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31.
公开(公告)号:US11198757B2
公开(公告)日:2021-12-14
申请号:US16347426
申请日:2017-11-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Robert S. Clough , Sheng Ye , Tao Gong , Jonathan D. Zook , Susan E. DeMoss , Charlie P. Blackwell
IPC: C08G59/56 , C08G75/045 , C09J163/00 , C09J181/02 , G03F7/004 , G03F7/038
Abstract: A composition includes a photolatent amine, camphorquinone, and a coumarin sensitizer. The coumarin sensitizer is triplet photosensitizer and has an absorbance with a wavelength of maximum absorbance in a range from 390 nanometers to 510 nanometers. Compositions that further include a polymerizable material are also disclosed. Polymer networks preparable from such compositions and methods for making the polymer networks are also disclosed.
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32.
公开(公告)号:US20210340311A1
公开(公告)日:2021-11-04
申请号:US17283084
申请日:2019-11-08
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Abstract: A composition is described comprising an amine-reactive material; and a polymeric catalyst comprising hydroxyl groups and tertiary amine groups. The polymeric catalyst is typically suspended or dispersed in a liquid dispersant. The liquid dispersant does not covalently bond with the tertiary amine groups. The liquid dispersant is typically a hydroxy-functional or thiol-functional. Also described is a polymer network comprising the cured composition described herein, a polymer catalyst, and catalyst dispersion; as well as methods.
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公开(公告)号:US20210062858A1
公开(公告)日:2021-03-04
申请号:US16643895
申请日:2018-09-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: William H. Moser , Erik M. Townsend , Jonathan D. Zook , Susan E. DeMoss , Clinton J. Cook , Scott A. Boyd , Michael D. Swan
IPC: F16B41/00 , C08F283/00
Abstract: Curable sealant compositions comprise the components: a) x weight percent of at least one polythiol; b) y weight percent of at least one unsaturated compound having at least two non-aromatic carbon-carbon double bonds, at least one carbon-carbon triple bond, or a combination thereof; c) from 0.01 to 8 weight percent of at least one organoborane-amine complex; d) from 0.05 to 10 weight percent of at least one organic peroxide; and e) from 0.01 to 10 weight percent of a photoinitiator system capable of generating free radicals upon exposure to actinic radiation. Each of x and y represents a positive real number. The sum x+y is in the range of 72 to 99. The weight percent ranges of the components a)-e) are based on the total weight of the components a)-e). A seal cap including the curable sealant composition and methods of making and using the curable sealant compositions are also disclosed.
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34.
公开(公告)号:US20190276588A1
公开(公告)日:2019-09-12
申请号:US16347417
申请日:2017-11-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Sheng Ye , Erik M. Townsend , Michael D. Swan , William H. Moser
Abstract: A composition including a polythiol having more than one thiol groups, a polyepoxide having more than one epoxide group, a photolatent base catalyst that can photochemically generate a first amine, and a second amine phase-separated within the composition. A polymer network preparable from the composition, and a method for making the polymer network are also disclosed.
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公开(公告)号:US20190255562A1
公开(公告)日:2019-08-22
申请号:US16347441
申请日:2017-11-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Michael D. Swan , Sheng Ye , Susan E. DeMoss
Abstract: The method includes applying a curable sealant to a surface of the aircraft component, forming a non-tacky skin on an exposed portion of the curable sealant within a first time period while allowing a portion of the curable sealant adjacent the surface of the aircraft component to be liquid for a second time period. The second time period is at least twice the first time period. The curable sealant comprises at least one of an adhesion promoter or a wetting agent.
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公开(公告)号:US10287466B2
公开(公告)日:2019-05-14
申请号:US15545849
申请日:2016-02-10
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Susan E. DeMoss , Jonathan D. Zook , Matthew Capel
IPC: C08G75/00 , C08G75/02 , C08G75/04 , C08G75/12 , C08L81/00 , C08L81/02 , C07C321/18 , C07C323/14 , C09J181/02
Abstract: Polythioether polymers, sealants containing polythioether polymers, and compounds useful as stabilizing monomers in the manufacture of polythioether polymers are provided. In many embodiments the polymers and sealants demonstrate reduced risk of spoilage that may be caused by low temperature storage of the polymer or uncured sealant. Compounds useful as stabilizing monomers include compounds according to formula I: CH2═CR1—CHR2—S—R3—S—CHR4—CR5═CH2 [I] wherein R1, R2, R4 and R5 are independently selected from —H, —CH3 or —C2H5, and wherein R3 is selected from divalent groups comprising 2-12 carbon atoms, 0-5 ether oxygen atoms and 0-5 thioether sulfur atoms, which may be straight, branched or cyclic.
