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公开(公告)号:CH513961A
公开(公告)日:1971-10-15
申请号:CH849769
申请日:1969-06-04
Applicant: BASF AG
Inventor: HOLZER KLAUS DR , MUELLER ALFRED DR , DOTZAUER BERNHARD DR
IPC: C09J7/02 , C09J133/06 , C09J3/14
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公开(公告)号:DE1669731A1
公开(公告)日:1971-07-22
申请号:DE1669731
申请日:1967-10-25
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WELZEL GERHARD DR
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公开(公告)号:DE59203505D1
公开(公告)日:1995-10-12
申请号:DE59203505
申请日:1992-01-09
Applicant: BASF AG
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公开(公告)号:AT127494T
公开(公告)日:1995-09-15
申请号:AT92100251
申请日:1992-01-09
Applicant: BASF AG
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公开(公告)号:DK0469295T3
公开(公告)日:1995-02-13
申请号:DK91110520
申请日:1991-06-26
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WISTUBA ECKEHARDT DR , SCHWARTZ MANFRED DR , PETRI ROLF , BECHERT BERTOLD
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公开(公告)号:DE59103764D1
公开(公告)日:1995-01-19
申请号:DE59103764
申请日:1991-06-26
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WISTUBA ECKEHARDT DR , SCHWARTZ MANFRED DR , PETRI ROLF , BECHERT BERTOLD
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公开(公告)号:ES2060716T3
公开(公告)日:1994-12-01
申请号:ES89119326
申请日:1989-10-18
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , BECKERLE WILHELM FRIEDRICH , DENU HANS-JURGEN , WENDEL KURT DR , SCHWARTZ MANFRED DR
IPC: B27N3/04 , C04B26/06 , C08K3/00 , C08K3/013 , C08K7/00 , C08K7/02 , C08L33/04 , C08L33/12 , D21J1/00
Abstract: The invention relates to the production of mouldings based on a particulate material as additive and an aqueous binding agent containing an acrylate polymer, the additive being moistened with the binding agent, converted into the desired shape and subsequently dried, characterised in that a binding agent is employed whose binder is an acrylate polymer whose glass transition range is relatively high and which is built up from (A) predominantly methyl methacrylate, (B) a minor amount of (meth)acrylic acid, (C) if desired, a minor amount of an alkyl ester of acrylic acid and (D) if desired, a small amount of other specific polymerisable compounds.
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公开(公告)号:ES2059022T3
公开(公告)日:1994-11-01
申请号:ES91120931
申请日:1991-12-06
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WISTUBA ECKEHARDT DR , SCHWARTZ MANFRED DR , PETRI ROLF , BECHERT BERTOLD , DENU HANS-JURGEN
IPC: C04B41/48 , C04B41/62 , C04B41/63 , C09D133/06
Abstract: A concrete tile (I) is claimed, which is coated with a copolymer (A) with Tg -25 to +30 deg.C, derived from (a) 0.1-10 wt.% monomer of formula R1CH=CR2-CO-X-R3-Z-CHR4R5 (III), (b) 85-99.9 wt.% at least 2 monomers of the type (1-24C alkyl) (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, 3-6C unsatd. nitriles, vinyl halides and/or 2-8C non-aromatic hydrocarbons with olefinic double bond(s), and (c) 0-10 wt.% other Sn-free comonomers; R1, R2 = H or 1-4C alkyl; R3 = 1-20C bridging gp.; R4 = -COR6, -COOR6 or CN; R5 = H, -COR9, -COOR9 or CN; X = O or NR7; Z = single bond, CH2, O, NR8 or -OCO-; (with R6-R9 = H, or 1-12C alkyl, aryl, alkaryl or aralkyl). Also claimed is a process for the prodn. of (I), by application of an aq. prepn. contg. (A) to at least one surface of the green concrete, and drying the prepn. by hardening the concrete. More specifically, monomer (a) is acetylacetoxyethyl (meth)acrylate, acetylacetoxybutyl (meth)acrylate, cyanoacetoxyethyl (meth)acrylate, 1,1-dibenzoyl-2-(meth)acrylamidoethane, 1-benzoyl-1-acetyl-2- (meth)acrylamidoethane, or ethyl alpha-benzoyl-beta-(meth) acrylamidopropionate, and (b) are vinylaromatics or (1-8C alkyl) (meth)acrylates; (I) is coated with a prepn. contg. copolymer (A) and up to 450 wt.% mineral additives (B) and/or colour pigments (C) (w.r.t. amt. of A); another layer of the aq. prepn. is applied to the hardened tile and dried; the amt. of prepn. used is such that the total amt. of dry coating is 50-500 g/m2.
