公开(公告)号：JP2003137864A

公开(公告)日：2003-05-14

申请号：JP2002265641

申请日：2002-09-11

Applicant: BASF AG

Inventor： SCHAFER MARTIN ,  BOETTCHER ARND ,  KRAMER ANDREAS ,  HOEHN ARTHUR ,  KACZMAREK REINHARD ,  HENKES ERHARD

IPC: B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  C07B61/00 ,  C07D207/32 ,  C07D207/323 ,  C07D213/06 ,  C07D213/133 ,  C07D213/16

Abstract: PROBLEM TO BE SOLVED: To provide an improved method for producing a pyrrole and a pyridine. SOLUTION: This method for producing the pyrrole of formula (I) by dehydrogenating a pyrrolidine of formula (II), or producing the pyridine of formula (III) by dehydrogenating a piperidine of formula (VI), in the presence of a noble metal catalyst is substantially carried out in the presence of 1-50 wt.% water based on the total of the pyrrolidine and the water or the piperidine and the water respectively.

公开(公告)号：JP2000256314A

公开(公告)日：2000-09-19

申请号：JP2000065327

申请日：2000-03-09

Applicant: BASF AG

Inventor： HENKES ERHARD ,  IFFLAND GABRIELE ,  CIPRIAN JUERGEN

IPC: C07D223/10 ,  C07B63/00 ,  C07D201/16 ,  C07D207/26 ,  C07D207/267 ,  C07D207/27 ,  C07D211/14 ,  C07D225/02

Abstract: PROBLEM TO BE SOLVED: To economically, selectively and efficiently reduce the concentration of amines existing in an N-substituted lactam as an impurity by treating a polluted N-substituted lactam with an acidic macroporous cation exchanger. SOLUTION: (A) An N-substituted lactam polluted with amines is treated with (B) an acidic macroporous cation exchanger. A strong acidic macroporous cation exchanger is used in the treatment and the component B has a styrene- divinylbenzene copolymer base material having 10-150 nm pore diameter. The usable capability of the component B is at least 0.5 mol of amines per 1 L of the cation exchanger and the component A is useful for purification of a compound expressed by the formula [R is a (substituted) saturated aliphatic group or the like; (n) is 1-4], especially for N-methyl-2-pyrrolidone, and the treatment is preferably performed at 5-130 deg.C.

公开(公告)号：WO2004024668A3

公开(公告)日：2004-10-14

申请号：PCT/EP0308831

申请日：2003-08-08

Applicant: BASF AG ,  FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36

CPC classification number: B01D3/141 ,  B01D3/146 ,  C07C209/84 ,  Y10S203/20 ,  C07C211/36

Abstract: The invention relates to a method for obtaining 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone diamine, IPDA) with a cis/trans isomer ratio of at least 73/27 by fractional distillation. Said method comprises the following steps: a) preparation of IPDA with a cis/trans isomer ratio /=73/27 and iv) an IPDA fraction with a cis/trans isomer ratio

Abstract translation: 本发明涉及一种用于具有顺式/反式异构体中的至少73/27通过分馏，其包括以下步骤比率回收3-氨基甲基-3,5,5-三甲基环己胺（异佛尔酮二胺，IPDA）：a）提供 具有IPDA顺/反异构体比率<73/27; b）将IPDA送入蒸馏塔的中间区域具有内部和在一定温度下在该蒸馏塔中蒸馏IPDA。 为5〜300℃，为10〜2000毫巴的压力; c）任选地进一步纯化由步骤b）通过在至少一个另外的塔中蒸馏得到IPDA; 其中，所述步骤b）和c）需要在步骤a中使用的IPDA的分离）放置到至少五个级分IA）至iv）：IA）erunreinigungen低于一小部分的有机比例反式IPDA沸腾V，IB）的含水部分 一小部分比反式IPDA沸点杂质下，ii）除了顺式IPDA沸点杂质更高的馏分，iii）具有> = 73/27的顺/反异构体比率的IPDA馏分和iv）具有顺式的IPDA馏分 式/反式异构体比率<= 66/34。

公开(公告)号：DE50308078D1

公开(公告)日：2007-10-11

申请号：DE50308078

申请日：2003-08-06

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/54 ,  C07C209/84 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：AT371638T

公开(公告)日：2007-09-15

申请号：AT03790870

申请日：2003-08-06

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/54 ,  C07C209/84 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：AT329900T

公开(公告)日：2006-07-15

申请号：AT02797938

申请日：2002-08-30

Applicant: BASF AG

Inventor： RUDLOFF MARTIN ,  STOPS PETER ,  HENKES ERHARD ,  SCHMIDTKE HELMUT ,  FISCHER ROLF-HARTMUTH ,  JULIUS MANFRED ,  LEBKUECHER ROLF ,  ROSS KARL-HEINZ

IPC: C07D207/26 ,  C07D201/08 ,  C07D207/267

Abstract: A process for continuously preparing 2-pyrrolidone by reacting gamma-butyrolactone with ammonia in the liquid phase in the presence of water, wherein the reaction is carried out at a temperature of from 275 to 300° C. and an absolute pressure of from 140 to 180 bar.

公开(公告)号：AU2003263200A1

公开(公告)日：2004-03-19

申请号：AU2003263200

申请日：2003-08-06

Applicant: BASF AG

Inventor： WATZDORF JOBST RUDIGER VON ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED ,  FUNKE FRANK ,  HILL THOMAS

IPC: C07C209/54 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/84 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：DE10236674A1

公开(公告)日：2004-02-19

申请号：DE10236674

申请日：2002-08-09

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  WATZDORF JOBST RUEDIGER VON ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36 ,  C07C209/82 ,  B01D3/00

Abstract: Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.

公开(公告)号：CA1234823A

公开(公告)日：1988-04-05

申请号：CA473197

申请日：1985-01-30

Applicant: BASF AG

Inventor： BUERSTINGHAUS RAINER ,  HENKES ERHARD ,  KIEHS KARL ,  ADOLPHI HEINRICH

IPC: A01N57/02 ,  A01N57/04 ,  A01N57/06 ,  C07F9/09 ,  C07F9/165 ,  C07F9/24 ,  C07F9/38 ,  C07F9/40 ,  C07F9/44

Abstract: - 16 - O.Z. 0050/36942 of the Diclosure: Oximinophosphoric acid derivatives of the formula I (I), where R1 is straight-chain or branched-alkyl of not more than 4 carbon atoms, R2 is straight-chain or branched alkoxy or alkylthio, each of not more than 4 carbon atoms, straight-chain or branched alkyl of not more than 3 carbon atoms, phenyl, amino, or straight-chain or branched alkylamino or dialkylamino, where alkyl in each case is of not more than 4 carbon atoms, R3 is straight-chain or branched alkyl of not more than 4 carbon atoms and X is oxygen or sulfur, their preparation, and their use as crop protection agents.

公开(公告)号：ES2276153T3

公开(公告)日：2007-06-16

申请号：ES03794858

申请日：2003-08-08

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36

Abstract: Procedimiento para la obtención de la 3-aminometil-3, 5, 5-trimetilciclohexilamina (isoforonadiamina, IPDA) con una proporción entre los isómeros cis/trans de, al menos, 73/27 mediante destilación fraccionada, que contiene las etapas siguientes: a) preparación de la IPDA con una proporción entre los isómeros cis/trans _ 73/27 y iv) una fracción de IPDA con una proporción entre los isómeros cis/trans >_ 66/34.