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    PRODUCTION OF N-SUBSTITUTED CYCLIC AMINE
    1.
    发明专利
    PRODUCTION OF N-SUBSTITUTED CYCLIC AMINE 失效

    公开(公告)号：JPH1072454A

    公开(公告)日：1998-03-17

    申请号：JP15828297

    申请日：1997-06-16

    Applicant: BASF AG

    Inventor： SIMON JOACHIM DR ,  DOSTALEK ROMAN DR ,  LINGK HEINZ ,  BECKER RAINER DR ,  HENNE ANDREAS DR ,  ROLF REEPUKYUUHIYAA ,  FREIRE ERDBRUEGGER CRISTINA DR ,  HESSE MICHAEL DR ,  KRATZ DETLEF DR

    IPC: C07D295/02 ,  B01J23/72 ,  B01J37/02 ,  C07B61/00 ,  C07D295/03

    Abstract: PROBLEM TO BE SOLVED: To enable to industrially simply and profitably obtain the subject compound from a primary amine and a diol by using a specific copper- containing hydrogenation/dehydrogenation catalyst. SOLUTION: This method for producing an N-substituted cyclic amine of formula I comprises reacting (C) a compound of the formula: R -NH2 [R is an (alkoxy)alkyl, an aryl, etc.,] with (D) a compound of the formula: HO-A-OH A is an alkylene (substituted by a group of the formula: R (R is R ), a group of the formula: (CH2 )n -[O-(CH )m ]r , [(m), (n) are each 2-8; (r) is 1-3]} in the presence of a coppercontaining catalyst. The copper-containing catalyst is obtained by impregnating an inactive carrier (e.g. silicon dioxide, a silicate or zeolite) with (A) hydrogen and (B) the aqueous ammine complex solution of an easily pyrolytic copper compound (e.g. copper carbonate, copper oxalate or copper formate)(preferably an ammoniacal copper carbonate solution), drying the impregnated carrier, and subsequently calcining the dried product, and contains the copper in an amount of 5-50wt.% converted into CuO on the basis of the whole amount of the calcined catalyst.

    Verfahren zur stereoselektiven Herstellung von (-)3a,6,6,9a-Tetramethyl-perhydronaphtho[2,1-b]furan
    2.
    发明公开
    Verfahren zur stereoselektiven Herstellung von (-)3a,6,6,9a-Tetramethyl-perhydronaphtho[2,1-b]furan 失效
    （f）（ - ）3a，6,6,9a-四甲基 - 过氢萘甲酰[2,1-b]呋喃的Verfahren zur stereoselektiven

    公开(公告)号：EP0696587A3

    公开(公告)日：1998-06-10

    申请号：EP95112005

    申请日：1995-07-31

    Applicant: BASF AG

    Inventor： HUELLMANN MICHAEL DR ,  BECKER RAINER DR ,  HASEL WINNFRIED DR ,  JESSEL BARBARA DR

    IPC: C07D307/92

    CPC classification number: C07D307/92

    Abstract: Verfahren zur stereoselektiven Herstellung von (-)3a,6,6,9-Tetramethyl-perhydronaphtho[2,1-b]furan der Formel Ia

    Abstract translation: 立体选择性制剂 的cpd。 （I），其被称为（ - ） - 3a,6,6,9-四甲基 - 全氢 - 萘并（2,1-b）呋喃，显示为3a，6,6,9a-四甲基衍生物。 的式（Ia）的化合物包括在液体中脱水和环化十氢-2-羟基-2,5,5,8-四甲基-1-萘 - 乙醇（II）。 相。 反应在10-50℃下，在10-100重量％的存在下，基于（II），具有高离子交换容量的商业蒙脱土催化剂或（b）在120-140℃下进行（a） 在10-100重量％的市售可用于制备柱色谱的活性酸性氧化铝的存在下。

    3.
    发明专利
    未知

    公开(公告)号：PT668271E

    公开(公告)日：2002-07-31

    申请号：PT95101740

    申请日：1995-02-09

    Applicant: BASF AG

    Inventor： KONRAD STOLZENBERG DR ,  BERND BRUCHMANN DR ,  OTTERBACH ANDREAS ,  FRANZ MERGER DR ,  GERHARD LAQUA DR ,  TOM WITZEL DR ,  BRANDT PETER DR ,  WOLFF STEFAN DR ,  BECKER RAINER DR

    IPC: B01J20060101 ,  B01J31/02 ,  C07B61/00 ,  C07D20060101 ,  C07D251/34 ,  C08G20060101 ,  C08G18/02 ,  C08G18/18 ,  C08G18/79 ,  C09D20060101

