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公开(公告)号：DE3565987D1
公开(公告)日：1988-12-08
申请号：DE3565987
申请日：1985-08-14
Applicant: KAO CORP
Inventor： MURAI OSAMU , MORIYAMA NOBORU
IPC: C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/28 , C08F12/12 , C08F212/00 , C08F212/12
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公开(公告)号：JPH041276A
公开(公告)日：1992-01-06
申请号：JP10232290
申请日：1990-04-17
Applicant: KAO CORP
Inventor： MURAI OSAMU , SAKAI TAKEYA
Abstract: PURPOSE:To obtain the title material used for a covering sheet or the like by using a foam obtained by foaming a composition comprising a synthetic resin emulsion in a specific condition. CONSTITUTION:An opacifying coating material comprises a foam obtained by mechanically foaming a composition comprising a synthetic resin emulsion such as an emulsion comprising i-butyl methacrylate, methyl methacrylate and methacrylic acid.
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公开(公告)号：JPH03269184A
公开(公告)日：1991-11-29
申请号：JP6478090
申请日：1990-03-15
Applicant: KAO CORP
Inventor： FUKUYAMA YUKIHIRO , MURAI OSAMU , SAKAI TAKEYA
Abstract: PURPOSE:To obtain wall paper having excellent stain resistance by coating a substrate sheet with a blend containing an aqueous dispersion of fluorine- containing resin to form a protective coating film. CONSTITUTION:A substrate sheet (e.g. wall paper processed with polyvinyl chloride) is coated with a composition of an aqueous dispersion of fluorine- containing resin blended with colloidal silica, etc., heat-treated and a protective coating film of the composition is formed to give wall paper having excellent stain resistance. The aqueous dispersion of fluorine-containing resin is obtained by copolymerizing an aqueous emulsion comprising a fluorine-containing resin having 5-95wt.% fluorine containing monomer with a vinyl monomer and is an aqueous dispersion of resin particles having double structure wherein a fluorine-containing resin is distributed in the shell part.
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公开(公告)号：JPH0649018A
公开(公告)日：1994-02-22
申请号：JP5340992
申请日：1992-03-12
Applicant: KAO CORP
Inventor： YAMADA HIROYUKI , MURAI OSAMU , YOKOTA YUKINAGA
IPC: C07C303/20 , C07C309/18
Abstract: PURPOSE:To obtain a sulfosuccinic acid monoamide having low smell and low irritation in reacting a maleic acid monoamide prepared from maleic anhydride and a primary amine with a sulfonating agent by carrying out a specific reaction process under a specified condition. CONSTITUTION:Maleic anhydride is reacted with a primary amine of the formula RNH2 (R is 8-22C straight-chain or branched-chain alkyl or alkenyl) to give a maleic acid monoamide of formula I (first process). Then the maleic acid monoamide is reacted with a sulfonating agent (alkali metal sulfite, alkali metal hydroxide or alkanolamine-containing alkali metal acidic sulfite) to give a sulfosuccinic acid monoamide of formula II [A and E are H or SO3M (M is cation and A and E are neither H nor SO3M at the same time)] (second process. In the first process, the amine is added to maleic anhydride melted at
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公开(公告)号：JPH01110518A
公开(公告)日：1989-04-27
申请号：JP26757087
申请日：1987-10-22
Applicant: KAO CORP
Inventor： MURAI OSAMU , SAKAI TAKEYA
IPC: C08F291/00 , C08F2/16 , C08F2/18
Abstract: PURPOSE:To obtain the above dispersion having moderate rate of polymerization, low frothing tendency, high surface tension and excellent water-resistance, by carrying out radical polymerization of a monomer containing polymerizable unsaturated bond in the presence of a specific polymer emulsion. CONSTITUTION:The objective dispersion is produced by the radical polymerization of (A) 99.8-97wt.% of a monomer containing polymerizable unsaturated bond (e.g., acrylic acid) in the presence of (B) 0.2-3wt.% (solid basis) of a polymer emulsion composed of a polymer of an ethylenic or conjugated diene unsaturated monomer and having an average particle diameter of 0.001-0.03mum. The component B is preferably a self-dispersing aqueous resin emulsion free from surfactant and obtained by phase-inversion process. Said emulsion can be produced by carrying out solution polymerization of a monomer having a polymerizable double bond and containing a salt-forming group with a copolymerizable monomer in an alcohol solvent, adding water to the obtained copolymer and distilling out the solvent.