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公开(公告)号:DE59103044D1
公开(公告)日:1994-10-27
申请号:DE59103044
申请日:1991-12-06
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WISTUBA ECKEHARDT DR , SCHWARTZ MANFRED DR , PETRI ROLF , BECHERT BERTOLD , DENU HANS-JUERGEN
IPC: C04B41/48 , C04B41/62 , C04B41/63 , C09D133/06
Abstract: A concrete tile (I) is claimed, which is coated with a copolymer (A) with Tg -25 to +30 deg.C, derived from (a) 0.1-10 wt.% monomer of formula R1CH=CR2-CO-X-R3-Z-CHR4R5 (III), (b) 85-99.9 wt.% at least 2 monomers of the type (1-24C alkyl) (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, 3-6C unsatd. nitriles, vinyl halides and/or 2-8C non-aromatic hydrocarbons with olefinic double bond(s), and (c) 0-10 wt.% other Sn-free comonomers; R1, R2 = H or 1-4C alkyl; R3 = 1-20C bridging gp.; R4 = -COR6, -COOR6 or CN; R5 = H, -COR9, -COOR9 or CN; X = O or NR7; Z = single bond, CH2, O, NR8 or -OCO-; (with R6-R9 = H, or 1-12C alkyl, aryl, alkaryl or aralkyl). Also claimed is a process for the prodn. of (I), by application of an aq. prepn. contg. (A) to at least one surface of the green concrete, and drying the prepn. by hardening the concrete. More specifically, monomer (a) is acetylacetoxyethyl (meth)acrylate, acetylacetoxybutyl (meth)acrylate, cyanoacetoxyethyl (meth)acrylate, 1,1-dibenzoyl-2-(meth)acrylamidoethane, 1-benzoyl-1-acetyl-2- (meth)acrylamidoethane, or ethyl alpha-benzoyl-beta-(meth) acrylamidopropionate, and (b) are vinylaromatics or (1-8C alkyl) (meth)acrylates; (I) is coated with a prepn. contg. copolymer (A) and up to 450 wt.% mineral additives (B) and/or colour pigments (C) (w.r.t. amt. of A); another layer of the aq. prepn. is applied to the hardened tile and dried; the amt. of prepn. used is such that the total amt. of dry coating is 50-500 g/m2.
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公开(公告)号:AT111878T
公开(公告)日:1994-10-15
申请号:AT91120931
申请日:1991-12-06
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WISTUBA ECKEHARDT DR , SCHWARTZ MANFRED DR , PETRI ROLF , BECHERT BERTOLD , DENU HANS-JUERGEN
IPC: C04B41/48 , C04B41/62 , C04B41/63 , C09D133/06
Abstract: A concrete tile (I) is claimed, which is coated with a copolymer (A) with Tg -25 to +30 deg.C, derived from (a) 0.1-10 wt.% monomer of formula R1CH=CR2-CO-X-R3-Z-CHR4R5 (III), (b) 85-99.9 wt.% at least 2 monomers of the type (1-24C alkyl) (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, 3-6C unsatd. nitriles, vinyl halides and/or 2-8C non-aromatic hydrocarbons with olefinic double bond(s), and (c) 0-10 wt.% other Sn-free comonomers; R1, R2 = H or 1-4C alkyl; R3 = 1-20C bridging gp.; R4 = -COR6, -COOR6 or CN; R5 = H, -COR9, -COOR9 or CN; X = O or NR7; Z = single bond, CH2, O, NR8 or -OCO-; (with R6-R9 = H, or 1-12C alkyl, aryl, alkaryl or aralkyl). Also claimed is a process for the prodn. of (I), by application of an aq. prepn. contg. (A) to at least one surface of the green concrete, and drying the prepn. by hardening the concrete. More specifically, monomer (a) is acetylacetoxyethyl (meth)acrylate, acetylacetoxybutyl (meth)acrylate, cyanoacetoxyethyl (meth)acrylate, 1,1-dibenzoyl-2-(meth)acrylamidoethane, 1-benzoyl-1-acetyl-2- (meth)acrylamidoethane, or ethyl alpha-benzoyl-beta-(meth) acrylamidopropionate, and (b) are vinylaromatics or (1-8C alkyl) (meth)acrylates; (I) is coated with a prepn. contg. copolymer (A) and up to 450 wt.% mineral additives (B) and/or colour pigments (C) (w.r.t. amt. of A); another layer of the aq. prepn. is applied to the hardened tile and dried; the amt. of prepn. used is such that the total amt. of dry coating is 50-500 g/m2.
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