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公开(公告)号：DE59500908D1
公开(公告)日：1997-12-04
申请号：DE59500908
申请日：1995-08-26
Applicant: BASF AG
Inventor： TIEFENSEE KRISTIN DR , GUENTHERBERG NORBERT DR , NEUMANN RAINER DR
Abstract: A thermoplastic moulding material (I) comprises a mixt. of (A) 15-70 wt.% methyl methacrylate polymer obtd. from a mixt. of (A1) 80-93 wt.% methyl methacrylate and (A2) 7-20 wt.% acrylic acid 1-8C alkyl ester, with viscosity index 55-60 ml/g (0.5 wt.% soln. in dimethyl formamide at 23 degrees C); (B) 10-50 wt.% copolymer obtd. from a mixt. of (B1) 78-88 wt.% vinyl aromatic monomers (w.r.t. (B)) and (B2) 12-22 wt.% vinyl cyanide (w.r.t. (B)), with viscosity index 60-80 ml/g (0.5 wt.% soln. in dimethyl formamide at 23 degrees C); (C) 20-50 wt.% graft polymer obtd. from (C1) 50-80 wt.% monomer mixt. core comprising (C11) 50-100 wt.% 1,3-diene and (C12) 0-50 wt.% vinyl aromatic monomer, and (C2) 20-50 wt.% graft obtd. by polymerisation in the presence of (C1) of a mixt. comprising (C21) 40-100 wt.% (meth)acrylic acid 1-8C alkyl ester and (C22) 0-60 wt.% vinyl aromatic monomer, with mean particle size of (C) 40-500 nm; and (D) 0-20 wt.% standard additives (w.r.t. sum of (A)-(C)). The sum of (A)-(C) is 100 wt.% and the difference in break index between (C) and the mixt. of (A), (B) and opt. (D) is less than 0.005. Also claimed are (i) prepn. of (I) by compounding (A)-(D) at 200-300 degrees C; (ii) use of (I) for making moulded prods.; and (iii) moulded prods. made from (I).
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公开(公告)号：DE59500907D1
公开(公告)日：1997-12-04
申请号：DE59500907
申请日：1995-08-26
Applicant: BASF AG
Abstract: A thermoplastic moulding compsn. comprises (A) 15-78% methacrylate polymer obtd. by polymerisation of a mixt. of (i) 90-100% Me methacrylate and (ii) 0-10% 1-8C alkyl acrylate; (B) 10-50% copolymer obtd. from a mixt. of (i) 78-88% vinyl aromatic monomer and (ii) 12-22% vinyl cyanide; (C) 20-50% graft copolymer with average particle size (d50) 40-50 nm, comprising (i) 50-80% substrate obtd. from (a) 50-100% 1,3-diene and (b) 0-50% grafted on portion obtd. by polymerisation in presence of (i) of (c) 40-100% 1-8C alkyl (meth)acrylate and (d) 0-60 % vinyl aromatic monomer; (D) 0,5-15% crosslinked methacrylate polymer of average particle size (d50) 50-80,000 nm obtd. by polymerisation of (i) 80-99.5% 1-8C alkyl methacrylate, (ii) 0-15% 1-8C alkyl acrylate, (iii) 0.5-5% crosslinking comonomer and (iv) 0-10% (meth)acrylic acid, hydroxyethyl or dimethylaminoethyl-(meth)acrylate; and opt. also (E) up to 20% conventional additives. (A)+(B)+(C)+(D) = 100%, and the difference between the RI of (C) and that of the mixt. of (A), (B), (D) and opt. (E) is less than 0.005. Mfr. of the compsn. comprises mixing the components at 200-300 degrees C.
