，内烯烃等进行 在溶剂中或在不存在溶剂的情况下在常温-30℃下进行加成反应，如果需要，进行氢化，得到含有烯基或烷基的取代的琥珀酸（或盐），其用作 表面活性剂。 优选0.1-10pts.wt。 的表面活性剂加入（C）100pts.wt。 含有1-50wt％α-甲基苯乙烯的可共聚单体如丙烯腈等的混合物，其通过使用自由基引发剂进行乳液聚合，得到目的共聚物。

公开(公告)号：JPH03269001A

公开(公告)日：1991-11-29

申请号：JP7146590

申请日：1990-03-19

Applicant: KAO CORP

Inventor： MURAI OSAMU ,  HORIO YASUNORI

IPC: B01F17/52 ,  C08F2/26 ,  C08F2/30 ,  C08F220/04 ,  C08F246/00

Abstract: PURPOSE:To obtain the title surfactant providing an emulsion having excellent water resistance and adhesivity of coating film by copolymerizing an unsaturated monomer containing carboxyl group, sulfonic group or polyalkylene oxide group with a comonomer having a specific glass transition temperature. CONSTITUTION:(A) 7-35 pts.wt. unsaturated monomer (e.g. 2-acrylamido-2 methylpropanesulfonic acid) containing carboxyl group, sulfonic group, a polyalkylene oxide group, etc., is copolymerized with (B) 93-65 pts.wt. one or more unsaturated monomers (e.g. ethyl acrylate) which are copolymerizable with the component A and comprise >=70wt.% monomers having

公开(公告)号：JPH03103458A

公开(公告)日：1991-04-30

申请号：JP23961689

申请日：1989-09-14

Applicant: KAO CORP

Inventor： MURAI OSAMU

IPC: C08J5/18 ,  C08L27/12

Abstract: PURPOSE:To obtain the subject anti-mist agent usable to PVC resin, ethylene- vinyl acetate copolymer or polyolefin, etc., without using a large amount of expensive fluorine monomer containing fluorine-containing resin having core-shell double layered structure distributing fluorine-containing resin in shell part. CONSTITUTION:20-99.8wt.% vinyl-based monomer is subjected to seed polymerization in the presence of 0.2-80wt.% (solid content) aqueous emulsion having 0.001-0.2mu average particle diameter composed of fluorine-containing resin containing 5-95wt.% fluorine-containing monomer unit to afford the aimed anti- mist agent containing fluorine-containing resin particles having core-shell double layered structure in which fluorine-containing resin is distributed in the shell part.

公开(公告)号：JPH0379678A

公开(公告)日：1991-04-04

申请号：JP21573989

申请日：1989-08-22

Applicant: KAO CORP

Inventor： MURAI OSAMU

IPC: C09D11/00 ,  C09D11/30

Abstract: PURPOSE:To provide the title composition excellent in quick dryability, printing quality (blur, contour sharpness, clearness, durability) and nozzle delivery stability, containing an emulsion of ultrafine particles. CONSTITUTION:The objective composition containing pref. 5-20wt.%, on a solid basis, of an emulsion of ultrafine particles 50-300Angstrom in average size. The solid concentration for the emulsion is pref. 20-30wt.%.

公开(公告)号：JPH02147601A

公开(公告)日：1990-06-06

申请号：JP29549188

申请日：1988-11-22

Applicant: KAO CORP

Inventor： SAKAI TAKEYA ,  MURAI OSAMU ,  HAYASHI HIROMITSU ,  RAKUTO YUMI

IPC: C08L27/12 ,  C08F2/04 ,  C08F2/06 ,  C08F6/10 ,  C08F8/00 ,  C08F14/18 ,  C08F16/14 ,  C08F16/16 ,  C08F20/22 ,  C08F20/32 ,  C08F214/18 ,  C08F216/14 ,  C08F216/16 ,  C08F220/22 ,  C08F220/32

Abstract: PURPOSE:To obtain an aq. emulsion of a resin with no foambility, high surface tension and excellent water resistance by adding water to a reaction product obtd. by soln.-polymerizing a monomer mixture contg. a specified monomer and a fluorinated monomer and distilling a solvent out. CONSTITUTION:A monomer mixture consisting of 0.5-60wt.% monomer (A) having a salt-forming group or a polyalkylene oxide group and a radical- polymerizable double bond, 5-99.5wt.% fluorinated monomer (B) having a radical- polymerizable double bond and 0-94.5wt.% monomer (C) which is different from monomers (A) and (B) and has a radical-polymerizable double bond is soln.- polymerized in an alcohol or ketone solvent. After, if necessary, a neutralizing agent is added to the obtd. reaction product, water is added thereto and the alcohol or ketone solvent is distilled out therefrom to obtain an aimed aq. emulsion.

