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公开(公告)号:DE10307233A1
公开(公告)日:2004-08-26
申请号:DE10307233
申请日:2003-02-14
Applicant: BASF AG
Inventor: ASPRION NORBERT , GROSMANN CHRISTOPH , HEGNER BERND , RUHNKE JUERGEN , KATZ TORSTEN
Abstract: Method for simulation of mass transport controlled separation processes in which a core-film layer is used to describe a mass exchange taking place at a phase border (P). According to the approach, an iterative solution of an implicit differential equation system is undertaken for discretization of an observed transfer area (10) of the core-film layer, from which the differential equation system, especially based on the Stefan-Maxwell equation, is generated. An independent claim is made for a device for simulation of mass transport controlled separation processes in which a core-film layer is used to describe a mass exchange taking place at a phase border.
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公开(公告)号:DE10210729A1
公开(公告)日:2003-10-02
申请号:DE10210729
申请日:2002-03-12
Applicant: BASF AG
Inventor: ASPRION NORBERT , GROSMANN CHRISTOPH
IPC: B01D19/00 , B01D53/14 , B01D53/78 , C07C215/08 , C07D295/00
Abstract: Disclosed is a method for deacidifying a fluid stream containing acidic gases as contaminants, according to which the fluid stream is brought into intimate contact with a washing liquid in at least one absorption step. Said washing liquid represents an aqueous solution containing a) tertiary aliphatic alkanolamines (alkanolamine A), at least 30 percent by weight of said tertiary aliphatic alkanolamines being 3-dimethylamino-1-propanol, and b) secondary aliphatic amines (activator B), at least 20 percent by weight of said secondary aliphatic amines being piperazin. The fluid stream which has been essentially purified of the acidic gases is then separated from the washing liquid that is loaded with acidic gases.
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公开(公告)号:DE59906371D1
公开(公告)日:2003-08-28
申请号:DE59906371
申请日:1999-06-23
Applicant: BASF AG
Inventor: GROSSMANN CHRISTOPH , HAENZEL KARL-HEINZ , KOLASSA DIETER , ASPRION NORBERT
Abstract: A process for removing acidic gas constituents, of the group consisting of CO2, H2S, COS, CS2 and mercaptans, from gases, in which, in an absorption step, a dirty gas rich in acidic gas constituents is brought into contact with an absorption medium, as a result of which a clean gas low in acidic gas constituents and an absorption medium laden with acidic gas constituents are obtained, the absorption medium used being a mixture comprisinga) from 0.1 to 50% by weight of one or more mono-cyclic or bicyclic nitrogen heterocycles which are unsubstituted and/or monosubstituted or poly-substituted on the carbon by OH, C1-C3 alkyl and/or C1-C3 hydroxyalkyl and which have from 5 to 14 ring atoms and 1 or 2 heterocyclically bound nitrogen atoms per ring as component A,b) from 1 to 60% by weight of a monohydric and/or polyhydric alcohol as component B,c) from 0 to 60% by weight of an aliphatic aminoalcohol as component C,d) from 0 to 98.9% by weight of water as component D,e) from 0 to 35% by weight of K2CO3 as component E,where the sum of components A, B, C, D and E is 100% by weight.
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公开(公告)号:DE10135370A1
公开(公告)日:2003-01-30
申请号:DE10135370
申请日:2001-07-20
Applicant: BASF AG
Inventor: ASPRION NORBERT , GROSMANN CHRISTOPH
Abstract: The invention relates to a method for the removal of acid gases from a gas flow, in which the gas flow containing an acid gas, having a sum of the partial pressures for the acid gases not exceeding 1500 mbar, is brought into contact with an aqueous absorption agent in an absorption step. The absorption agent used comprises methyldiethanolamine and piperazine in a concentration of at least 8 wt. % of the absorption agent. A gas flow with reduced acid gas content and an absorption agent loaded with acid gas are obtained.
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公开(公告)号:PE20001149A1
公开(公告)日:2000-10-25
申请号:PE00077599
申请日:1999-08-02
Applicant: BASF AG
Inventor: GROSSMANN CHRISTOPH , HANZEL KARL-HEINZ , KOLASSA DIETER , ASPRION NORBERT
