公开(公告)号：FR2305424A1

公开(公告)日：1976-10-22

申请号：FR7608665

申请日：1976-03-25

Applicant: STANDARD OIL CO

Inventor： WHITE JAMES FERGUSON ,  REGE JAMES ROBERT ,  GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ

IPC: B01J27/198 ,  B01J23/30 ,  B01J23/34 ,  B01J23/652 ,  B01J23/68 ,  B01J23/88 ,  B01J23/888 ,  B01J27/00 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04 ,  B01J27/18 ,  C07C51/26

公开(公告)号：FR2279706A1

公开(公告)日：1976-02-20

申请号：FR7522660

申请日：1975-07-21

Applicant: STANDARD OIL CO

Inventor： GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ ,  HARDMAN HARLEY FOCH

IPC: B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/02 ,  B01J27/192 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C27/14 ,  C07C47/20 ,  C07C57/00 ,  B01J23/00

Abstract: 1523141 Oxidation catalyst STANDARD OIL CO 15 July 1975 [22 July 1974 5 Aug 1974] 29589/75 Heading B1E [Also in Division C2] An oxidation catalyst used for the preparation of unsaturated aldehydes (see Division C2) formula wherein X is Ce, Th, Pr, Nb, Ge, Y, Zr, Ru, Ga, In, Cu, La, Ta, Sb or mixtures thereof; A is alkali metal or Tl or mixture thereof; D is Ni, Co, Mg, Mn, Zn, Cd, Ca, Sr or mixture thereof, except that D is not Mn unless X is Sb; E is P; As, B, S, Al or mixture thereof; a is greater than O but less than S; b and d are 0-4 except that b is not zero if X is Ga, In, La, Nb, Ge or Ta; c, f and g are 0.1-12; and X is a positive number. The catalyst may be supported, e.g. on alumina, silica, titania, zirconia or silicon carbide. The Examples relate to silicasupported catalysts formed by mixing a silica sol with solutions of compounds of the elements to be present, evaporating and calcining.

公开(公告)号：BR9805660A

公开(公告)日：2000-04-11

申请号：BR9805660

申请日：1998-12-04

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV DHANARAJ ,  PAPARIZOS CHRISTOS ,  SEELY MICHAEL J ,  DRENSKI TAMA LEE ,  FRIEDRICH MARIA STRADA

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/64 ,  B01J23/88 ,  B01J23/92 ,  B01J27/057 ,  B01J27/192 ,  B01J38/00 ,  B01J38/68 ,  B01J38/66

Abstract: A process for regenerating molybdenum containing ammoxidation catalyst comprising replacing the molybdenum loss from the catalyst during the ammoxidation reaction wherein ammonium dimolybdenum is utilized as the source for replacement of the molybdenum loss from the original catalyst.

公开(公告)号：RO115333B1

公开(公告)日：2000-01-28

申请号：RO9801345

申请日：1998-08-31

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV DHANARAJ ,  PAPARIZOS CHRISTOS ,  SEELY MICHAEL J ,  FRIEDRICH MARIA STRADA ,  DRENSKI TAMA LEE

IPC: B01J23/00 ,  B01J23/31 ,  B01J23/76 ,  B01J23/84 ,  B01J23/843 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/192 ,  B01J27/199 ,  B01J37/00 ,  B01J37/08 ,  C01C3/02 ,  C01G53/00 ,  C07B61/00 ,  C07C253/18 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08 ,  B01J23/78

Abstract: The invention relates to a catalyst composition used for preparing acrylonitrile and hydrocyanic acid based on oxides of iron, bismuth, molybdenum and calcium, which comprises, on an inert carrier selected from oxides of silicon, aluminium, zirconium or mixtures thereof, an oxide complex having the following empirical formula: A a B b C c D d Fe e Bi f Mo 12 O x, where A represents one or more elements selected from Li, Na, K, Rb, Cs or mixtures thereof, B represents one or more elements selected from Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures thereof, C represents one or more elements selected from Ce, Cr, Al, Sb, P, Ge, La, Sn, V, W or mixtures thereof, D represents one or more elements selected from Ca, Sr, Ba, or mixtures thereof, and a, b, c, d, e, f and x are coefficients, where a=001 to 10; b and e=1010; c, d and f=01 to 50 and x is a number determined by the conditions imposed by the valence of the other elements

公开(公告)号：SG65779A1

公开(公告)日：1999-06-22

申请号：SG1998002982

申请日：1998-08-12

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV DHANARAJ ,  PAPARIZOS CHRISTOS ,  SEELY MICHAEL J ,  FRIEDRICH MARIA STRADA ,  DRENSKI TAMA LEE

IPC: B01J23/00 ,  B01J23/31 ,  B01J23/76 ,  B01J23/84 ,  B01J23/843 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/192 ,  B01J27/199 ,  B01J37/00 ,  B01J37/08 ,  C01C3/02 ,  C01G53/00 ,  C07B61/00 ,  C07C253/18 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08 ,  B01J23/18 ,  B01J23/04

Abstract: A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum and calcium and characterized by the following empirical formula:         A a B b C c D d Fe e Bi f Mo 12 O x    whereA =one or more of Li, Na, K, Rb and Cs or mixtures thereofB =one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures thereofC =one or more of Ce, Cr, Al, Sb, P, Ge, La, Sn, V and W or mixtures thereofD =one or more of Ca, Sr, Ba or mixtures thereofanda = 0.01 to 1.0; b and e = 1.0 - 10;c, d, and f = 0.1 to 5.0 and x is a number determined by the valence requirements of the other elements present.

