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    MOULDINGS MADE OF THERMOPLASTIC MOULDING MASSES
    2.
    发明申请
    MOULDINGS MADE OF THERMOPLASTIC MOULDING MASSES 审中-公开
    热塑性塑料模具的制造

    公开(公告)号：WO9741174A3

    公开(公告)日：1997-12-11

    申请号：PCT/EP9702099

    申请日：1997-04-24

    Applicant: BASF AG ,  LINDENSCHMIDT GERHARD ,  ROSENAU BERNHARD ,  MC KEE GRAHAM EDMUND ,  FISCHER WOLFGANG

    Inventor： LINDENSCHMIDT GERHARD ,  ROSENAU BERNHARD ,  MC KEE GRAHAM EDMUND ,  FISCHER WOLFGANG

    IPC: C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L ,  C08J ,  E04B

    CPC classification number: C08L25/12 ,  C08L51/003 ,  C08L51/04 ,  C08L2666/24 ,  C08L2666/04

    Abstract: Mouldings made of thermoplastic moulding masses contain (A) 30 to 99 wt %, relative to the total weight of the moulding mass, of a thermoplastic polymer, comprising, relative to (A): (a1) 50 to 100 wt % of a styrene compound of general formula (I), in which R?1 and R2¿ stand for hydrogen or C¿1?-C8 alkyl, or a (C1-C8-alkyl)ester of acrylic or methacrylic acid, or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (a2) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (a3) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers different from (a2); (b) 1 to 70 wt %, with respect to the total weight of the moulding mass, of a graft polymer comprising, relative to (B): (b1) 30 to 90 wt % of a rubber-elastic grafted core made of a polymer with a glass transition temperature below 0 °C and obtained by copolymerising (b11) 50 to 99.99 wt %, with respect to (b1), of a (C1-C10-alkyl)ester of acrylic acid; (b12) 0.01 to 10 wt % of a polyfunctional, cross-linking monomer; and (b13) 0 to 40 wt % of one or several others monoethylenically unsaturated monomers different from (b11); and (b2) 10 to 70 wt % of a grafted sheath which contains, relative to (b2): (b21) 50 to 100 wt % of a styrene compound of general formula (I), in which R?1 and R2¿ stand for hydrogen or C¿1?-C8-alkyl; or a (C1-C8-alkyl)ester of acrylic acid or methacrylic acid; or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (b22) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (b23) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers.

    5.
    发明专利
    未知

    公开(公告)号：AT366280T

    公开(公告)日：2007-07-15

    申请号：AT05701330

    申请日：2005-02-03

    Applicant: BASF AG

    Inventor： STORK MARTIN ,  WEBER MARTIN ,  GOTTSCHALK AXEL ,  RIECHERS SVEN ,  GUENTHERBERG NORBERT ,  FISCHER WOLFGANG ,  LEBER LUDGER ,  ITTEMANN PETER ,  JUENGLING STEPHAN ,  DUIJZINGS WIL

    IPC: C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08F285/00 ,  C08L55/02

    Abstract: The invention relates to thermoplastic moulding materials containing a mixture of (A) between 30 and 69 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a methylmethacrylate polymer, (B) between 30 and 69 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a copolymer that can be obtained by the polymerisation of a vinylaromatic monomer and a vinylcyanide, and (C) between 1 and 40 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a graft copolymer that can be obtained from (C1) between 60 and 90 wt. %, in relation to (C), of a core, (C2) between 5 and 20 wt. %, in relation to (C), of a first graft envelope consisting of a vinylaromatic monomer, an alkylmethacrylate and optionally a cross-linking monomer, and (C3) between 5 and 20 wt. %, in relation to (C), of a second graft envelope consisting of an alkyl(meth)acrylate polymer, on the proviso that the quantitative ratio of (C2) to (C3) is between 2:1 and 1:2. The invention is characterised in that the average particle size D50 of the core (C1) is between 50 and 250 nm, the average particle size D90 of the core (C1) is between 60 and 1000 nm, the average particle size D90 of the core (C1) being larger than the average particle size D50 of the core (C1), by a factor between 1.15 and 20, and the core (C1) can be obtained by the polymerisation of a monomer mixture comprising (C11) between 65 and 89 wt. %, in relation to (C1), of a 1,3-diene, (C12) between 10 and 34.9 wt. %, in relation to (C1), of a vinylaromatic monomer, and (C13) between 0.1 and 5 wt. %, in relation to (C1), of an agglomeration polymer. The invention also relates to a method for producing said moulding masses, to the use thereof, and to the moulded bodies obtained therefrom.

    6.
    发明专利
    未知

    公开(公告)号：ES2207956T3

    公开(公告)日：2004-06-01

    申请号：ES99934213

    申请日：1999-01-26

    Applicant: BASF AG

    Inventor： FISCHER WOLFGANG ,  BUCHNER EUGEN-WALTER ,  DEIMLING AXEL ,  GAUSEPOHL HERMANN ,  SCHADE CHRISTIAN

    IPC: C08F2/00 ,  C08F279/02 ,  C08F287/00 ,  B01J19/18

    Abstract: A process for preparing impact-modified styrene polymers (HIPS) omprises anionic polymerization of styrene in the presence of a rubber in one or more polymerization reactors in succession. The rubber is prepared in solution in an immediately upstream process. The heat of polymerization is utilized to remove the solvent for the rubber, this solvent having a boiling point lower than those of styrene and ethylbenzene, from at least one of the polymerization reactors via distillation with distillative cooling, and the solvent is reintroduced into the process of rubber preparation.

    9.
    发明专利
    未知

    公开(公告)号：DE59805907D1

    公开(公告)日：2002-11-14

    申请号：DE59805907

    申请日：1998-06-29

    Applicant: BASF AG

    Inventor： KNOLL KONRAD ,  KINDLER ALOIS ,  FISCHER WOLFGANG

    IPC: C08L53/00 ,  C08C19/44 ,  C08F4/00 ,  C08F297/00 ,  C08F297/02 ,  C08F297/04 ,  C08G81/02

    Abstract: New oximsulfonate compounds of formulae (I) or (II), wherein m is 0 or 1; x is 1 or 2; R1 is, for example phenyl, which is unsubstituted or substituted or R1 is a heteroaryl radical that is unsubstituted or substituted, or, if m is 0, R1 additionally is C2-C6alkoxycarbonyl, phenoxycarbonyl or CN; R'1 is for example C2-C12alkylene, phenylene; R2 has for example one of the meanings of R1; n is 1 or 2; R3 is for example C1-C18alkyl, R'3 when x is 1, has one of the meanings given for R3, or R'3 in formula (IV) and when x is 2 in formula (I), is for example C2-C12 alkylene, phenylene; R4 and R5 are independently of each other for example hydrogen, halogen, C1-C6alkyl; R6 is for example hydrogen, phenyl; R7 and R8 are independently of each other for example hydrogen or C1-C12alkyl; R9 is for example C1-C12alkyl; A is S, O, NR6, or a group of formula (A1), (A2), (A3) or (A4); R10 and R11 independently of each other have one of the meanings given for R4; R12, R13, R14 and R15 independently of one another are for example hydrogen, C1-C4alkyl; Z is CR11 or N; Z1 is -CH2-, S, O or NR6, are useful as latent sulfonic acids, especially in photoresist applications.

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