公开(公告)号：DE69209462D1

公开(公告)日：1996-05-02

申请号：DE69209462

申请日：1992-10-30

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  WAGNER DAVID RUDOLPH ,  BLUM PATRICIA RAE

IPC: B01J23/36 ,  B01J27/195 ,  C07B61/00 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.

公开(公告)号：AT136017T

公开(公告)日：1996-04-15

申请号：AT92309990

申请日：1992-10-30

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  WAGNER DAVID RUDOLPH ,  BLUM PATRICIA RAE

IPC: B01J23/36 ,  B01J27/195 ,  C07B61/00 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.

公开(公告)号：NO950644L

公开(公告)日：1995-12-04

申请号：NO950644

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPARIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  WAGNER DAVID RUDOLPH

IPC: B01J8/24 ,  B01J8/32 ,  B01J23/58 ,  B01J8/38 ,  B01J19/00 ,  C07B61/00 ,  C07C67/05 ,  C07C67/055 ,  C07C67/313 ,  C07C69/15 ,  C07C69/01

Abstract: A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding ethylene and acetic acid into a fluid bed reactor through one or more inlets, introducing the oxygen into the reactor through at least one further inlet, co-joining the oxygen, ethylene and acetic acid in the reactor in contact with a fluid bed catalyst to produce vinyl acetate. The particle size diameter of the particulate catalyst material preferably has a range of 60% of the particles being below 200 microns (0.2 mm) with no more than 40% of the particles being below 40 microns (0.04 mm).

公开(公告)号：ZA9208654B

公开(公告)日：1993-05-11

申请号：ZA928654

申请日：1992-11-10

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  WAGNER DAVID RUDOLPH

IPC: B01J23/36 ,  B01J27/195 ,  C07B61/00 ,  C07C51/215 ,  C07C53/08 ,  C07B ,  B01J

CPC classification number: C07C53/08 ,  C07C51/215

公开(公告)号：NO924746D0

公开(公告)日：1992-12-08

申请号：NO924746

申请日：1992-12-08

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  WAGNER DAVID RUDOLPH

IPC: B01J27/195 ,  C07B61/00 ,  B01J23/36 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.

公开(公告)号：NZ270545A

公开(公告)日：1996-12-20

申请号：NZ27054595

申请日：1995-02-22

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPARIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  WAGNER DAVID RUDOLPH

IPC: B01J8/24 ,  B01J8/32 ,  B01J8/38 ,  B01J23/58 ,  B01J19/00 ,  C07B61/00 ,  C07C67/05 ,  C07C67/055 ,  C07C67/313 ,  C07C69/15

Abstract: A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding ethylene and acetic acid into a fluid bed reactor through one or more inlets, introducing the oxygen into the reactor through at least one further inlet, co-joining the oxygen, ethylene and acetic acid in the reactor in contact with a fluid bed catalyst to produce vinyl acetate. The particle size diameter of the particulate catalyst material preferably has a range of 60% of the particles being below 200 microns (0.2 mm) with no more than 40% of the particles being below 40 microns (0.04 mm).

公开(公告)号：ZA951441B

公开(公告)日：1996-08-21

申请号：ZA951441

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA RAE ,  LEMANSKI MICHAEL FRANCIS ,  PEPERA MARC ANTHONY ,  CIRJAK LARRY MICHAEL ,  PAPARIZOS CHRISTOS ,  SURESH DEVASIRVATHAM DHANARAH

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/10 ,  B01J37/00 ,  C07C67/055 ,  B01J ,  C07C

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns.

公开(公告)号：DE69209462T2

公开(公告)日：1996-08-14

申请号：DE69209462

申请日：1992-10-30

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  WAGNER DAVID RUDOLPH ,  BLUM PATRICIA RAE

IPC: B01J23/36 ,  B01J27/195 ,  C07B61/00 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.

公开(公告)号：NO950644A

公开(公告)日：1995-12-04

申请号：NO950644

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  CIRJAK LARRY MICHAEL ,  LEMANSKI MICHAEL FRANCIS ,  PAPARIZOS CHRISTOS ,  PEPERA MARC ANTHONY ,  WAGNER DAVID RUDOLPH

IPC: B01J23/58 ,  B01J8/24 ,  B01J8/32 ,  B01J8/38 ,  B01J19/00 ,  C07B61/00 ,  C07C67/05 ,  C07C67/055 ,  C07C67/313 ,  C07C69/15 ,  C07C69/01

CPC classification number: B01J19/002 ,  B01J8/24 ,  B01J8/32 ,  B01J8/388 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

公开(公告)号：NO177850B

公开(公告)日：1995-08-28

申请号：NO924746

申请日：1992-12-08

Applicant: STANDARD OIL CO OHIO

Inventor： BENKALOWYCZ NANCY CHRISTOFFERS ,  BLUM PATRICIA RAE ,  WAGNER DAVID RUDOLPH

IPC: B01J27/195 ,  C07B61/00 ,  B01J23/36 ,  C07C51/215 ,  C07C53/08

Abstract: Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone, wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.