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公开(公告)号：DE59906807D1
公开(公告)日：2003-10-02
申请号：DE59906807
申请日：1999-05-10
Applicant: BASF AG
Inventor： RIECHERS HARTMUT , SIMON JOACHIM , HOEHN ARTHUR , KRAMER ANDREAS , FUNKE FRANK , SIEGEL WOLFGANG , NUEBLING CHRISTOPH
IPC: B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/68 , C07C209/88 , C07C211/03 , C07C213/02 , C07C213/08 , C07C217/08
Abstract: A process for the preparation of racemic amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III and the amine of the formula R3NH2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.
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公开(公告)号：AT248140T
公开(公告)日：2003-09-15
申请号：AT99924920
申请日：1999-05-10
Applicant: BASF AG
Inventor： RIECHERS HARTMUT , SIMON JOACHIM , HOEHN ARTHUR , KRAMER ANDREAS , FUNKE FRANK , SIEGEL WOLFGANG , NUEBLING CHRISTOPH
IPC: B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/68 , C07C209/88 , C07C211/03 , C07C213/02 , C07C213/08 , C07C217/08
Abstract: A process for the preparation of racemic amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III and the amine of the formula R3NH2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.
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公开(公告)号：DE59906464D1
公开(公告)日：2003-09-04
申请号：DE59906464
申请日：1999-05-10
Applicant: BASF AG
Inventor： RIECHERS HARTMUT , SIMON JOACHIM , HOEHN ARTHUR , KRAMER ANDREAS , FUNKE FRANK , SIEGEL WOLFGANG , NUEBLING CHRISTOPH
IPC: B01J23/88 , B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/00 , C07C209/68 , C07C209/86 , C07C209/88 , C07C211/03 , C07C213/08 , C07C217/08
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公开(公告)号：DE10145119A1
公开(公告)日：2003-04-03
申请号：DE10145119
申请日：2001-09-13
Applicant: BASF AG
Inventor： SCHAEFER MARTIN , BOETTCHER ARND , KRAMER ANDREAS , HOEHN ARTHUR , LIANG SHELUE , FUNKE FRANK
IPC: C07C209/22 , C07B61/00 , C07C209/26 , C07C211/07 , C07C211/03
Abstract: A process for the production of amines comprises catalytic hydrogenation-amination of carbonyl compounds and/or alcohols containing at least 50 ppm halogen (with respect to the mixture ) with nitrogen compounds in the presence of Co and/or Ni containing catalysts and solid acid cocatalysts. A process for the production of amines of formula R R CH-NR R (1) by catalytic hydrogenation-amination of carbonyl compounds of formula R -C(=O)-R (2) and/or alcohols of formula R -CH(OH)-R (3) containing at least 50 ppm halogen (with respect to the mixture ) with nitrogen compounds of formula HNR R (4) in the presence of Co and/or Ni containing catalysts and solid acid cocatalysts. R -R = H, 1-12C alkyl, 3-12C cycloalkyl, 6-10C aryl or 7-11C aralkyl.
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公开(公告)号：DE10144631A1
公开(公告)日：2003-03-27
申请号：DE10144631
申请日：2001-09-11
Applicant: BASF AG
Inventor： SCHAEFER MARTIN , BOETTCHER ARND , KRAMER ANDREAS , HOEHN ARTHUR , KACZMAREK REINHARD , HENKES ERHARD
IPC: B01J23/42 , B01J23/44 , B01J23/63 , C07B61/00 , C07D207/32 , C07D207/323 , C07D213/06 , C07D213/133 , C07D213/16 , C07D213/24
Abstract: Production of pyrroles (I) or pyridines (III), comprises dehydrogenating the corresponding pyrrolidines (II) or piperidines (IV) in the presence of a supported noble metal catalyst comprises performing the reaction in the presence of 1-50 wt.% water. Production of pyrroles of formula (I) or pyridines of formula (III), comprises dehydrogenating the corresponding pyrrolidines of formula (II) or piperidines of formula (IV) in the presence of a supported noble metal catalyst comprises performing the reaction in the presence of 1-50 wt.% water. R -R = H or 1-6C aliphatic group.
