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    OZONE PRODUCTION FROM CO2
    22.
    发明申请
    OZONE PRODUCTION FROM CO2 审中-公开
    来自二氧化碳的臭氧生成

    公开(公告)号：WO2002064498A1

    公开(公告)日：2002-08-22

    申请号：PCT/US2002/003921

    申请日：2002-01-30

    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY

    Inventor： MORAN, Edward, F., Jr. ,  PIASECKI, Robert, V.

    IPC: C01B13/11

    CPC classification number: C01B13/11 ,  C01B2201/60

    Abstract: Process for making ozone comprising passing substantially pure carbon dioxide between electrodes having a sufficient voltage difference between them to cause a corona discharge across them.

    Abstract translation: 用于制造臭氧的方法包括在其间具有足够的电压差的电极之间通过基本上纯的二氧化碳以引起它们之间的电晕放电。

    METHOD OF GENERATING OZONE
    24.
    发明申请
    METHOD OF GENERATING OZONE 有权
    生成臭氧的方法

    公开(公告)号：US20120103791A1

    公开(公告)日：2012-05-03

    申请号：US13348147

    申请日：2012-01-11

    Applicant: Youichiro TABATA ,  Hajime NAKATANI ,  Masaki KUZUMOTO

    Inventor： Youichiro TABATA ,  Hajime NAKATANI ,  Masaki KUZUMOTO

    IPC: C01B13/11

    CPC classification number: C01B13/11 ,  C01B2201/60 ,  C01B2201/66

    Abstract: A method of generating ozone by applying a silent discharge to oxygen as a first raw material gas, and an oxide compound gas, as a second raw material gas, in which excited light, excited and generated by a discharge in the oxygen and the oxide compound gas, dissociates the oxide compound gas, or excites the oxide compound gas, accelerating dissociation of the oxygen and generation of ozone. In this way, ozone generation efficiency is raised.

    Abstract translation: 作为第一原料气体，通过对作为第一原料气体的氧进行静电放电而产生臭氧的方法和作为第二原料气体的氧化物化合物气体，其中通过在氧气和氧化物化合物中的放电而激发和产生的激发光 气体，解离氧化物复合气体，或激发氧化物化合物气体，促进氧的分解和产生臭氧。 这样就可以提高臭氧发生效率。

    Ozone generator
    25.
    发明授权
    Ozone generator 有权
    臭氧发生器

    公开(公告)号：US08075844B2

    公开(公告)日：2011-12-13

    申请号：US12100444

    申请日：2008-04-10

    Applicant: Youichiro Tabata

    Inventor： Youichiro Tabata

    IPC: B01J19/08

    CPC classification number: C01B13/11 ,  C01B2201/60 ,  C01B2201/66

    Abstract: An ozone generator for generating ozone by applying a specified process to oxygen by discharge includes a first raw material gas supply unit for supplying the oxygen as a first raw material gas, and a second raw material gas supply unit for supplying an oxide compound gas as a second raw material gas, in which, by excited light, excited and generated by a discharge in the oxygen and the oxide compound gas, the oxide compound gas is dissociated, or the oxide compound gas is excited accelerating dissociation of the oxygen, and ozone is generated. In this way, ozone generation efficiency is raised.

    Abstract translation: 一种用于通过排出对氧气进行特定工艺来产生臭氧的臭氧发生器包括：第一原料气体供应单元，用于供应作为第一原料气体的氧;以及第二原料气体供应单元，用于将氧化物化合物气体作为 第二原料气体，其中通过激发光激发并通过在氧气和氧化物化合物气体中的放电产生氧化物化合物气体，氧化物化合物气体被分解，或氧化物化合物气体被激发以促进氧的解离，臭氧是 生成。 这样就可以提高臭氧发生效率。

    Process for conditioning ozone gas recycle stream in ozone pulp bleaching
    27.
    发明授权
    Process for conditioning ozone gas recycle stream in ozone pulp bleaching 失效
    在臭氧纸浆漂白中调节臭氧气体循环流的方法

    公开(公告)号：US6126781A

    公开(公告)日：2000-10-03

    申请号：US739050

    申请日：1991-08-01

    Applicant: James Joseph ,  Michael A. Pikulin ,  William H. Friend

    Inventor： James Joseph ,  Michael A. Pikulin ,  William H. Friend

    IPC: C01B13/10 ,  B01D53/62 ,  B30B9/20 ,  C01B13/11 ,  D21C9/153 ,  D21C9/18 ,  D21C11/06

    CPC classification number: D21C9/153 ,  B01D53/62 ,  C01B13/11 ,  C01B2201/60 ,  Y02C10/04 ,  Y02P20/152 ,  Y02P70/24

    Abstract: A process for conditioning an ozone gas recycle stream in an ozone pulp bleaching process, wherein the level of carbon dioxide in the recycle stream is controlled to allow full capacity operation of the ozone generator. Carbon dioxide concentration is identified over the relevant operational ranges and maximum concentration is identified for full capacity/optimum efficiency operation. Specific methods are described for controlling carbon dioxide concentration including purging a portion of the recycle stream, counter-current scrubbing of the recycle stream with an alkaline solution and passing the recycle stream through an adsorbent material. Contaminants entering the system also may be reduced by directing the purged recycle stream, which is relatively oxygen rich, into the dewatering press where pulp consistency is increased. In this manner nitrogen surrounding the pulp is displaced by oxygen and thus, does not enter the bleaching/ozone system with the pulp.

