公开(公告)号：AU547200B2

公开(公告)日：1985-10-10

申请号：AU7975582

申请日：1982-01-22

Applicant: UNION CARBIDE CORP

Inventor： DOUMAUX ARTHUR ROY ,  DOWNEY JAMES MICHAEL ,  HENRY JOSEPH PETER ,  HURT JOHN MARION

IPC: C07C201/04 ,  C07C203/00 ,  C07C76/00 ,  C07C77/00

公开(公告)号：AT14570T

公开(公告)日：1985-08-15

申请号：AT82400119

申请日：1982-01-22

Applicant: UNION CARBIDE CORP

Inventor： KAPICAK LOUIS ANTHONY ,  HENRY JOSEPH PETER

IPC: C07C67/36 ,  C07C69/36

公开(公告)号：ZA826898B

公开(公告)日：1983-07-27

申请号：ZA826898

申请日：1982-09-20

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  HENRY JOSEPH PETER

IPC: B01J23/00 ,  C07B61/00 ,  C07C27/00 ,  C07C27/04 ,  C07C29/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/60 ,  C07C31/08 ,  C07C31/20 ,  C07C41/00 ,  C07C41/18 ,  C07C43/13 ,  C07C67/00 ,  C08F ,  C08G

Abstract: This invention relates to a process for selectively cleaving a polyalkylene glycol, e.g., diethylene glycol, containing at least one ether group therein at a carbon-to-oxygen covalent bond and independently at a carbon-to-carbon covalent bond by heating the polyalkylene glycol with molecular hydrogen in the presence of a hydrogenation catalyst containing nickel to produce at least one of monoethylene glycol monomethyl ether, monoethylene glycol and ethanol. Monoethylene glycol monomethyl ether can be produced in predominant amounts by employing the process of this invention.

公开(公告)号：AU8861882A

公开(公告)日：1983-04-14

申请号：AU8861882

申请日：1982-09-22

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  HENRY JOSEPH PETER

IPC: C07C27/04 ,  B01J23/00 ,  B01J23/16 ,  B01J23/40 ,  B01J23/70 ,  C07B61/00 ,  C07C27/00 ,  C07C29/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/58 ,  C07C29/60 ,  C07C31/08 ,  C07C31/20 ,  C07C67/00

Abstract: This invention relates to a process for cleaving a polyalkylene glycol. e.g., diethylene glycol, containing at least one ether group therein at a carbon-to-oxygen covalent bond by heating the polyalkylene glycol with molecular hydrogen in the presence of a hydrogenation catalyst, e.g., copper chromite, to produce both monoethylene glycol and ethanol.

公开(公告)号：BR8200313A

公开(公告)日：1982-11-23

申请号：BR8200313

申请日：1982-01-21

Applicant: UNION CARBIDE CORP

Inventor： KAPICAK LOUIS ANTHONY ,  HENRY JOSEPH PETER

IPC: C07C69/36 ,  C07C69/38 ,  B01J23/42

Abstract: The invention deals with a process for preparing a diester of oxalic acid from carbon monoxide and an ester of nitrous acid in the vapor phase under a pressure in the presence of a special palladium supported catalyst. The catalyst is a solid palladium supported catalyst comprising metallic palladium or a salt thereof deposited on a nonacidic carrier, such as alpha-alumina, having a surface area of less than about 10 square meters per gram. This process provides an increased conversion to the diester product, a longer catalyst life and less by-product formation.

公开(公告)号：AU7975682A

公开(公告)日：1982-07-29

申请号：AU7975682

申请日：1982-01-22

Applicant: UNION CARBIDE CORP

Inventor： KAPICAK LOUIS ANTHONY ,  HENRY JOSEPH PETER

IPC: C07C69/36 ,  B01J23/44 ,  B01J35/10 ,  C07C67/36

Abstract: The invention deals with a process for preparing a diester of oxalic acid from carbon monoxide and an ester of nitrous acid in the vapor phase under a pressure in the presence of a special palladium supported catalyst. The catalyst is a solid palladium supported catalyst comprising metallic palladium or a salt thereof deposited on a nonacidic carrier, such as alpha-alumina, having a surface area of less than about 10 square meters per gram. This process provides an increased conversion to the diester product, a longer catalyst life and less by-product formation.

公开(公告)号：AU546474B2

公开(公告)日：1985-09-05

申请号：AU7975482

申请日：1982-01-22

Applicant: UNION CARBIDE CORP

Inventor： CLEVELAND THOMAS COOPER ,  DEITZLER JAMES EDWARD ,  DOUMAUX ARTHUR ROY ,  HENRY JOSEPH PETER ,  HURT JOHN MARION ,  KAPICAK LOUIS ANTHONY ,  REAM BERNARD CLAUDE

IPC: C07C67/36 ,  A61K20060101 ,  B01J23/00 ,  B01J23/44 ,  C01B20060101 ,  C07B61/00 ,  C07C69/36 ,  B01J35/10 ,  C07C67/40

Abstract: A continuous vapor state process for the preparation of diesters of oxalic acid from a nitrogen oxide, an alcohol and carbon monoxide.

公开(公告)号：AT12629T

公开(公告)日：1985-04-15

申请号：AT82400120

申请日：1982-01-22

Applicant: UNION CARBIDE CORP

Inventor： DOUMAUX ARTHUR ROY JR ,  DOWNEY JAMES MICHAEL ,  HENRY JOSEPH PETER ,  HURT JOHN MARION

IPC: C07C76/00 ,  C07C77/00

公开(公告)号：ZA8206929B

公开(公告)日：1983-11-30

申请号：ZA8206929

申请日：1982-09-21

Applicant: UNION CARBIDE CORP

Inventor： HENRY JOSEPH PETER

IPC: C07C27/04 ,  B01J23/00 ,  B01J23/16 ,  B01J23/40 ,  B01J23/70 ,  C07B61/00 ,  C07C27/00 ,  C07C29/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/58 ,  C07C29/60 ,  C07C31/08 ,  C07C31/20 ,  C07C67/00 ,  B01J ,  C07B ,  C07C

CPC classification number: C07C29/00 ,  C07C29/10 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/08

公开(公告)号：BR8205656A

公开(公告)日：1983-08-30

申请号：BR8205656

申请日：1982-09-28

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  HENRY JOSEPH PETER

IPC: B01J23/00 ,  C07B61/00 ,  C07C27/00 ,  C07C27/04 ,  C07C29/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/60 ,  C07C31/08 ,  C07C31/20 ,  C07C41/00 ,  C07C41/18 ,  C07C43/13 ,  C07C67/00 ,  C07C37/08

Abstract: This invention relates to a process for selectively cleaving a polyalkylene glycol, e.g., diethylene glycol, containing at least one ether group therein at a carbon-to-oxygen covalent bond and independently at a carbon-to-carbon covalent bond by heating the polyalkylene glycol with molecular hydrogen in the presence of a hydrogenation catalyst containing nickel to produce at least one of monoethylene glycol monomethyl ether, monoethylene glycol and ethanol. Monoethylene glycol monomethyl ether can be produced in predominant amounts by employing the process of this invention.