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Patent Agency Ranking
公开(公告)号：ZA200107485B
公开(公告)日：2002-09-11
申请号：ZA200107485
申请日：2001-09-11
Applicant: BASF AG
Inventor： RIECHERS HARTMUT , SIMON JOACHIM , HOEHN ARTHUR , KRAMER ANDREAS , FUNKE FRANK , SIEGEL WOLFGANG , NUEBLING CHRISTOPH
IPC: B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/68 , C07C209/88 , C07C211/03 , C07C213/02 , C07C213/08 , C07C217/08 , C07C , C07B
Abstract: A process for the preparation of racemic amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III and the amine of the formula R3NH2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.
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公开(公告)号：DE10028800A1
公开(公告)日：2001-12-20
申请号：DE10028800
申请日：2000-06-15
Applicant: BASF AG
Inventor： KRAMER ANDREAS , SIEGEL WOLFGANG
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公开(公告)号：DE19852282A1
公开(公告)日：2000-05-18
申请号：DE19852282
申请日：1998-11-13
Applicant: BASF AG
Inventor： RIECHERS HARTMUT , SIMON JOACHIM , HOEHN ARTHUR , KRAMER ANDREAS , FUNKE FRANK , SIEGEL WOLFGANG , NUEBLING CHRISTOPH
IPC: C07C209/68 , C07C213/08 , C07C217/08 , C07B55/00 , C07C209/00
Abstract: The racemization of optically active, optionally substituted aliphatic secondary amines (I) by contacting with hydrogen and a (de)hydrogenation catalyst is carried out in the gas phase. Racemization of optically active amines (I) involves contacting (I), in the gas phase, with hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperatures. R1 = H, alkyl, cycloalkyl, aralkyl, aryl, heteroaryl or heterocyclyl (all optionally substituted by alkyl, cycloalkyl, alkoxy, aryloxy, alkylamino or dialkylamino); with the proviso that R1 and R2 are different. R2, R3 = alkyl, cycloalkyl, aralkyl, aryl, heteroaryl or heterocyclyl (all optionally substituted by alkyl, cycloalkyl, alkoxy, aryloxy, alkylamino or dialkylamino);
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公开(公告)号：ES2285495T3
公开(公告)日：2007-11-16
申请号：ES04763087
申请日：2004-07-03
Applicant: BASF AG
Inventor： VICARI MAXIMILIAN , RUDLOFF MARTIN , KRAMER ANDREAS , DREWS RONALD
IPC: C07C29/42 , C07C33/042
Abstract: Un proceso para preparar alcohol propargílico mediante conversión de una solución acuosa de formaldehído que contiene acetileno sobre un catalizador que contiene acetiluro de cobre a una presión de operación de 1 hasta 15 bar y de 70 a 120°C sin que se forme una fase gaseosa continua, caracterizado porque la solución acuosa de formaldehído contiene tetrahidrofurano en calidad de solvente orgánico para acetileno y el catalizador se dispone en un lecho fluidizado.
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公开(公告)号：ES2215730T3
公开(公告)日：2004-10-16
申请号：ES00966145
申请日：2000-10-10
Applicant: BASF AG
Inventor： THERRE JIRG , KRAMER ANDREAS , WEIPER-IDELMANN ANDREAS , SCHULIK MICHAEL , BENFER REGINA , SCHOSSIG JURGEN
IPC: C07B61/00 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/228 , C07C47/232
Abstract: The present invention relates to a continuous process for the preparation of cinnamaldehyde or cinnamaldehyde derivatives by continuous reaction of benzaldehyde derivatives with alkanals in the presence of bases and optionally subsequent continuous hydrogenation in a circulation reactor in the presence of a suspension catalyst and hydrogen to give dihydrocinnamaldehyde derivatives.
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