公开(公告)号：DE4216315A1

公开(公告)日：1993-11-18

申请号：DE4216315

申请日：1992-05-16

Applicant: BASF AG

Inventor： BECKER RAINER DR ,  GRAMLICH WALTER DR ,  HUELLMANN MICHAEL DR ,  SCHOLZ HANS-ULRICH DR

IPC: C07B61/00 ,  C07C29/56 ,  B01J23/36 ,  C07C33/035

Abstract: The preparation of vinyl glycols (I) (R to R = H, C-organic radical, optionally substituted> by isomerizing an unsaturated diol (II) under neutral conditions in the presence of a rhenium catalyst. The compounds (I) are used as intermediates in the preparation of active ingredients and in the preparation of polymers.

公开(公告)号：DE3777052D1

公开(公告)日：1992-04-09

申请号：DE3777052

申请日：1987-08-25

Applicant: BASF AG

Inventor： GRAMLICH WALTER DR ,  HOFFMANN WERNER DR ,  SCHUSTER LUDWIG DR

IPC: A61K8/00 ,  A61K8/33 ,  A61K8/37 ,  A61Q13/00 ,  C07C29/20 ,  C07C41/00 ,  C07C41/20 ,  C07C43/184 ,  C07C67/00 ,  C07C67/08 ,  C07C69/03 ,  C07C69/06 ,  C07C69/14 ,  C07C69/24 ,  C11B9/00 ,  C11D3/50 ,  A61K7/46

Abstract: New 2-tert. butyl-4-methyl-cyclohexyl derivs. have formula (I) R1=1-3C alkyl or an acyl gp. having formula (a), where R2=1-5C alkyl. Cpds. are (Ii) 2-tert. butyl-4-methyl- cyclohexyl formate, (Iii) 2-tert. butyl-4-methyl -cyclohexyl acetate, (Iiii) 2-tert. butyl-4-methyl -cyclohexyl propionate, (Viv) 2-tert. butyl-4-methyl -1-methoxy-cyclohexane.

公开(公告)号：DE3760415D1

公开(公告)日：1989-09-14

申请号：DE3760415

申请日：1987-12-15

Applicant: BASF AG

Inventor： DEGNER DIETER DR ,  GRAMLICH WALTER DR ,  HANNEBAUM HEINZ

IPC: A61K8/35 ,  A61K8/00 ,  A61Q13/00 ,  C07C41/00 ,  C07C43/315 ,  C07C45/00 ,  C07C47/575 ,  C07C67/00 ,  C11B9/00 ,  C25B3/23 ,  C25B3/02 ,  A61K7/46

Abstract: Benzaldehyde derivatives of the general formula I, where X is an oxygen atom or two R2O groups and R1 and R2 are alkyl radicals of 1-4 carbon atoms, their preparation, and their use as odorants or odorant intermediates. I

公开(公告)号：DE3664761D1

公开(公告)日：1989-09-07

申请号：DE3664761

申请日：1986-05-09

Applicant: BASF AG

Inventor： GRAMLICH WALTER DR ,  SCHUSTER LUDWIG DR

IPC: A23L27/00 ,  A23L27/20 ,  A61K8/31 ,  A61K8/34 ,  A61K8/35 ,  A61K8/37 ,  A61Q13/00 ,  C07C27/00 ,  C07C31/135 ,  C07C41/00 ,  C07C43/04 ,  C07C43/115 ,  C07C45/00 ,  C07C45/62 ,  C07C49/303 ,  C07C67/00 ,  C07C69/02 ,  C07C69/14 ,  C11B9/00 ,  C11D3/50 ,  A23L1/226 ,  A61K7/46

公开(公告)号：DE3664468D1

公开(公告)日：1989-08-24

申请号：DE3664468

申请日：1986-10-22

Applicant: BASF AG

Inventor： GRAMLICH WALTER DR ,  SIEGEL HARDO DR

IPC: C07D321/00 ,  A61K8/49 ,  A61Q13/00 ,  C07D321/06 ,  C07D407/04 ,  C11B9/00 ,  C11D3/50 ,  A61K7/46

Abstract: Substituted 4-methyl-4,7-dihydro-1,3-dioxepins of the general formula I (I) where R1 is an alkyl of 1 to 12 carbon atoms which may furthermore contain oxygen in the form of an ether group, or a 5-membered to 8-membered ring which is unsubstituted or substituted by alkyl groups and/or an alkylene group, has up to 10 carbon atoms and may furthermore contain oxygen in the form of an ether group, and R2, R3 and R4 are each hydrogen or methyl, with the exception of the compound 2-tert-butyl-4,7-dihydro-4,7-dimethyl-1,3-dioxepin, the preparation of substituted 4-methyl-4,7-dihydro-1,3-dioxepins and their use as scents and aromas, and scent compositions containing these compounds.