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公开(公告)号：DE19621731A1
公开(公告)日：1997-12-04
申请号：DE19621731
申请日：1996-05-30
Applicant: BASF AG
Inventor： GUENTHERBERG NORBERT DR , WEBER MARTIN DR
IPC: C08L25/02 , C08L25/08 , C08L33/06 , C08L51/04 , C08L69/00 , C08J3/20 , C08J5/00 , C08J5/18 , C08L25/12 , C08L33/08 , C08L33/10 , C08L35/00 , D01F6/96
Abstract: Thermoplastic moulding materials (TMM) contains: (A) 10-90.9 wt% aromatic polycarbonate (PC), (B) 5-30 wt% graft copolymer comprising (b1) 20-80 wt% rubber-elastic polymer base with a Tg of below 0 deg C and (b2) 20-80 wt% grafted component with a Tg of above 50 deg C derived from 2 monomers (b2.1) and (b2.2), (C) 2-70 wt% thermoplastic copolymer of (c1) 50-90 wt% styrene and (c2) 10-50 wt% acrylonitrile and/or 1-8C alkyl (meth)acrylate, with a Tg of more than 50 deg C and a viscosity number of 40-160 cm /g, (D) 2-70 wt% thermoplastic copolymer other than (C), containing (d1) 50-99 wt% styrene and/or substituted styrene of formula (I), and (d2) 1-50 wt% (meth)acrylonitrile, maleic anhydride, maleimide (optionally N-substituted with 1-8C alkyl or 6-20C aryl), 1-8C alkyl (meth)acrylate, (meth)acrylamide and/or 1-8C alkyl vinyl ether, (E) 0.1-25 wt% copolymer(s) of (e1) 50-99 wt% of a mixture of (e1.1) 80-100 wt% 1-10C alkyl (meth)acrylate and/or 5-8C cycloalkyl (meth)acrylate and (e1.2) up to 20 wt% 1-10C alkyl acrylate, (e2) 0.5-20 wt% maleic acid or anhydride, fumaric acid, itaconic acid and/or maleimide (optionally N-substituted as above) and (e3) 0.5-40 wt% vinylaromatic(s) (optionally ring- substituted with one or two 1-4C alkyl groups), (F) 0-12.5 wt% polymeric, hydroxyl group-containing compound(s) and (G) 0-50 wt% additives, auxiliary substances and/or fibrous and/or particulate fillers. Components (E) and (F) together make up not more than 25 wt% of the mixture. In (I), R = 1-8C alkyl or H, R' = 1-8C alkyl and n = 0, 1, 2 or 3. Also claimed are mouldings, semi- finished products and film obtained from these TMM.
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公开(公告)号：DE19610572A1
公开(公告)日：1997-09-25
申请号：DE19610572
申请日：1996-03-18
Applicant: BASF AG
Inventor： WEBER MARTIN DR , GUENTHERBERG NORBERT DR
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公开(公告)号：ES2099890T3
公开(公告)日：1997-06-01
申请号：ES93119726
申请日：1993-12-08
Applicant: BASF AG
Inventor： FISCHER WOLFGANG DR , GUENTHERBERG NORBERT DR
IPC: C08F2/22 , C08F265/04 , C08F279/02 , C08F291/08 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02 , C08L69/00 , C08L71/12 , C08L101/00
Abstract: Particulate graft polymer composed of 30 to 90% by weight of at least one elastomeric grafting base A having a weight average particle size from 30 to 1000 nm, based on A, 85 to 99.8% by weight of at least one alkyl acrylate A11 having 1-8 carbon atoms in the alkyl radical, 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A12 and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or methacrylate A13 or at least 50% by weight of one or more dienes A111, up to 50% by weight of one or more ethylenically unsaturated monomers A112 and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or methacrylate A113 and 10 to 70% by weight of a graft sheath B composed of, based on B, up to 99.9% by weight of at least one vinylaromatic monomer B1, up to 99.9% by weight of at least one polar, copolymerisable, ethylenically unsaturated monomer B2 and 0.1 to 20% by weight of at least one monomer B3 containing one or more basic or acid groups.