公开(公告)号：ZA987256B

公开(公告)日：1999-02-15

申请号：ZA987256

申请日：1998-08-13

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV DHANARAJ ,  PAPARIZOS CHRISTOS ,  SEELY MICHAEL J ,  FRIEDRICH MARIA STRADA ,  DRENSKI TAMA LEE

IPC: B01J23/00 ,  B01J23/31 ,  B01J23/76 ,  B01J23/84 ,  B01J23/843 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/192 ,  B01J27/199 ,  B01J37/00 ,  B01J37/08 ,  C01C3/02 ,  C01G53/00 ,  C07B61/00 ,  C07C253/18 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08 ,  B01J

Abstract: A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum and calcium and characterized by the following empirical formula:         A a B b C c D d Fe e Bi f Mo 12 O x    whereA =one or more of Li, Na, K, Rb and Cs or mixtures thereofB =one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures thereofC =one or more of Ce, Cr, Al, Sb, P, Ge, La, Sn, V and W or mixtures thereofD =one or more of Ca, Sr, Ba or mixtures thereofanda = 0.01 to 1.0; b and e = 1.0 - 10;c, d, and f = 0.1 to 5.0 and x is a number determined by the valence requirements of the other elements present.

公开(公告)号：MX159067A

公开(公告)日：1989-04-14

申请号：MX19199282

申请日：1982-03-26

Applicant: STANDARD OIL CO OHIO

Inventor： GRASELLI ROBERT KARL ,  SURESH DEV DHANARAJ ,  JOSEPH ROBERT

IPC: C07C27/14 ,  B01J21/08 ,  B01J23/00 ,  B01J23/18 ,  B01J23/843 ,  B01J27/057 ,  B01J27/14 ,  B01J32/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/35 ,  C07C47/22 ,  C07C67/00 ,  C07C253/00 ,  C07C253/18 ,  C07C255/08 ,  B01J27/132

Abstract: A slurry process for producing a fluid-bed catalyst comprising an antimonate-based oxide complex supported on a catalyst support in which (1) source compounds containing all of the elements of said oxide complex and said support material are combined to form a pre-catalyst slurry, (2) the liquid removed from said pre-catalyst slurry to form a pre-catalyst, and (3) said pre-catalyst is heated at elevated temperature to form said catalyst, in which the support material combined with the source compounds in step (1) is composed of (a) a fumed catalyst support material, such as fumed silica, and (b) a catalyst support material sol, such as a silica sol. The pro-catalyst slurry is formed without the addition of a slurry-derived solid containing fumed catalyst support material and one or more of the source compounds. The process is preferably a single slurry process. The catalyst produced has improved catalytic properties and attrition resistance.

公开(公告)号：IN158093B

公开(公告)日：1986-08-30

申请号：IN104DE1982

申请日：1982-02-09

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ ,  TAGATA ROBERT JOSEPH ,  FORCE GRAY EDWARD

IPC: C07C27/14 ,  B01J21/08 ,  B01J23/00 ,  B01J23/18 ,  B01J23/843 ,  B01J27/057 ,  B01J27/14 ,  B01J32/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/35 ,  C07C47/22 ,  C07C67/00 ,  C07C253/00 ,  C07C253/18 ,  C07C255/08 ,  B01J11/06 ,  B01J11/28

Abstract: A slurry process for producing a fluid-bed catalyst comprising an antimonate-based oxide complex supported on a catalyst support in which (1) source compounds containing all of the elements of said oxide complex and said support material are combined to form a pre-catalyst slurry, (2) the liquid removed from said pre-catalyst slurry to form a pre-catalyst, and (3) said pre-catalyst is heated at elevated temperature to form said catalyst, in which the support material combined with the source compounds in step (1) is composed of (a) a fumed catalyst support material, such as fumed silica, and (b) a catalyst support material sol, such as a silica sol. The pro-catalyst slurry is formed without the addition of a slurry-derived solid containing fumed catalyst support material and one or more of the source compounds. The process is preferably a single slurry process. The catalyst produced has improved catalytic properties and attrition resistance.

公开(公告)号：DE3270713D1

公开(公告)日：1986-05-28

申请号：DE3270713

申请日：1982-02-15

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA STRADA ,  GRASSELLI ROBERT KARL ,  SURESH DEV DHANARAJ

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/051 ,  B01J27/057 ,  B01J27/19 ,  C07C5/48 ,  C07C45/34 ,  C07C51/25 ,  C07C51/00 ,  C07C120/14

公开(公告)号：IN157646B

公开(公告)日：1986-05-10

申请号：IN105DE1982

申请日：1982-02-09

Applicant: STANDARD OIL CO OHIO

Inventor： FRIEDRICH MARIA STRADA ,  SURESH DEV DHANARAJ ,  GRASSELLI ROBERT KARL

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/053 ,  B01J27/057 ,  B01J27/192 ,  B01J11/06 ,  B01J11/46 ,  C07C11/12 ,  C07B3/00

Abstract: An element selected from Groups IA, IB, IIB, IIIA and IIIB is incorporated into an iron bismuth molybdate oxide complex catalyst by impregnation.