    Abstract: The prodn. of isocyanurate gp.-contg. polyisocyanates (A) comprises partial trimerisation of (cyclo)aliphatic di-isocyanates (B) in the presence of tetra-alkylammonium alkyl carbonates of formula (I) and/or quat. ammonio-alkyl carbonate betaines of formula (II) as catalyst(s), followed by deactivation of the catalyst on reaching the required deg. of trimerisation. In formulae, R , R , R = 1-20 C alkyl, 5-6C cycloalkyl, 7-10C aralkyl or Ph; or R + R can form a 5- or 6-membered cycloalkyl gp., or R + R + N can form a 5- or 6-membered ring with another N or O as bridging gp. or R + R + R + N can form a multi-membered ring with one or more extra N and/or O bridges; R = 1-4C alkyl; R = 2-20 C alkylene, 5-6C cycloalkylene, 7-10C aralkylene or phenylene; or R + R = alkylene gp. which forms a 5- to 7-membered ring with a N bridge. Pref. trimerisation catalysts are carbonates of formula (III), (IV), or (V), or betaine carbonates of formula (V), (VII) or (VIII). Trimerisation is carried out at 30-150 degrees C and the catalyst is deactivated with dibutyl phosphate (DBP); unreacted monomeric di-isocyanate is then removed. Pref. di-isocyanates are (cyclo)aliphatic di-isocyanates obtd. by a phosgene-free process, esp. by thermal cleavage of (cyclo)aliphatic dicarbamate esters; esp. pref. di-isocyanates obtd. by this method are 1,6-hexamethylenedi-isocyanate (HDI), 2-butyl-2-ethyl-pentamethylene-1,5-di-isocyanate and 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane (IPDI).

    6.
    发明专利
    未知

    公开(公告)号：DE59408268D1

    公开(公告)日：1999-06-24

    申请号：DE59408268

    申请日：1994-07-21

    Applicant: BASF AG

    Inventor： HUELLMANN MICHAEL DR ,  BECKER RAINER DR ,  SCHARF EMIL DR

    IPC: B01J23/74 ,  B01J23/88 ,  C07B61/00 ,  C07D295/08 ,  C07D295/088

    Abstract: N-(2-Hydroxyethyl)piperazine of the formula I is prepared by reaction of triethanolamine of the formula II with ammonia in the presence of hydrogen at temperatures from 100 to 500 DEG C and pressures from 10 to 500 bar on heterogeneous catalysts, employing heterogeneous catalysts having an active mass containing 20 to 85% by weight of ZrO2 and/or Al2O3, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 1 to 60% by weight of oxygen-containing compounds of cobalt calculated as CoO and/or oxygen-containing compounds of nickel, calculated as NiO and/or oxygen-containing compounds of molybdenum, calculated as MoO3.

    7.
    发明专利
    未知

    公开(公告)号：DE19755415A1

    公开(公告)日：1999-06-17

    申请号：DE19755415

    申请日：1997-12-12

    Applicant: BASF AG

    Inventor： ELLER KARSTEN DR ,  RUETTER HEINZ DR ,  HESSE MICHAEL DR ,  BECKER RAINER DR

    IPC: C08G65/10 ,  C08G65/20 ,  C08G65/26

    Abstract: The invention relates to a method for producing polytetrahydrofuran and polytetrahydrofuran copolymers, diesters or monoesters thereof by polymerising tetrahydrofuran in the presence of at least one telogen and/or comonomer on acid- activated montmorillonite catalysts, whereby the ratio of the montmorillonite structure to the sum of the muscovite and kaolin structure in the montmorillonite catalyst, which is determined from the intensities of the reflexes measured at 5.5 DEG 2È for montmorillonite, 9.0 DEG 2È for muscovite and 12,5 DEG 2È for kaolin is, after acid activation, at least 5:1.

    Production of aromatic poly:amine mixtures
    9.
    发明专利
    Production of aromatic poly:amine mixtures 未知

    公开(公告)号：DE19724237A1

    公开(公告)日：1998-12-10

    申请号：DE19724237

    申请日：1997-06-09

    Applicant: BASF AG

    Inventor： BECKER RAINER DR ,  ELLER KARSTEN DR ,  LANGENSIEPEN HANS-WERNER DR ,  HESSE MICHAEL DR

    IPC: B01J21/16 ,  C07C209/78 ,  C07C211/54

    Abstract: Production of aromatic polyamine mixtures contg. cpds. of formula: H2NACH2BNH2(I) (where, A and B = 1,4-phenylene residues which can have 1-4 substits. chosen from 1-20C alkyls and halogens) comprises converting a cpd. of formula: HANHCH2NHBH (IV) and/or a cpd. of formula HANHCH2BNH2 (V) (where, A and B = as above) at a temp. of 20-200 deg C in the presence of a heterogeneous inorganic catalyst chosen from: (a) oxides of 3-10 group element which can be acid-activated; (b) a clay doped with an oxide of a 2-13 group element or lanthanide which an be acid-activated; and (c) opt. acid-activated layered silicates acidity of below pK3 = 0.5 of more than 0.05 mmol/g catalyst.

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