公开(公告)号：JP2009298706A

公开(公告)日：2009-12-24

申请号：JP2008152424

申请日：2008-06-11

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  NAKANO TATSUYA ,  ISHII YASUTAKA

IPC: C07D201/04 ,  C07B61/00 ,  C07D223/10

CPC classification number: C07D201/04 ,  C07D223/10 ,  Y02P20/52

Abstract: PROBLEM TO BE SOLVED: To provide a method for easily producing an amide or a lactam at a high yield by causing the rearrangement reaction of an oxime compound to proceed, without generating a large amount of byproducts such as ammonium sulfate. SOLUTION: The method for producing an amide or a lactam comprises subjecting an oxime compound to a rearrangement reaction in the presence of a compound comprising a structure represented by the following formula (1)-Z-X (1) (in the formula, Z represents a P atom, an N atom, an S atom, a B atom or an Si atom, and X represents a leaving group, provided that Z is bound to one or two or more atom(s) or group(s) in addition to X) to form a corresponding amide or a corresponding lactam. In the production method, X may be a halogen atom. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 待解决的问题：提供通过使肟化合物的重排反应进行而容易地以高产率制备酰胺或内酰胺的方法，而不产生大量的副产物如硫酸铵。 解决方案：制备酰胺或内酰胺的方法包括在包含由下式（1）-ZX（1）表示的结构的化合物的存在下使肟化合物进行重排反应（式中， Z表示P原子，N原子，S原子，B原子或Si原子，X表示离去基团，条件是Z与一个或两个以上的原子或基团结合， 除了X之外）以形成相应的酰胺或相应的内酰胺。 在制造方法中，X可以是卤素原子。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：US20180093949A1

公开(公告)日：2018-04-05

申请号：US15562518

申请日：2015-06-04

Applicant: ANTHEA AROMATICS PRIVATE LIMITED

Inventor： Manoj Kumar MOHAPATRA ,  Ramamohanrao BENDAPUDI ,  Paul Vincent MENACHERRY ,  Vincent PAUL

IPC: C07D201/06 ,  C07D201/16 ,  C07D227/087 ,  C01G9/02 ,  C01B21/14

CPC classification number: C07D201/06 ,  B01D3/36 ,  C01B21/14 ,  C01G9/02 ,  C07D201/04 ,  C07D201/16 ,  C07D227/087

Abstract: Disclosed herein is an efficient, economical, industrially advantageous, straight-through process for the preparation of cyclic amides, also referred as lactams, in substantially pure form and high yield, from the corresponding cyclic ketones and a hydroxylammonium salt, using a combination of amphoteric metal oxide or amphoteric masked metal oxide and a base.

公开(公告)号：US20170298015A1

公开(公告)日：2017-10-19

申请号：US15517424

申请日：2015-09-17

Applicant: TORAY INDUSTRIES, INC.

Inventor： Takenori Sugimoto ,  Toru Takahashi ,  Kazuki Sugawara

IPC: C07D201/04 ,  B01J19/12 ,  C07C249/06

CPC classification number: C07D201/04 ,  B01J19/12 ,  B01J19/127 ,  B01J2219/0801 ,  B01J2219/0877 ,  B01J2219/1203 ,  C07B61/00 ,  C07C249/04 ,  C07C249/06 ,  C07C251/44

Abstract: Provided is a photochemical reaction device wherein two partitions formed from an optically transparent material are arranged apart from each other between a light source and a reaction liquid, and an optically transparent fluid introduction/discharge means for introducing an optically transparent fluid between the partitions and discharging the fluid and a state change detection means for detecting a change in the state of the optically transparent fluid at the discharge side of the optically transparent fluid introduction/discharge means are provided. Also provided are a photochemical reaction method that uses the photochemical reaction device and a lactam production method that uses the photochemical reaction method. The present invention prevents decreases in the performance of the light source even when the optically transparent material in the photochemical reaction device is damaged, and makes it possible to reliably prevent ignition even if the reaction liquid is a flammable liquid.

