Abstract:
PURPOSE: A molten carbonate fuel cell system equipped with a hydrocarbon reactor is provided to reduce the amount of carbon dioxide released into the atmosphere by regenerating the carbon dioxide into hydrocarbon. CONSTITUTION: A molten carbonate fuel cell system equipped with a hydrocarbon reactor includes an air pole(130), a fuel cell(100), a hydrocarbon reactor(200), a gas and liquid separator(210), and a hydrocarbon reservoir(220). The air pole receives oxygen and carbon dioxide and generates carbonate ions. The fuel cell includes a fuel pole(110). The fuel pole reacts fuels containing the carbonate ions, hydrogen, and electrolyte absorbing the carbonate ions. The fuel pole generates the exhausted gas of the fuel pole, and the exhausted gas contains water and the carbon dioxide. The hydrocarbon reactor generates hydrocarbon based on the exhausted gas. The gas and liquid separator separates water from the hydrocarbon result. The hydrocarbon without the water is stored in the hydrocarbon reservoir.
Abstract:
Disclosed is a carbon dioxide marine isolation method which uses a neutralizing step using calcium oxide usually contained in industrial alkali waste for changing carbon dioxide into high concentrate bicarbonate ions, an aeration step for producing leakage water stably containing the bicarbonate ions during the contact with the atmosphere, and a discharge step of the leakage water to the sea with relatively shallow water level for isolating. According to the present invention, a user can perform the carbon dioxide marine isolation with a relatively low cost by using the industrial alkali waste, and can store carbon dioxide in an environmentally friendly way for a long time by minimizing environmental harmful influences including marine oxidation. Through the carbon dioxide marine isolation method, a user can actively correspond to the regulations on discharging carbon dioxide, and can obtain an economical effect by securing the carbon ecoright.
Abstract:
본 발명은 화력발전 시스템과 용융 탄산염 연료전지발전 시스템을 연계한 복합발전 시스템에 관한 것이다. 본 발명은 화력발전 플랜트에서 배출되는 배기가스로부터 이산화탄소를 포집하기 위한 이산화탄소 포집장치를 포함하는 화력발전 시스템과; 포집된 이산화탄소가 공급되는 공기극을 구비한 연료전지 스택을 포함하고, 탄화수소 발생장치에서 발생한 탄화수소를 연료전지 스택의 연료극으로 공급하는 용융 탄산염 연료전지발전 시스템을 포함한다. 또한, 공기극에서는 산소와 이산화탄소가 반응하여 탄산염 이온이 만들어짐으로써, 연료전지 발전과 이산화탄소 저감이 동시에 이루어진다. 이와 같은 본 발명에 의하면, 화력 발전소의 배기가스로부터 포집된 이산화탄소를 용융 탄산염 연료전지 연료전지의 공기극에 공급하여 연료전지 발전과 이산화탄소 저감을 동시에 수행할 수 있는 효과가 있다.
Abstract:
PURPOSE: A carbon dioxide conversion method and an apparatus are provided to convert carbon dioxide into dissolved inorganic carbon which comprises high concentration and density of bicarbonate ion by reacting carbon dioxide to magnesium hydroxide (Mg(OH)2) aqueous solution. CONSTITUTION: A carbon dioxide conversion method comprises the following steps. Generate dissolved inorganic carbon which includes bicarbonate ion by reacting carbon dioxide to magnesium hydroxide (Mg(OH)2) aqueous solution. Concentration of the magnesium hydroxide is 150mM or greater. A carbon dioxide conversion device(100) comprises a reaction bath(10), a seawater feeder(20), a magnesium hydroxide feeder(30), a carbon dioxide feeder(40), a gas distributor(41), a mixer(50), and a vent(60). The raction bath generates dissolved inorganic carbon by reacting carbon dioxide to aqueous solution which includes magnesium hydroxide. The seawater feeder supplies seawater within the reaction bath.The magnesium hydroxide feeder supplies magnesium hydroxide within the reaction bath. The carbon dioxide feeder supplies carbon dioxide within the reaction bath. The gas distributor evenly distributes carbon dioxide in seawater. The mixer mixes more than two reactants selected from the seawater, magnesium hydroxide or carbon dioxide. The vent ejects reactant from the reaction bath after generating dissolved inorganic carbon.
Abstract:
PURPOSE: A tubular flow converting concentrate reactor for carbon dioxide ocean storage is provided to safely separate in the ocean using density difference, and to release treating water including bicarbonate ion on a shallow place by using the tubular reactor. CONSTITUTION: A tubular reactor for carbon dioxide treatment comprises a tubular shape and have transform reaction of carbon dioxide to bicarbonate ion(HCO_3) by alkali solution. The tubular reactor comprises an Alkali component inlet(220), a carbon dioxide inlet(230), a water inlet(210), and a treating water discharge unit(240). The treating water discharge unit discharges the treating water including bicarbonate ion. .
Abstract:
본 발명은 탄화수소발생장치를 포함하는 용융탄산염연료전지시스템에 관한 것이다. 개시발명은 산소와 이산화탄소를 공급받아 탄산염 이온을 생성하는 공기극, 공기극에서 생성된 탄산염 이온을 흡수하는 전해질, 및 전해질로부터 공급받은 탄산염 이온과 배관을 통하여 공급받은 수소를 포함하는 연료를 반응시켜 물과 이산화탄소를 포함하는 연료극배가스를 생성하는 연료극으로 이루어지는 연료전지; 및 연료전지의 연료극으로부터 연료극배가스를 공급받아 탄화수소반응에 의하여 탄화수소를 발생시키는 탄화수소발생장치;를 포함한다. 따라서, 연료극의 배가스에 포함되어 있는 일산화탄소나 이산화탄소 등의 가스를 탄화수소화하여 저장, 공급하는 것을 특징으로 한다.
Abstract:
PURPOSE: A catalyst for inner reforming type molten carbonate fuel cells is provided to ensure excellent poisoning resistance against electrolyte and to stably supply hydrogen in a long-term operation. CONSTITUTION: A catalyst for inner reforming type molten carbonate fuel cells is used for methane steam reforming reaction of a fuel cell. The active material is nickel and the carrier is magnesium-silica complex oxide. A method for manufacturing the catalyst comprises the steps of: dipping nickel in an MgSiO3 carrier; drying a catalyst precursor in which the nickel is dipped; and sintering the dried catalyst precursor to prepare a catalyst precursor.