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Patent Agency Ranking
公开(公告)号：DE19524178A1
公开(公告)日：1997-01-09
申请号：DE19524178
申请日：1995-07-03
Applicant: BASF AG
Inventor： TICKTIN ANTON DR , MC KEE GRAHAM EDMUND DR , FISCHER WOLFGANG DR , GUNESIN BINNUR DR , GUENTHERBERG NORBERT DR
IPC: C08F2/44 , C08F6/00 , C08K5/15 , C08K5/1545 , C08L25/12 , C08L25/16 , C08L33/12 , C08L33/20 , C08L33/22 , C08L55/02 , C08J3/20
Abstract: The invention pertains to thermoplastic molding compounds consisting of A) 98 to 99.995 wt.%, relative to A + B, acrylonitrile-containing polymer and B) 0.005 to 2 wt.%, relative to A + B, alpha -tocopherol. In addition, the invention pertains to a method of reducing the formation of residual monomers when the thermoplastic molding compounds are subjected to shear and thermal stress by adding alpha -tocopherol.
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公开(公告)号：ES2093336T3
公开(公告)日：1996-12-16
申请号：ES93112466
申请日：1993-08-04
Applicant: BASF AG
Inventor： DECKERS ANDREAS DR , GUENTHERBERG NORBERT DR , BUESCHL RAINER DR , JAHNS EKKEHARD DR
Abstract: A thermoplastic moulding composition containing, based on the total amount of its constituents A, B and C, A: from 70 to 99% by weight of a thermoplastic resin A comprising, based on A, A1: from 50 to 100% by weight of a hard matrix A1 comprising, based on A1, A11: from 50 to 95% by weight of units of a vinylaromatic compound or methyl methacrylate or mixtures thereof (A11) and A12: from 5 to 50% by weight of units of acrylonitrile A12; A2: up to 50% by weight of an elastomeric, particulate graft copolymer A2 comprising, based on A2, A21: from 30 to 80% by weight of at least one elastomeric graft base A21 having a mean particle size of from 30 to 1000 nm comprising, based on A21, A211: from 50 to 100% by weight of units of a 1,3-diene or of a C4-C8-alkyl acrylate which forms elastomeric polymers (A211) and A212: up to 50% by weight of units of at least one vinyl monomer A212; and A22: from 15 to 85% by weight of a graft shell A22 comprising, based on A22, A221: from 50 to 90% by weight of units of a vinylaromatic monomer A221 and A222: from 10 to 50% by weight of units of acrylonitrile A222; B: from 0.5 to 15% by weight of a nitrile rubber B comprising, based on B, B1: from 10 to 40% by weight of units of acrylonitrile and B2: from 60 to 90% by weight of units of butadiene; and C: from 0.5 to 15% by weight of a particulate polymer C distributed in the hard matrix A and comprising, based on C, C1: from 80 to 99% by weight of units of methyl methacrylate, C2: from 0.5 to 15% by weight of units of an ester of acrylic acid, C3: from 0.5 to 5% by weight of units of a crosslinking monomer which can be copolymerised with C1 and C2, and C4: up to 10% by weight of units of a polar monomer selected from (meth)acrylic acid, hydroxyethyl (meth)acrylate and dimethylaminoethyl (meth)acrylate, the mean particle size of C being from 50 to 50,000 nm.b
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公开(公告)号：DE59304263D1
公开(公告)日：1996-11-28
申请号：DE59304263
申请日：1993-08-04
Applicant: BASF AG
Inventor： DECKERS ANDREAS DR , GUENTHERBERG NORBERT DR , BUESCHL RAINER DR , JAHNS EKKEHARD DR
