Titanium part having an etched surface

    公开(公告)号:US11511519B2

    公开(公告)日:2022-11-29

    申请号:US16867200

    申请日:2020-05-05

    Applicant: Apple Inc.

    Abstract: This application relates to a part for a portable electronic device. The part includes a titanium alloy substrate including a network of branching channels. The branching channels include a first channel and a second channel, where the first channel is defined by a first channel wall that extends away from a first opening in the exterior surface, and the second channel is defined by a second channel wall that extends away from a second opening in the first channel wall.

    Using dispersion agents to chemically stabilize dyeing of metal parts

    公开(公告)号:US10669642B2

    公开(公告)日:2020-06-02

    申请号:US15715014

    申请日:2017-09-25

    Applicant: Apple Inc.

    Abstract: This application relates to a part that includes a metal oxide layer having pore structures. In some embodiments, dye molecules having aromatic rings can be disposed within at least one of the pore structures. Additionally, the at least one pore structures can include dispersion molecules, where the dispersion molecules form non-covalent interactions with the dye molecules. By forming non-covalent interactions between the dye molecules and the dispersion molecules, the aromatic rings of the dye molecules are prevented from forming other non-covalent interactions with other dye molecules. Additionally, techniques for chemically stabilizing the color dye bath for dyeing anodized parts are also described.

    Durable cosmetic finishes for titanium surfaces

    公开(公告)号:US10151021B2

    公开(公告)日:2018-12-11

    申请号:US14965716

    申请日:2015-12-10

    Applicant: Apple Inc.

    Abstract: A method for providing a surface finish to a metal part includes both diffusion hardening a metal surface to form a diffusion-hardened layer, and oxidizing the diffusion-hardened layer to create an oxide coating thereon. The diffusion-hardened layer can be harder than an internal region of the metal part and might be ceramic, and the oxide coating can have a color that is different from the metal or ceramic, the color being unachievable only by diffusion hardening or only by oxidizing. The metal can be titanium or titanium alloy, the diffusion hardening can include carburizing or nitriding, and the oxidizing can include electrochemical oxidization. The oxide layer thickness can be controlled via the amount of voltage applied during oxidation, with the oxide coating color being a function of thickness. An enhanced hardness profile can extend to a depth of at least 20 microns below the top of the oxide coating.

    PROCESSES TO AVOID ANODIC OXIDE DELAMINATION OF ANODIZED HIGH STRENGTH ALUMINUM ALLOYS
    39.
    发明申请
    PROCESSES TO AVOID ANODIC OXIDE DELAMINATION OF ANODIZED HIGH STRENGTH ALUMINUM ALLOYS 审中-公开
    避免阳极氧化分层的高强度铝合金的工艺

    公开(公告)号:US20170051425A1

    公开(公告)日:2017-02-23

    申请号:US14830705

    申请日:2015-08-19

    Applicant: Apple Inc.

    CPC classification number: C22C21/10 C25D11/04 C25D11/08 C25D11/16

    Abstract: Methods of forming anodic oxide coatings on high strength aluminum alloys are described. Methods involve preventing or reducing the formation of interface-weakening species, such as zinc-sulfur compounds, at an interface between an anodic oxide coating and underlying aluminum alloy substrate during anodizing. In some embodiments, a micro-alloying element is added in very small amounts to an aluminum alloy substrate to prevent enrichment of zinc at the anodic oxide and substrate interface, thereby reducing or preventing formation of the zinc-sulfur interface-weakening species. In some embodiments, a sulfur-scavenging species is added to an aluminum alloy substrate to prevent sulfur from a sulfuric acid anodizing bath from binding with zinc and forming the zinc-sulfur interface-weakening species at the anodic oxide and substrate interface. In some embodiments, a micro-alloying element and a sulfur-scavenging species are added to an aluminum alloy substrate. Resultant anodic oxide coatings have minimal or no discoloration.

    Abstract translation: 描述了在高强度铝合金上形成阳极氧化物涂层的方法。 方法包括在阳极氧化期间在阳极氧化物涂层和下面的铝合金基底之间的界面处防止或减少界面弱化物质如锌 - 硫化合物的形成。 在一些实施方案中,微合金元素以非常少的量添加到铝合金基底以防止锌在阳极氧化物和基底界面处的富集,从而减少或防止锌 - 硫界面弱化物质的形成。 在一些实施方案中,将硫清除物质加入到铝合金基底中以防止硫酸阳极氧化浴中的硫与锌结合并在阳极氧化物和基底界面处形成锌 - 硫界面弱化物质。 在一些实施方案中,将微合金元素和除硫物质加入到铝合金基底中。 所得的阳极氧化物涂层具有最小或无变色。

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