Preparation of pentachlorophenol
    21.
    发明专利

    公开(公告)号:GB2234971A

    公开(公告)日:1991-02-20

    申请号:GB9015161

    申请日:1990-07-10

    Abstract: Pentachlorophenol is prepared by the chlorination of dichlorophenols and trichlorophenols, using gaseous chlorine in the presence of an effective amount of a zirconium, hafnium, tellurium, antimony, niobium or aluminium halide or one of their precursors, until tetrachlorophenol is predominantly formed and then adding an effective amount of aluminium halide in order to obtain the pentachlorophenol. Pentachlorophenol is used as a fungicide and as a wood preservative.

    26.
    发明专利
    未知

    公开(公告)号:DE69609806T2

    公开(公告)日:2001-03-15

    申请号:DE69609806

    申请日:1996-02-14

    Abstract: PCT No. PCT/FR96/00241 Sec. 371 Date Oct. 16, 1996 Sec. 102(e) Date Oct. 16, 1996 PCT Filed Feb. 14, 1996 PCT Pub. No. WO96/26175 PCT Pub. Date Aug. 29, 1996The subject of the present invention is a process for the preparation of a 4-hydroxybenzaldehyde carrying at least one substituent in the position ortho to the OH group. It more particularly relates to the preparation of 3-methoxy-4-hydroxybenzaldehyde and of 3-ethoxy-4-hydroxybenzaldehyde. The process for the preparation of a substituted 4-hydroxybenzaldlehyde, substituted at least in the 3 position by an alkoxy group, is characterized in that it comprises subjecting a substituted phenol compound, substituted at least in the 2 position by an alkoxy group and in which the 4 and 6 positions are free, to a first stage of carboxylation in the 6 position, then to a stage of hydroxymethylation in the 4 position, followed by a stage of oxidation of the hydroxymethyl group to a formyl group, and finally to a last decarboxylation stage.\!

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