Abstract: A thermoplastic moulding composition containing, based on the total amount of its constituents A, B and C, A: from 70 to 99% by weight of a thermoplastic resin A comprising, based on A, A1: from 50 to 100% by weight of a hard matrix A1 comprising, based on A1, A11: from 50 to 95% by weight of units of a vinylaromatic compound or methyl methacrylate or mixtures thereof (A11) and A12: from 5 to 50% by weight of units of acrylonitrile A12; A2: up to 50% by weight of an elastomeric, particulate graft copolymer A2 comprising, based on A2, A21: from 30 to 80% by weight of at least one elastomeric graft base A21 having a mean particle size of from 30 to 1000 nm comprising, based on A21, A211: from 50 to 100% by weight of units of a 1,3-diene or of a C4-C8-alkyl acrylate which forms elastomeric polymers (A211) and A212: up to 50% by weight of units of at least one vinyl monomer A212; and A22: from 15 to 85% by weight of a graft shell A22 comprising, based on A22, A221: from 50 to 90% by weight of units of a vinylaromatic monomer A221 and A222: from 10 to 50% by weight of units of acrylonitrile A222; B: from 0.5 to 15% by weight of a nitrile rubber B comprising, based on B, B1: from 10 to 40% by weight of units of acrylonitrile and B2: from 60 to 90% by weight of units of butadiene; and C: from 0.5 to 15% by weight of a particulate polymer C distributed in the hard matrix A and comprising, based on C, C1: from 80 to 99% by weight of units of methyl methacrylate, C2: from 0.5 to 15% by weight of units of an ester of acrylic acid, C3: from 0.5 to 5% by weight of units of a crosslinking monomer which can be copolymerised with C1 and C2, and C4: up to 10% by weight of units of a polar monomer selected from (meth)acrylic acid, hydroxyethyl (meth)acrylate and dimethylaminoethyl (meth)acrylate, the mean particle size of C being from 50 to 50,000 nm.b
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公开(公告)号：AT143400T
公开(公告)日：1996-10-15
申请号：AT93120270
申请日：1993-12-16
Applicant: BASF AG
Inventor： DECKERS ANDREAS DR , GUENTHERBERG NORBERT DR , TIEFENSEE KRISTIN DR
IPC: C08K5/00 , C08L25/02 , C08L25/12 , C08L33/00 , C08L33/04 , C08L33/06 , C08L33/24 , C08L35/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L51/06 , C08L73/00 , C08L79/08
Abstract: Transparent and impact-resistant moulding compounds containing essentially A) 5 to 50% by weight of a polymer obtainable by polymerisation of a C1-C20-alkyl ester of methacrylic or acrylic acid or mixtures of such esters, B) 5 to 50% by weight of a polymer obtainable by polymerisation of a monomer mixture of b1) 75 to 82% by weight of an aromatic vinyl monomer and b2) 18 to 25% by weight of acrylonitrile or methacrylonitrile or a mixture thereof, C) 10 to 40% by weight of a polymer containing c1) 10 to 90% by weight of units of the general formula I where R is hydrogen or C1-C4-alkyl and R is C1-C18-alkyl, C5-C12-cycloalkyl, C6-C10-aryl or C6-C10-aryl-C1-C4- alkyl, which radicals, with the exception of the C1-C4-alkyl groups, can be substituted by up to three radicals selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy and halogen, c2) 10 to 90% by weight of a C1-C20-alkyl ester of methacrylic or acrylic acid or mixtures of such esters, D) 5 to 60% by weight of a graft copolymer having a weight average particle diameter of less than 200 nm and obtainable by polymerisation of 20 to 70% by weight of a monomer mixture of d1) 30 to 100% by weight of a C1-C20-alkyl ester of methacrylic or acrylic acid or mixtures of such esters and d2) 0 to 70% by weight of an aromatic vinyl monomer in the presence of 30 to 80% by weight of a grafting base obtainable by polymerisation of at least one monomer of the group consisting of butadiene, isoprene, aromatic vinyl monomers and C4-C20-alkyl esters of acrylic acid and E) 0 to 20% by weight of components A) to D), of customary additives, the percentages of components A) to D) adding to 100 and the difference between the refractive index of component D) and that of the mixture of components A), B) and C) and if desired E) being less than 0.01.
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公开(公告)号：DE59206478D1
公开(公告)日：1996-07-11
申请号：DE59206478
申请日：1992-09-10
Applicant: BASF AG
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