公开(公告)号：US20170238381A1

公开(公告)日：2017-08-17

申请号：US15518946

申请日：2015-09-18

Applicant: TORAY INDUSTRIES, INC.

Inventor： Fumikatsu Ohno ,  Toru Takahashi ,  Hiroyasu Ito ,  Kazuki Sugawara

IPC: H05B33/08 ,  C07D223/10 ,  H02M1/084 ,  C07C249/06 ,  H02M7/217 ,  B01J19/12 ,  C07C251/44

CPC classification number: H05B33/0815 ,  B01J19/122 ,  B01J2219/0877 ,  B01J2219/1203 ,  C07B61/00 ,  C07C249/06 ,  C07C251/44 ,  C07C2601/20 ,  C07D201/04 ,  C07D223/10 ,  C07D225/02 ,  H01L33/00 ,  H02M1/084 ,  H02M7/12 ,  H02M7/2173 ,  H05B33/0842

Abstract: Provided are a three-phase AC/DC converter disposed between a three-phase AC power supply and a light emitting diode group, the converter including a three-phase full bridge circuit in which pairs of switching elements are connected in parallel between DC buses for the three phases of the three-phase AC power supply; reactors connecting connection portions between the switching elements and corresponding phases of the three-phase AC power supply; a smoothing capacitor on the output side of the three-phase full bridge circuit; a DC voltage detection means; a power supply voltage phase detection means; and a pulse width modulation means for outputting pulse width modulation signals of the switching elements, wherein the pulse width modulation means outputs the pulse width modulation signals based on a power supply voltage phase and an output voltage between the DC buses.

公开(公告)号：US09221762B2

公开(公告)日：2015-12-29

申请号：US14273688

申请日：2014-05-09

Applicant: Honeywell International Inc. ,  University of Southampton

Inventor： Alan B. Levy ,  Robert Raja ,  Matthew E. Potter

IPC: C07D201/04 ,  C07D223/10 ,  B01J29/85 ,  B01J35/00 ,  C07D225/02

CPC classification number: B01J29/85 ,  B01J35/002 ,  C01B37/08 ,  C01B39/54 ,  C07D201/04 ,  C07D223/10 ,  C07D225/02 ,  Y02P20/52

Abstract: Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

Abstract translation: 提供了通过使用硅铝磷酸盐催化剂进行贝克曼重排来从肟产生内酰胺的方法。 这些催化剂可用于气相或液相反应以将肟转化成内酰胺。 使用所公开的方法制备肟的高转化率和高选择性，包​​括由环己酮肟产生的ε-己内酰胺的高转化率和选择性，以及由环十二酮肟产生的ω-月桂内酰胺的高转化率和选择性。

公开(公告)号：US08816069B2

公开(公告)日：2014-08-26

申请号：US13635092

申请日：2011-03-15

Applicant: Junichi Kugimoto ,  Joji Kawai ,  Hiroshi Matsumoto

Inventor： Junichi Kugimoto ,  Joji Kawai ,  Hiroshi Matsumoto

IPC: C07D225/02 ,  C07D201/04 ,  C07D201/06

CPC classification number: C07D201/06 ,  C07D201/04 ,  C07D225/02

Abstract: The present invention relates to a method for producing a high purity, high quality amide compound, particularly, lactam. A first embodiment of the present invention is characterized in that an amount of each of a halide, an aldehyde compound, an alcohol compound and a nitrile compound contained in a solution recycled into an oxime-forming step is controlled to an amount of 0.4 mol % or less based on the ketone as a starting material. A second embodiment of the present invention is characterized in that one or more compounds selected from the group consisting of a ketone, an oxime and an amide compound are purified by hydrogenation and/or crystallization for eliminating impurities containing a double bond. A third embodiment of the present invention is characterized in that a content of impurities having a cyclic bridge structure is controlled by using a cycloalkanone purified by recrystallization.