Abstract: CARACTERIZADO POR: LA ABSORCION DE COMPONENTES GASEOSOS ACIDOS, TALES COMO CO2, H2S, COS, CS2 Y MERCAPTANOS, PONIENDO EN CONTACTO GAS NO TRATADO CON UN MEDIO DE ABSORCION QUE COMPRENDE : a) DE 0,1% A 50% EN PESO DE UNO O MAS HETEROCICLOS DE NITROGENO MONOCICLICO O BICICLICO, QUE SON INSUSTITUIDOS Y/O MONOSUSTITUIDOS O POLISUSTITUIDOS EN EL CARBONO POR OH, ALQUIL C1-C3 Y/O HIDROALQUIL C1-C3, LOS CUALES TIENEN DE 5 A 14 ANILLOS ATOMICOS Y 1 o 2 ATOMOS DE NITROGENO HETEROCICLICAMENTE ENLAZADOS POR ANILLO, DICHO HETEROCICLO ES DE PREFERENCIA PIPERAZINA; b) DE 1% A 60% EN PESO DE UN ALCOHOL MONOHIDRICO Y/O POLIHIDRICO, DE PREFERENCIA GLICEROL, 1,3-PROPANODIOL, NEOPENTIGLICOL O TRIMETILOLPROPANO; c) DE 0% A 60% EN PESO DE UN AMINOALCOHOL ALIFATICO, DE PREFERENCIA METILDIETANOLAMINA (MDEA); d) DE 0% A 98,9% EN PESO DE AGUA; Y e) DE 0% A 35% EN PESO DE K2CO3. ADEMAS, DICHO MEDIO LIQUIDO DE ABSORCION PUEDE COMPRENDER DE 0% HASTA 5% EN PESO DE DESESPUMANTES, INHIBIDORES Y FLOCULANTES, ADEMAS DE UNA ETAPA DE REGENERACION, EN DONDE LOS COMPONENTES GASEOSOS ACIDOS SE LIBERAN DEL MEDIO DE ABSORCION CARGADO PARA OBTENER UN MEDIO DE ABSORCION REGENERADO EL CUAL ES RECICLADO A LA ETAPA DE ABSORCION
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公开(公告)号:PE11492000A1
公开(公告)日:2000-10-25
申请号:PE00077599
申请日:1999-08-02
Applicant: BASF AG
Inventor: GROSSMANN CHRISTOPH , HANZEL KARL-HEINZ , KOLASSA DIETER , ASPRION NORBERT
CPC classification number: B01D53/1487 , B01D53/1456 , B01D53/1493 , C10K1/10 , C10K1/143 , C10L3/10
Abstract: CARACTERIZADO POR: LA ABSORCION DE COMPONENTES GASEOSOS ACIDOS, TALES COMO CO2, H2S, COS, CS2 Y MERCAPTANOS, PONIENDO EN CONTACTO GAS NO TRATADO CON UN MEDIO DE ABSORCION QUE COMPRENDE : a) DE 0,1% A 50% EN PESO DE UNO O MAS HETEROCICLOS DE NITROGENO MONOCICLICO O BICICLICO, QUE SON INSUSTITUIDOS Y/O MONOSUSTITUIDOS O POLISUSTITUIDOS EN EL CARBONO POR OH, ALQUIL C1-C3 Y/O HIDROALQUIL C1-C3, LOS CUALES TIENEN DE 5 A 14 ANILLOS ATOMICOS Y 1 o 2 ATOMOS DE NITROGENO HETEROCICLICAMENTE ENLAZADOS POR ANILLO, DICHO HETEROCICLO ES DE PREFERENCIA PIPERAZINA; b) DE 1% A 60% EN PESO DE UN ALCOHOL MONOHIDRICO Y/O POLIHIDRICO, DE PREFERENCIA GLICEROL, 1,3-PROPANODIOL, NEOPENTIGLICOL O TRIMETILOLPROPANO; c) DE 0% A 60% EN PESO DE UN AMINOALCOHOL ALIFATICO, DE PREFERENCIA METILDIETANOLAMINA (MDEA); d) DE 0% A 98,9% EN PESO DE AGUA; Y e) DE 0% A 35% EN PESO DE K2CO3. ADEMAS, DICHO MEDIO LIQUIDO DE ABSORCION PUEDE COMPRENDER DE 0% HASTA 5% EN PESO DE DESESPUMANTES, INHIBIDORES Y FLOCULANTES, ADEMAS DE UNA ETAPA DE REGENERACION, EN DONDE LOS COMPONENTES GASEOSOS ACIDOS SE LIBERAN DEL MEDIO DE ABSORCION CARGADO PARA OBTENER UN MEDIO DE ABSORCION REGENERADO EL CUAL ES RECICLADO A LA ETAPA DE ABSORCION
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公开(公告)号:CA2861539A1
公开(公告)日:2007-11-29
申请号:CA2861539
申请日:2007-05-11
Applicant: BASF AG
Inventor: ASPRION NORBERT , CLAUSEN IVEN , LICHTFERS UTE , WAGNER RUPERT
Abstract: A description is given of an absorption medium for removing carbon dioxide from a gas stream, which comprises an aqueous solution of at least one amine and at least one aminocarboxylic acid and/or aminosulfonic acid. The concomitant use of an aminocarboxylic acid or aminosulfonic acid reduces the energy required for regeneration of the absorption medium.
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公开(公告)号:CA2643667A1
公开(公告)日:2007-09-22
申请号:CA2643667
申请日:2007-03-16
Applicant: BASF AG
Inventor: GROBYS MAURICIO , ASPRION NORBERT
IPC: B01D53/14
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公开(公告)号:AU2006303219A1
公开(公告)日:2007-04-26
申请号:AU2006303219
申请日:2006-10-19
Applicant: BASF AG
Inventor: ANDERS JOACHIM-THIERRY , MELDER JOHANN-PETER , CLAUSEN IVEN , LICHTFERS UTE , BRETTSCHNEIDER OLE , ECK BERND , ASPRION NORBERT
IPC: B01D53/14
Abstract: A description is given of an absorption medium for removing carbon dioxide from gas streams which comprises aqueous solution of an amine of the formula I HNR2 (I) where one or both radicals R are and the other radical R is hydrogen. The absorption medium is distinguished by particular oxidation resistance.
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公开(公告)号:DE502004002449D1
公开(公告)日:2007-02-08
申请号:DE502004002449
申请日:2004-01-24
Applicant: BASF AG
Inventor: GROSSMANN CHRISTOPH , ASPRION NORBERT
Abstract: Absorbent (I) for removing acid gases (II) from fluids comprises (a) tertiary alkanolamine(s) and (b) an amine selected from hydroxyethylpiperazine, bis(hydroxyethylpiperazine or a mixture of these. An independent claim is also included for a process for absorption of (II) from fluid streams by contacting the fluid stream with absorbent (I) to give a fluid stream depleted in (II) and (I) charged with (II).
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