    Abstract translation: 一种用于在臭氧纸浆漂白方法中调节臭氧气体再循环流的方法，其中控制再循环流中的二氧化碳水平以允许臭氧发生器的全容量运行。 在相关工作范围内确定二氧化碳浓度，并确定最大浓度用于满容量/最佳效率运行。 描述了用于控制二氧化碳浓度的具体方法，包括清洗一部分循环物流，用碱性溶液逆流洗涤再循环物流并使循环物流通过吸附材料。 进入系统的污染物也可以通过将相对富氧的净化的再循环流引导到脱浆压机中来减少纸浆稠度增加。 以这种方式，纸浆周围的氮被氧气置换，因此不会与纸浆进入漂白/臭氧系统。

    Method and apparatus for generating ozone and methods of its use
    29.
    发明授权
    Method and apparatus for generating ozone and methods of its use 失效
    用于生成臭氧的方法和装置及其使用方法

    公开(公告)号：US5792326A

    公开(公告)日：1998-08-11

    申请号：US782390

    申请日：1997-01-13

    Applicant: Minoru Harada ,  Ryoichi Shinjo ,  Manabu Tsujimura ,  Rempei Nakata ,  Kunihiro Miyazaki ,  Naruhiko Kaji ,  Yutaka Nakano

    Inventor： Minoru Harada ,  Ryoichi Shinjo ,  Manabu Tsujimura ,  Rempei Nakata ,  Kunihiro Miyazaki ,  Naruhiko Kaji ,  Yutaka Nakano

    IPC: C01B13/10 ,  C01B13/11 ,  C23C8/12 ,  C23C16/40 ,  C23C16/44 ,  C23C16/448

    CPC classification number: C23C16/448 ,  C01B13/10 ,  C01B13/11 ,  C23C16/402 ,  C23C16/4402 ,  C23C8/12 ,  C01B2201/60

    Abstract: Ozonizer (10) which supplies a feed gas to ozone generating cell (11) under application of a high voltage and which delivers an ozone gas through an ozone gas transport path (consisting of pipes (14) and (15)) as it has been generated in said ozone generating cell (11) is characterized in that the ozone gas transport path is furnished with means for removing at least one of NOx, HF and SOx (in the drawings, the means is for removing NOx) and that the ozone gas from the ozone generating cell (11) is passed through said removing means, whereby at least one of NOx, HF and SOx in said ozone gas is removed before it is delivered to a subsequent stage. The product ozone is not contaminated with Cr compounds at all or insufficiently contaminated to cause any practical problems in the fabrication of highly integrated semiconductor devices. Alternatively, ozonizer (10) which comprises an ozone generating cell (11) having an inlet (8) for supplying a feed gas, high voltage applying means (35) and an outlet (29) for discharging the ozone generated, and ozone delivery paths (30) and (31) for delivering the generated ozone is characterized in that oxygen (1) supplemented with 10-20 vol % of carbon dioxide and/or carbon monoxide (2) is used as the feed gas. The thus produced ozone is significantly low in the level of Cr compounds and, hence, can suitably be used in the formation of metal oxides, in particular, silicon oxide.

    Abstract translation: 臭氧发生器（10），其在施加高压下向臭氧发生电池（11）供应进料气体，并且通过臭氧气体输送路径（由管道（14）和（15）组成）输送臭氧气体） 在臭氧发生电池（11）中产生的臭氧气体输送路径的特征在于，臭氧气体输送路径具有用于除去NOx，HF和SO x中的至少一种的装置（在附图中，用于除去NOx的装置），臭氧气体 从臭氧发生电池（11）通过所述去除装置，由此在所述臭氧气体中的NOx，HF和SO x中的至少一种在被输送到后续阶段之前被去除。 产物臭氧根本不被Cr化合物污染或污染不足，导致制造高度集成的半导体器件的任何实际问题。 或者，臭​​氧发生器（10）包括具有用于供应进料气体的入口（8）的臭氧发生电池（11），用于排出产生的臭氧的高压施加装置（35）和出口（29），以及臭氧输送路径 （30）和（31）用于输送生成的臭氧的特征在于，使用补充有10〜20体积％的二氧化碳和/或一氧化碳（2）的氧（1）作为原料气。 这样生成的臭氧在Cr化合物的含量上显着地很低，因此可以适当地用于形成金属氧化物，特别是氧化硅。

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