Abstract translation: 本发明涉及一种生产高纯度，优质酰胺化合物，特别是内酰胺的方法。 本发明的第一实施方案的特征在于，将再循环到肟形成步骤的溶液中所含的卤化物，醛化合物，醇化合物和腈化合物中的每一种的量控制为0.4mol％ 基于酮作为原料。 本发明的第二个实施方案的特征在于，通过氢化和/或结晶纯化一种或多种选自酮，肟和酰胺化合物的化合物，以消除含有双键的杂质。 本发明的第三实施方案的特征在于通过使用通过重结晶纯化的环烷酮来控制具有环状桥结构的杂质的含量。

公开(公告)号：US08772476B2

公开(公告)日：2014-07-08

申请号：US13658495

申请日：2012-10-23

Applicant: Honeywell International Inc. ,  University of Southampton

Inventor： Alan B. Levy ,  Robert Raja ,  Matthew E. Potter

IPC: C07D201/04 ,  C07D223/10

CPC classification number: B01J29/85 ,  B01J35/002 ,  C01B37/08 ,  C01B39/54 ,  C07D201/04 ,  C07D223/10 ,  C07D225/02 ,  Y02P20/52

Abstract: Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

Abstract translation: 提供了通过使用硅铝磷酸盐催化剂进行贝克曼重排来从肟产生内酰胺的方法。 这些催化剂可用于气相或液相反应以将肟转化成内酰胺。 使用所公开的方法制备肟的高转化率和高选择性，包​​括由环己酮肟产生的ε-己内酰胺的高转化率和选择性，以及由环十二酮肟产生的ω-月桂内酰胺的高转化率和选择性。

公开(公告)号：US08309714B2

公开(公告)日：2012-11-13

申请号：US12744675

申请日：2008-11-19

Applicant: Junichi Kugimoto ,  Joji Kawai ,  Hideo Shimomura ,  Ryouta Yasumatsu ,  Nobuhiro Ii

Inventor： Junichi Kugimoto ,  Joji Kawai ,  Hideo Shimomura ,  Ryouta Yasumatsu ,  Nobuhiro Ii

IPC: C07D201/04 ,  C07D225/02

CPC classification number: C07D201/04 ,  C07D225/02 ,  Y02P20/582

Abstract: Provided is a process for efficiently producing laurolactam by simple steps from cyclododecanone and hydroxylamine. This production process comprises the steps of: (a) reacting cyclododecanone with hydroxylamine in an aqueous solution in the presence of an oxime-formation solvent to produce cyclododecanone oxime; (b) separating the reaction mixture obtained after the oxime-forming step into an oil and an aqueous phases and collecting a solution of cyclododecanone oxime of the oil phase; (c) removing a part or all of the oxime-formation solvent and dissolved water from the solution of cyclododecanone oxime which is collected as an oil phase in the oil/aqueous phase separation step, whereby preparing a solution containing a rearrangement solvent to be used in a rearrangement reaction in a later step and the cyclododecanone oxime; (d) producing laurolactam from cyclododecanone oxime by rearrangement reaction using an aromatic-ring containing compound as a rearrangement catalyst; and (e) separating and removing the rearrangement solvent and the rearrangement catalyst from the reaction mixture after the rearrangement step, and purifying the laurolactam.

Abstract translation: 提供一种通过简单的步骤从环十二酮和羟胺有效地生产十二内酰胺的方法。 该制备方法包括以下步骤：（a）在肟形成溶剂存在下，使环十二酮与羟胺在水溶液中反应，生成环十二烷酮肟; （b）将在肟形成步骤后获得的反应混合物分离成油相和水相，并收集油相的环十二烷酮肟溶液; （c）从油/水相分离步骤中以油相收集的环十二烷酮肟溶液中除去部分或全部肟形成溶剂和溶解的水，由此制备含有使用的重排溶剂的溶液 在后续步骤中的重排反应和环十二酮肟; （d）使用含芳环的化合物作为重排催化剂，通过重排反应从环十二酮肟生产月桂内酰胺; 和（e）在重排步骤之后从反应混合物中分离和除去重排溶剂和重排催化剂，并纯化月桂内酰胺。

