-
公开(公告)号:AT261457T
公开(公告)日:2004-03-15
申请号:AT00977456
申请日:2000-10-31
Applicant: BASF AG
Inventor: DESBOIS PHILIPPE , WARZELHAN VOLKER , SCHADE CHRISTIAN , FONTANILLE MICHEL , DEFFIEUX ALAIN , MENORET STEPHANE
IPC: C08F2/38 , C08F2/44 , C08F4/44 , C08F4/48 , C08F4/52 , C08F4/54 , C08F12/00 , C08F12/04 , C08F36/00 , C08F36/04 , C08F291/00 , C08F297/04
Abstract: In a process for the anionic polymerization of vinylaromatic monomers or dienes in the presence of a lithium organyl or lithium alcoholate and a magnesium and/or an aluminum compound, a sterically hindered phenol or amine is added.
-
公开(公告)号:BR0015492A
公开(公告)日:2002-06-25
申请号:BR0015492
申请日:2000-10-31
Applicant: BASF AG
Inventor: DESBOIS PHILIPPE , WARZELHAN VOLKER , SCHADE CHRISTIAN , FONTANILLE MICHEL , DEFFIEUX ALAIN , MENORET STEPHANE
IPC: C08F2/38 , C08F2/44 , C08F4/44 , C08F4/48 , C08F4/52 , C08F4/54 , C08F12/00 , C08F12/04 , C08F36/00 , C08F36/04 , C08F291/00 , C08F297/04
Abstract: In a process for the anionic polymerization of vinylaromatic monomers or dienes in the presence of a lithium organyl or lithium alcoholate and a magnesium and/or an aluminum compound, a sterically hindered phenol or amine is added.
-
公开(公告)号:DE19806774A1
公开(公告)日:1999-08-19
申请号:DE19806774
申请日:1998-02-18
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , KLOSTERMANM RAINER , WARZELHAN VOLKER , FONTANILLE MICHEL , DEFFIEUX ALAIN , DESBOIS PHILIPPE
IPC: C08F4/52 , C08F4/46 , C08F4/50 , C08F12/04 , C08F236/10 , C08F279/02 , C08F297/06 , C08F12/00 , C08F236/00
Abstract: A process for the homopolymerization of vinyl aromatic monomers or copolymerization of vinyl aromatic monomers and dienes comprises polymerization of the monomers in the presence of at least an organoalkali metal, an organomagnesium compound and an organoaluminum compound. Independent claims are included for: (i) an initiator composition comprising an organoalkali metal, an organomagnesium compound and an organoaluminum compound, whereby the molar ratio of magnesium to the alkali metal is 0.2-3.8 and the molar ratio of aluminum to the alkali metal is 0.2-4; (ii) a process for the preparation of an initiator composition by dissolving the organometallic compounds in inert hydrocarbons and allowing the mixture to mature at 0-120 deg C for at least 5 minutes.
-
公开(公告)号:DE502004002993D1
公开(公告)日:2007-04-05
申请号:DE502004002993
申请日:2004-10-30
Applicant: BASF AG
Inventor: DESBOIS PHILIPPE , DEFFIEUX ALAIN , CARLOTTI STEPHANE , BILLOUARD CYRILLE
Abstract: The invention relates to a process for preparation of homopolymers composed of oxiranes, or of copolymers composed of oxirans and comonomers, via anionic polymerization, which comprises carrying out a polymerization in the presence of a quaternary ammonium and/or phosphonium compound and of a mononuclear organylaluminum compound.
-
公开(公告)号:DE102005012210A1
公开(公告)日:2006-09-28
申请号:DE102005012210
申请日:2005-03-15
Applicant: BASF AG
Inventor: DESBOIS PHILIPPE , DEFFIEUX ALAIN , CARLOTTI STEPHANE , SHCHEGLOVA LARISA
IPC: C08F236/00 , C08F2/38 , C08F212/00 , C08F212/08 , C08F236/06 , C08F236/08 , C08F279/02
Abstract: Preparation of homo- or copolymer comprises anionic polymerization of styrene monomer and/or diene monomer in the presence of an initiator composition comprising potassium hydride, at least one alkali metal compound from alkali metal alcoholate, alkali metal carboxylate or alkali metal amid and at least one aluminum organyl.
-
公开(公告)号:DE59910224D1
公开(公告)日:2004-09-16
申请号:DE59910224
申请日:1999-09-16
Applicant: BASF AG
-
公开(公告)号:DE10307058A1
公开(公告)日:2004-09-02
申请号:DE10307058
申请日:2003-02-19
Applicant: BASF AG
Inventor: DESBOIS PHILIPPE , ISHAQUE MICHAEL , SCHADE CHRISTIAN , DEFFIEUX ALAIN , CARLOTTI STEPHANE
IPC: C08F2/38 , C08F4/46 , C08F4/52 , C08F4/56 , C08F12/08 , C08F212/12 , C08F236/06 , C08F236/08
-
公开(公告)号:DE59908107D1
公开(公告)日:2004-01-29
申请号:DE59908107
申请日:1999-02-05
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , KLOSTERMANN RAINER , WARZELHAN VOLKER , FONTANILLE MICHEL , DEFFIEUX ALAIN , DESBOIS PHILIPPE
IPC: C08F4/52 , C08F4/46 , C08F4/50 , C08F12/04 , C08F236/10 , C08F279/02 , C08F297/06
Abstract: In a process for the homopolymerization of vinylaromatic monomers or the copolymerization of vinylaromatic monomers and dienes, the monomers are polymerized in the presence of at least one alkali metal organyl, at least one magnesium organyl and at least one aluminum organyl. The invention also provides an initiator composition for carrying out the process.
-
公开(公告)号:DE10065331A1
公开(公告)日:2002-07-04
申请号:DE10065331
申请日:2000-12-27
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , DESBOIS PHILIPPE , FISCHER WOLFGANG , GAUSEPOHL HERMANN , DEFFIEUX ALAIN , MINORET STEPHANE , FONTANILLE MICHEL
-
公开(公告)号:BR9908079A
公开(公告)日:2000-10-31
申请号:BR9908079
申请日:1999-02-05
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , KLOSTERMANN RAINER , WARZELHAN VOLKER , FONTANILLE MICHEL , DEFFIEUX ALAIN , DESBOIS PHILIPPE
IPC: C08F4/52 , C08F4/46 , C08F4/50 , C08F12/04 , C08F236/10 , C08F279/02 , C08F297/06
Abstract: In a process for the homopolymerization of vinylaromatic monomers or the copolymerization of vinylaromatic monomers and dienes, the monomers are polymerized in the presence of at least one alkali metal organyl, at least one magnesium organyl and at least one aluminum organyl. The invention also provides an initiator composition for carrying out the process.
-
-
-
-
-
-
-
-
-