公开(公告)号：JPH02132101A

公开(公告)日：1990-05-21

申请号：JP13173189

申请日：1989-05-25

Applicant: KAO CORP

Inventor： SAKAI TAKEYA ,  MURAI OSAMU ,  HAYASHI HIROMITSU ,  RAKUTOKU YUMI

IPC: C08F2/06 ,  C08F2/04 ,  C08F2/22 ,  C08F259/08 ,  C09D5/00 ,  C09D5/02 ,  D06M15/327

Abstract: PURPOSE:To obtain the title dispersion of high surface tension with reduced foaming, and high water resistance and high water and oil repulsion, by seed polymerization of vinyl monomers in the presence of an aqueous emulsion of a fluorine-containing resin of fine particle size. CONSTITUTION:The seed polymerization of vinyl monomers such as (meth)- acrylates, vinyl esters, or vinyl ethers in an amount of 20 to 99.8wt.% is conducted in the presence of an aqueous emulsion of a fluorine-containing resin containing 5 to 95wt.% of fluorine containing monomer units in which emulsion particles have an average size of 0.001 to 0.2mu preferably 0.001 to 0.05mu in an amount of 0.2 to 80wt.% based on the solid parts to give the subject dispersion. The aqueous emulsion is preferably produced by copolymerizing a radically polymerizable, unsaturated fluorine-containing monomer, a surface active vinyl monomer in an alcohol or ketone solvent, combining the product with water and distilling off the solvent.

公开(公告)号：JPS63193901A

公开(公告)日：1988-08-11

申请号：JP2752187

申请日：1987-02-09

Applicant: KAO CORP

Inventor： MURAI OSAMU ,  SENOO MASAMICHI ,  HAYASHI HIROMITSU

IPC: C08C1/15 ,  C08C1/00 ,  C08L21/02 ,  C09J121/02

Abstract: PURPOSE:To obtain the titled gelling agent, consisting of an alkylene oxide adduct of an alkylphenol-formalin condensate and capable of efficiently gelatinizing a latex without impairing performance thereof. CONSTITUTION:The aimed gelling agent obtained by initially heating an alkylphenol having preferably a 1-30C alkyl group and formalin in the presence of an acid or alkali catalyst in a solvent to provide a condensate having preferably 2-20 average condensation degree, reacting the above-mentioned condensate with an alkylene oxide, preferably ethylene oxide and propylene oxide used together so as to provide 90-450mol. total number of added mol. in the presence of an alkali catalyst to give an alkylene oxide adduct of the alkylphenol-formalin condensate having preferably 20-70 deg.C cloud point and, as necessary, blending a surfactant, etc., therewith. Furthermore, 0.1-3pts.wt. afore-mentioned gelling agent is added to 100pts.wt. latex.

公开(公告)号：JPS59227903A

公开(公告)日：1984-12-21

申请号：JP10349483

申请日：1983-06-09

Applicant: KAO CORP

Inventor： MURAI OSAMU ,  MORIYAMA NOBORU

IPC: C08F2/00 ,  C08F2/24

Abstract: PURPOSE:To obtain an emulsion capable of forming a film which is exempt from deterioration of water resistance, adhesion, strength, etc., by emulsion-polymerizing an ethylenically unsaturated monomer in the presence of a specified surfactant for emulsion polymerization. CONSTITUTION:100pts.wt. ethylenically unsaturated monomer (e.g., styrene) is mixed with 5-20pts.wt. surfactant for emulsion polymerization of the formula (wherein R1 is alkyl or alkenyl, R2 is alkylene or alkenylene, the total number of carbon atoms of R1 and R2 is 6-28, and X is an alkali metal, ammonium or an organic amine group) and 80-200pts.wt. water, and the mixture is emulsion- polymerized in an atmosphere of nitrogen in the presence of a radical polymerization initiator and, optionally, a chain transfer agent, etc.