公开(公告)号：US08212028B2

公开(公告)日：2012-07-03

申请号：US12543022

申请日：2009-08-18

Applicant: Tatsuya Okubo ,  Yuki Suzuki ,  Tsuyoshi Matsushita ,  Tatsuya Suzuki

Inventor： Tatsuya Okubo ,  Yuki Suzuki ,  Tsuyoshi Matsushita ,  Tatsuya Suzuki

IPC: C07D201/04

CPC classification number: C07D201/04 ,  C01B37/02 ,  C01B39/36 ,  C01B39/40 ,  Y02P20/52

Abstract: The present invention provides a method which can produce ε-caprolactam with a good selectivity by reacting cyclohexanone oxime with a good conversion in a vapor phase Beckmann rearrangement reaction. Disclosed is a method for producing ε-caprolactam, which comprises performing a vapor phase Beckmann rearrangement reaction of cyclohexanone oxime in the presence of a pentasil type zeolite, wherein the pentasil type zeolite is a zeolite obtained by subjecting a mixture containing a silicon compound, water, and a compound represented by formula (I): [(R1)3N+—(CH2)m—N+(R1)2—(CH2)m—N+(R1)3]·3/n(A)  (I) wherein R1 represents an alkyl group having 1 to 4 carbon atoms, A represents an n-valent anion, m represents an integer of 5 to 7, and n represents an integer of 1 to 3, to a hydrothermal synthesis reaction.

Abstract translation: 本发明提供了一种通过在气相贝克曼重排反应中使环己酮肟与良好的转化率反应，能够以良好的选择性生产“己内酰胺”的方法。 公开了一种生产ε-己内酰胺的方法，其包括在pentasil型沸石存在下进行环己酮肟的气相Beckmann重排反应，其中pentasil型沸石是通过使含有硅化合物的混合物， 水和由式（I）表示的化合物：[（R1）3N + - （CH2）m-N +（R1）2-（CH2）m-N +（R1）3]·3 / n（A） 其中，R1表示碳原子数1〜4的烷基，A表示n价阴离子，m表示5〜7的整数，n表示1〜3的整数。

公开(公告)号：US20110077429A1

公开(公告)日：2011-03-31

申请号：US12627681

申请日：2009-11-30

Applicant: Tung-Han Tsai ,  Cheng-Fa Hsieh ,  Chi-Yuan Chen

Inventor： Tung-Han Tsai ,  Cheng-Fa Hsieh ,  Chi-Yuan Chen

IPC: C07C231/10 ,  B01J31/04

CPC classification number: C07C231/10 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/0209 ,  B01J31/0217 ,  B01J31/0218 ,  B01J31/0222 ,  B01J31/0238 ,  B01J31/0247 ,  B01J31/0251 ,  B01J31/0279 ,  B01J31/0285 ,  C07B43/06 ,  C07C229/24 ,  C07D201/04 ,  C07D223/10

Abstract: The present invention provides a catalyst composition for preparing an amide, including an amino acid ionic liquid having a cation of formula (I) and an anion selected from the group consisting of an inorganic acid group, an organic acid group and a combination thereof, wherein the numbers of the anion and the cation are such that the amino acid ionic liquid is electroneutral; and a Bronsted acid. The present invention also provides a method for preparing an amide in the presence of the catalyst composition, and the method has advantages such as decreasing viscosity of ionic liquid, and increasing conversion rate of ketoximes and selectivity of amides.

Abstract translation: 本发明提供一种制备酰胺的催化剂组合物，其包括具有式（I）的阳离子的氨基酸离子液体和选自无机酸基，有机酸基及其组合的阴离子，其中 阴离子和阳离子的数量使得氨基酸离子液体是电中性的; 和布朗斯台德酸。 本发明还提供了在催化剂组合物存在下制备酰胺的方法，该方法具有降低离子液体的粘度，提高酮肟的转化率和酰胺选择性的优点。