Abstract:
PROBLEM TO BE SOLVED: To purify the subject compound in an industrial scale and simple and sure manner by carrying out crystallization on cooling surface on which crystals of an imidazole compound are grown. SOLUTION: In a method for purifying either one of an imidazole of formula I (R to R are each H, a halogen, acetyl, carboxyl, a 1-20C alkyl, a 6-12C aryl, etc.), and an effective substance containing the imidazole as a base by crystallization, the crystallization is carried out on at least one cooling surface on which crystals of imidazole compound grows. The effective substance containing the imidazole as a base includes e.g. secnidazole of formula II or climbazole of formula III. In the purification, crystals of imidazole compound which grows on the cooling surface are preferably brought through the cooling surface into contact with a liquid mixture (preferably containing at least 80 wt.% imidazole compound) of a substance containing an imidazole compound to be purified and the cooling surface is cooled to form the corresponding crystals.
Abstract:
PROBLEM TO BE SOLVED: To increase the application range of crystallization and to obtain an economically advantageous method by controlling the partial pressure of the fluid component which is condensed from a liquid mixture containing a specified material to be isolated, to be lower than the partial pressure of the fluid component on a crystallization soln., and controlling the solidifying temp. of the liquid mixture to be lower than the condensation temp. in the liquid mixture. SOLUTION: The material to be isolated means inorg. salts, salts. of org. compds., solvates of these, and preferably hydrates present in a mixture with water or an org. solvent as a fluid. Or, it means a certain kind of org. component in such a mixture with water or an org. solvent that has a narrow boiling temp. range, however, the gas phase and the liquid phase in an equilibrium state under crystallization pressure and a crystallization temp. show
Abstract:
PROBLEM TO BE SOLVED: To provide a method for purifying acrylic acid or methacrylic acid, whereby high purity and a high yield of the acid are achieved. SOLUTION: (a) A mixture comprising the acrylic acid or methacrylic acid is subjected to a stringently defined separation treatment essentially in the absence of an organic solvent, this phase is then taken off, (b) at least a part of a residual phase from step (a) is subjected to a less stringently defined separation treatment, and (c) one of phases formed in step (b) is fed to the stringently defined separation treatment in step (a). This method offers a possibility that the overall economical efficiency of the treatment is increased through circulation and that the economical efficiency is improved even when static crystallization is omitted. COPYRIGHT: (C)2007,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a process for producing particles of neopentyl hydroxypivalate(NHP) free from the defects of conventional process while suppressing the generation of cake, provide a particulate NHP having low cake-generation rate and provide a process for granulating the particle with a granulator. SOLUTION: This process for the production of particulate NHP comprises the supply of a molten NHP containing >=3wt.% of NHP crystal based on the total weight of NHP to a cooling zone to solidify the molten NHP. A particulate NHP having low caking tendency can be produced by this process. The particles can be granulated by a method using a granulator for molten material provided with a precooling device 2, a precrystallizer 3, a liquid droplet forming machine 4 or a planar applicator, a cooling belt 6 and a crusher in the case of using a planar applicator.
Abstract:
The invention relates to a method for the production of a purified melt of a monomer melt obtained by condensation, absorption or extraction in a crystallizer, wherein the inlet to the crystallizer is subjected to a mechanical solid/liquid separation operation.
Abstract:
The invention relates to a method for obtaining pure N-vinyl pyrrolidone from raw materials containing N-vinyl pyrrolidone, said method comprising a single or multiple-stage crystallisation method. The method is characterised in that the mother liquor of the first crystallisation stage is either purified by distillation and/or extraction or is returned to a product stream of the production process, said stream containing an N-vinyl pyrrolidone.
Abstract:
The invention concerns a method for purifying (meth)acrylic acid by means of crystallization, whereby the (meth)acrylic acid is purified by combining at least two different dynamic crystallization methods, especially a suspension crystallization method and a layer crystallization method.
Abstract:
A description is given of an absorption medium for removing carbon dioxide from gas streams which comprises aqueous solution of an amine of the formula I HNR2 (I) where one or both radicals R are and the other radical R is hydrogen. The absorption medium is distinguished by particular oxidation resistance.
Abstract:
(METH)ACRYLIC ACID IS PURIFIED BY CRYSTALLIZATION BY A PROCESS IN WHICH THE (METH) ACRYLIC ACID IS PURIFIED BY A COMBINATION OF AT LEAST TWO DIFFERENT DYNAMIC CRYSTALLIZATION PROCESSES, IN PARTICULAR A SUSPENSION CRYSTALLIZATION AND A LAYER CRYSTALLIZATION.(FIG 1A)
Abstract:
A thermal separating process for removing a stream containing enriched (meth)acrylic monomers from a mixture containing (meth)acrylic monomers, in which the liquid phases retained in the separating space at high temperature and high (meth)acrylic monomer content are minimized.