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37.
公开(公告)号:US20180187009A1
公开(公告)日:2018-07-05
申请号:US15739485
申请日:2016-06-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Sheng Ye , Kathleen S. Shafer , Michael S. Wendland , Susan E. DeMoss , Jonathan D. Zook
IPC: C08L81/04 , C08L81/02 , C08F291/04 , C08F216/12 , C08F222/26 , C08K5/23 , C08K3/04 , C08K3/26 , C08K3/34 , C08K3/36 , C09B29/033 , C09K3/10
Abstract: A curable composition having a polythiol; at least one unsaturated compound comprising more than one carbon-carbon double bond, carbon-carbon triple bond, or a combination thereof; and a dye compound represented by formula (I). A crosslinked composition prepared from the curable composition, a method of making an at least partially crosslinked network, a method for indicating curing in a curable composition, and a method of stabilizing a curable composition comprising a polythiol and at least one unsaturated compound comprising more than one carbon-carbon double bond, carbon-carbon triple bond, or a combination thereof are also disclosed. Z is not reactive with the polythiol or unsaturated compound.
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公开(公告)号:US20180094097A1
公开(公告)日:2018-04-05
申请号:US15565952
申请日:2016-04-29
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Susan E. DeMoss , Sheng Ye , Andrew R. Davis , Tao Gong
IPC: C08G59/22 , C08G59/32 , C08G75/04 , C08L81/02 , C08L81/04 , C08L63/00 , C08G59/40 , C08G59/56 , C08G59/66 , C08G59/68
CPC classification number: C08G59/4021 , C08G59/22 , C08G59/32 , C08G59/56 , C08G59/66 , C08G59/686 , C08G75/02 , C08G75/04 , C08L63/00 , C08L81/02 , C08L81/04
Abstract: A method of making a polymer network. The method includes providing a composition including a polythiol having more than one thiol group and a polyepoxide having more than one epoxide group, applying a solution including a photolatent base catalyst to a surface of the composition, and subsequently exposing the composition to light. Upon exposure to light, the photolatent base catalyst photochemically generates a first amine and at least partially cures at least the surface of the composition to form the polymer network.
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公开(公告)号:US20180016480A1
公开(公告)日:2018-01-18
申请号:US15545849
申请日:2016-02-10
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Susan E. DeMoss , Jonathan D. Zook , Matthew Capel
IPC: C09J181/02 , C08G75/04 , C07C323/14 , C08G75/12 , C07C321/18
CPC classification number: C09J181/02 , C07C321/18 , C07C323/14 , C08G75/00 , C08G75/02 , C08G75/04 , C08G75/12 , C08L81/00 , C08L81/02
Abstract: Polythioether polymers, sealants containing polythioether polymers, and compounds useful as stabilizing monomers in the manufacture of polythioether polymers are provided. In many embodiments the polymers and sealants demonstrate reduced risk of spoilage that may be caused by low temperature storage of the polymer or uncured sealant. Compounds useful as stabilizing monomers include compounds according to formula I: CH2═CR1—CHR2—S—R3—S—CHR4—CR5═CH2 [I] wherein R1, R2, R4 and R5 are independently selected from —H, —CH3 or —C2H5, and wherein R3 is selected from divalent groups comprising 2-12 carbon atoms, 0-5 ether oxygen atoms and 0-5 thioether sulfur atoms, which may be straight, branched or cyclic.
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公开(公告)号:US09650150B2
公开(公告)日:2017-05-16
申请号:US14783913
申请日:2014-04-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Larry S. Hebert , Michael D. Swan , Sheng Ye , Susan E. DeMoss , Robin E. Wright
CPC classification number: B64D37/06 , B64D37/02 , B64D45/02 , F16B33/004 , F16B37/14
Abstract: The present disclosure provides methods and articles useful in sealing fasteners, including seal caps and in particular translucent or transparent seals or seal caps. In some embodiments, a seal cap which is optically translucent and optionally visibly transparent contains an uncured sealant, which is optionally optically translucent or visibly transparent, and is applied to a fastener. In some embodiments, the sealant is cured by application of actinic radiation to the sealant through the seal cap. In another aspect, a protected fastener construction is provided comprising: q) a fastener; r) a seal cap; and s) a cured sealant; wherein the sealant is optically translucent and optionally visibly transparent.
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