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Patent Agency Ranking
公开(公告)号：JPH01110506A
公开(公告)日：1989-04-27
申请号：JP26757187
申请日：1987-10-22
Applicant: KAO CORP
Inventor： MURAI OSAMU , SAKAI TAKEYA
IPC: C08F2/30
Abstract: PURPOSE:To obtain an aqueous resin dispersion useful as an ink, paper processing agent, etc., by carrying out radical polymerization of a monomer having polymerizable unsaturated bond in the presence of a urethane emulsion having a specific average particle diameter. CONSTITUTION:An aqueous resin dispersion having a moderate rate of polymerization, low frothing tendency, high surface tension and excellent water-resistance can be produced by the radical polymerization of 97-99.8wt.% of a monomer having polymerizable unsaturated bond (e.g., acrylic acid, hydroxyethyl acrylate or acrylonitrile) in the presence of 0.2-3wt.% of one or more urethane emulsions having an average particle diameter of 0.001-0.035mum and preferably in the presence of a polymerization catalyst such as potassium persulfate or di-tert-butyl hydroperoxide.
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公开(公告)号：JPH01104601A
公开(公告)日：1989-04-21
申请号：JP26332587
申请日：1987-10-19
Applicant: KAO CORP
Inventor： HAYASHI HIROMITSU , MARUYAMA TETSUSHI , MURAI OSAMU
Abstract: PURPOSE:To efficiently coagulate a polymer in latex and to efficiently recover the polymer having low contents of metal and surface activator, by blending a polymer latex prepared by emulsion polymerization with a nonionic activator and heating. CONSTITUTION:A polymer latex (e.g. acrylonitrile-butadiene-styrene copolymer) prepared by emulsion polymerization is blended with a nonionic activator having 0-100 deg.C cloud point and >=1,000mol.wt. as a coagulant, heated to >= the cloud point of the activator, the polymer in the polymer latex is coagulated and recovered. An organopolysiloxane-polyoxyalkylene copolymer or an adduct of an (alkyl)phenol with a polyoxyalkylene is preferable as the nonionic activator. The recovered polymer has low metallic corrosive properties and hardly causes corrosion of devices.
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公开(公告)号：JPH06248070A
公开(公告)日：1994-09-06
申请号：JP3978493
申请日：1993-03-01
Applicant: KAO CORP
Inventor： IWAHASHI MASAAKI , MURAI OSAMU
Abstract: PURPOSE:To produce an adduct of a polyoxyalkylene hardly being colored even in air under heating. CONSTITUTION:In producing an adduct of a polyoxyalkylene by adding an active hydrogen-containing compound to an alkylene oxide in the presence of an alkali catalyst, 0.002-0.02mol of the alkali catalyst is used based on 1mol of active hydrogen of the active hydrogen-containing compound to give the objective adduct of a polyoxyalkylene hardly being colored under heating.
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公开(公告)号：JPH05295313A
公开(公告)日：1993-11-09
申请号：JP8077792
申请日：1992-04-02
Applicant: KAO CORP
Inventor： MURAI OSAMU , SAKAI TAKEYA , TANIGUCHI TAKAO
Abstract: PURPOSE:To obtain the objective vehicle having very good heat resistance and satisfactory adhesiveness, water resistance and blocking resistance. CONSTITUTION:This vehicle is obtained by blending nitrocellulose and a chelating agent with a polyamide resin which is prepared by condensation of constituents comprising a polymeric fatty acid, a polyamide and, if necessary, a monocarboxylic acid or nomoamine and has a viscosity (25 deg.C) of 180-1000cp in the form of a 35wt.% solution thereof in a mixture of toluene and isopropanol in a weight ratio of 2:1.
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公开(公告)号：JPH02308843A
公开(公告)日：1990-12-21
申请号：JP13173289
申请日：1989-05-25
Applicant: KAO CORP
Inventor： MURAI OSAMU , HAYASHI HIROMITSU , IWASAKI MASANORI
IPC: C08L27/12 , C09D127/12 , C09D127/16
Abstract: PURPOSE:To obtain the subject composition, containing a fluorine-containing resin aqueous dispersion with a shell substance having a two-layer structure composed of a fluorine-containing resin, excellent in weather, water resistance, water repellency, etc., and suitable for coating metal materials, woody materials, etc., of household appliances, general machines, etc. CONSTITUTION:A composition obtained by homogeneously copolymerizing 5-95wt.% fluorine-containing monomer units with 5-60wt.% surface-active vinyl monomer units and 0-90wt.% other monomer units having radically polymerizable unsaturated bonds in an organic solvent, then, as necessary, adding a neutralizing agent thereto, subsequently removing the solvent, carrying out seed polymerization of 20-99.5wt.% vinylic monomer in the presence of 0.5-80wt.% resultant self-dispersible type aqueous resin emulsion having 0.005-0.2mu average particle diameter and blending the obtained fluorine-containing resin aqueous dispersion with a shell substance having a two-layer structure composed of the fluorine-containing resin.
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