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公开(公告)号:GB2234971A
公开(公告)日:1991-02-20
申请号:GB9015161
申请日:1990-07-10
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , JOUVE ISABELLE
IPC: C07C37/62
Abstract: Pentachlorophenol is prepared by the chlorination of dichlorophenols and trichlorophenols, using gaseous chlorine in the presence of an effective amount of a zirconium, hafnium, tellurium, antimony, niobium or aluminium halide or one of their precursors, until tetrachlorophenol is predominantly formed and then adding an effective amount of aluminium halide in order to obtain the pentachlorophenol. Pentachlorophenol is used as a fungicide and as a wood preservative.
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公开(公告)号:FR2634759B1
公开(公告)日:1990-11-02
申请号:FR8810534
申请日:1988-07-29
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , JOUVE ISABELLE
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公开(公告)号:FR2626274B1
公开(公告)日:1990-05-04
申请号:FR8800910
申请日:1988-01-27
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , JOUVE ISABELLE
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公开(公告)号:FR2618144B1
公开(公告)日:1989-11-24
申请号:FR8710417
申请日:1987-07-17
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN , BESSON BERNARD , JOUVE ISABELLE
IPC: B01J31/02 , C07B39/00 , C07B61/00 , C07C27/00 , C07C37/62 , C07C39/27 , C07C39/32 , C07C67/00 , C07C67/287 , C07C69/157
Abstract: A process for the chlorination, using gaseous chlorine, of phenolic compounds substituted in an ortho position relative to the hydroxyl function group. More precisely, it is a process for the chlorination of these phenolic compounds in the molten state or in a solvent medium, using gaseous chlorine, in the presence of an organic cation. The process is applicable especially to the chlorination of 2,6- dichlorophenol to 2,4,6-trichlorophenol.
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公开(公告)号:FR2626275A1
公开(公告)日:1989-07-28
申请号:FR8800911
申请日:1988-01-27
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , JOUVE ISABELLE
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公开(公告)号:DE69609806T2
公开(公告)日:2001-03-15
申请号:DE69609806
申请日:1996-02-14
Applicant: RHONE POULENC CHIMIE
Inventor: METIVIER PASCAL , JOUVE ISABELLE , MALIVERNEY CHRISTIAN
IPC: B01J27/053 , C07B61/00 , C07C45/65 , C07C45/67 , C07C47/575 , C07C47/58 , C07C51/15 , C07C51/353 , C07C51/367 , C07C51/373 , C07C65/21
Abstract: PCT No. PCT/FR96/00241 Sec. 371 Date Oct. 16, 1996 Sec. 102(e) Date Oct. 16, 1996 PCT Filed Feb. 14, 1996 PCT Pub. No. WO96/26175 PCT Pub. Date Aug. 29, 1996The subject of the present invention is a process for the preparation of a 4-hydroxybenzaldehyde carrying at least one substituent in the position ortho to the OH group. It more particularly relates to the preparation of 3-methoxy-4-hydroxybenzaldehyde and of 3-ethoxy-4-hydroxybenzaldehyde. The process for the preparation of a substituted 4-hydroxybenzaldlehyde, substituted at least in the 3 position by an alkoxy group, is characterized in that it comprises subjecting a substituted phenol compound, substituted at least in the 2 position by an alkoxy group and in which the 4 and 6 positions are free, to a first stage of carboxylation in the 6 position, then to a stage of hydroxymethylation in the 4 position, followed by a stage of oxidation of the hydroxymethyl group to a formyl group, and finally to a last decarboxylation stage.\!
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公开(公告)号:DE68901469D1
公开(公告)日:1992-06-17
申请号:DE68901469
申请日:1989-01-16
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , JOUVE ISABELLE
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公开(公告)号:CA1301194C
公开(公告)日:1992-05-19
申请号:CA572164
申请日:1988-07-15
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , BESSON BERNARD , JOUVE ISABELLE
IPC: C07C41/22 , B01J31/02 , C07B39/00 , C07B61/00 , C07C37/62 , C07C39/27 , C07C43/23 , C07C51/363 , C07C65/03 , C07C67/307 , C07C69/63 , C07C69/88 , C07C205/59 , C07C231/00 , C07C233/25 , C07C233/33 , C07C233/43 , C07C233/54 , C07C255/53 , C07C201/12
Abstract: L'invention concerne un procédé de chloration sélective en position ortho par rapport à la fonction hydroxyle, de composés phénoliques de formule générale (I): (I) dans laquelle: R2 représente: un atome d'halogène; un groupement alkyle ayant 1 à 4 atomes de carbone; un groupement alkoxy ayant 1 à 4 atomes de carbone; un groupement acyloxy ayant 2 à 4 atomes de carbone; un groupement acyle ayant 2 à 4 atomes de carbone; un groupement acide carboxylique; un groupement ester -COOR5, R5 représentant un radical alkyle linéaire ou ramifié ayant de 1 à 4 atomes de carbone; un groupement nitrile; un groupement OH; un groupement -CHO; un groupement -NO2; un groupement acétamido; -R1 représente un atome d'hydrogène ou possède l'une des significations indiquées pour R2; -R3 et R4, identiques ou différents, représentent un atome d'hydrogène ou un atome ou groupement tel que ceux représentés par R2; en milieu fondu, par le chlore gazeux, caractérisé en ce que l'on opère en présence d'une quantité efficace d'au moins un cation organique. Ce procédé est applicable notamment à la chloration du dichloro-2,4 phénol en mélange avec le dichloro-2,6 phénol.
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公开(公告)号:DE3866806D1
公开(公告)日:1992-01-23
申请号:DE3866806
申请日:1988-07-13
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , BESSON BERNARD , JOUVE ISABELLE
IPC: C07C41/22 , B01J31/02 , C07B39/00 , C07B61/00 , C07C37/62 , C07C39/27 , C07C43/23 , C07C51/363 , C07C65/03 , C07C67/307 , C07C69/63 , C07C69/88 , C07C205/59 , C07C231/00 , C07C233/25 , C07C233/33 , C07C233/43 , C07C233/54 , C07C255/53
Abstract: Selective chlorination, using gaseous chlorine, of phenolic compounds, in an ortho position relative to the hydroxyl functional group. More precisely, a process for the selective chlorination in an ortho position relative to the hydroxyl functional group of phenolic compounds, using gaseous chlorine in a molten medium and in the presence of an organic cation. The process is applicable especially to the chlorination of 2,4- dichlorophenol as a mixture with 2,6-dichlorophenol.
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公开(公告)号:FR2636942B1
公开(公告)日:1990-11-09
申请号:FR8812713
申请日:1988-09-23
Applicant: RHONE POULENC CHIMIE
Inventor: DESMURS JEAN-ROGER , JOUVE ISABELLE
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