公开(公告)号：DE3713732A1

公开(公告)日：1988-11-17

申请号：DE3713732

申请日：1987-04-24

Applicant: BASF AG

Inventor： DEGNER DIETER DR ,  GRAMLICH WALTER DR ,  LANZENDOERFER FRANZ DR ,  SIEGEL HARDO DR

IPC: C07C41/00 ,  C07C43/315 ,  C07C67/00 ,  C11B9/00 ,  C25B3/23 ,  C25B3/02 ,  A61K7/46 ,  C07C47/575

Abstract: Benzaldehyde dialkyl acetals of the formula where R is alkyl of 1 to 4 carbon atoms, are prepared by electrochemical oxidation of 3-tert-butyl-4-methoxytoluene in the presence of an alkanol of the formula ROH and are used as scents or scent intermediates.

公开(公告)号：DE3639158A1

公开(公告)日：1988-05-26

申请号：DE3639158

申请日：1986-11-15

Applicant: BASF AG

Inventor： MARTIN ROLAND DR ,  GRAMLICH WALTER DR

IPC: A61K8/40 ,  A61Q13/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/32 ,  C07C255/33 ,  C11B9/00 ,  C11D3/50 ,  C07C121/75 ,  C07C120/00 ,  A61K7/46 ,  C11D9/44

Abstract: 2-methyl-3-(p-methylphenyl)-propionitrile is prepared for use as a scent.

公开(公告)号：DE3469444D1

公开(公告)日：1988-03-31

申请号：DE3469444

申请日：1984-06-15

Applicant: BASF AG

Inventor： DEGNER DIETER DR ,  HANNEBAUM HEINZ ,  SIEGEL HARDO DR ,  GRAMLICH WALTER DR

IPC: C07C43/307 ,  C25B3/23 ,  C25B3/02

Abstract: Benzaldehyde dialkyl acetals of the formula I wherein R1 and R2 are each alkyl, are prepared by electrochemical oxidation of an alkyltoluene of the formula II by a process in which the electrolyte used contains from 60 to 90% by weight of an alkanol of the formula R2OH, from 8.5 to 40% by weight of the alkyltoluene and from 0.01 to 1.5% by weight of an HO3S-containing acid.

公开(公告)号：DE3622600A1

公开(公告)日：1988-01-14

申请号：DE3622600

申请日：1986-07-05

Applicant: BASF AG

Inventor： GRAMLICH WALTER DR ,  SIEGEL HARDO DR

IPC: A61K8/33 ,  A61K8/00 ,  A61Q13/00 ,  C07C45/00 ,  C07C45/62 ,  C07C45/73 ,  C07C45/74 ,  C07C47/02 ,  C07C47/21 ,  C07C67/00 ,  C11B9/00 ,  C11D3/50 ,  C07C45/72 ,  C07C45/65 ,  A61K7/46

Abstract: Aliphatic aldehydes of the general formula I (I) where R1 is hydrogen or methyl, R2 is a straight-chain or branched alkyl radical of 1 to 4 carbon atoms and the two radicals X are each hydrogen or together form a further C-C bond, in particular 2,5,7,7-tetramethyloctanal, 2,4,5,7,7-pentamethyloctanal, 2-ethyl-5,7,7-trimethyloctanal and 2,5,7,7-tetramethyl-2-octen-1-al, are used in scent compositions and are prepared by a process in which an aldehyde of the general formula II (II) is condensed with an aldehyde of the general formula III (III) in the presence of an aldol condensation catalyst to give the substituted octenal of the general formula I, and, if required, the latter is partially hydrogenated or reduced to give the ocorresponding octanal of the formula I.

公开(公告)号：DE3460472D1

公开(公告)日：1986-09-18

申请号：DE3460472

申请日：1984-05-22

Applicant: BASF AG

Inventor： GRAMLICH WALTER DR ,  HOFFMANN WERNER DR ,  HUPFER LEOPOLD DR ,  MERGER FRANZ DR ,  PAETSCH JUERGEN DR

IPC: C07C45/73 ,  C07C45/74 ,  C07C49/04