公开(公告)号：JP2003137845A

公开(公告)日：2003-05-14

申请号：JP2002265909

申请日：2002-09-11

Applicant: BASF AG

Inventor： SCHAFER MARTIN ,  BOETTCHER ARND ,  KRAMER ANDREAS ,  HOEHN ARTHUR ,  LIANG SHELUE ,  FUNKE FRANK DR

IPC: C07C209/22 ,  C07B61/00 ,  C07C209/26 ,  C07C211/07

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an amine, comprising the reductive amination of the corresponding carbonyl or alcohol containing a considerable amount (at least 50 ppm, especially organically bound) of a halogen, by which the amine can simply be produced at a low cost in reduced catalyst consumption rate and in a high yield. SOLUTION: This method for producing the amine of formula (I): R R CH- NR R (I) (R , R , R and R are each, for example, a 1 to 12C alkyl), comprising the catalytic reductive amination of a mixture of a carbonyl compound of formula (II): R -C(=O)-R and/or an alcohol of formula (III): R -CH(OH)-R with at least 50 ppm (based on the mixture) of a halogen in the presence of a Co- and/or Ni-containing catalyst with a nitrogen compound of formula (IV): HNR R , is characterized in that the reductive animation is carried out in the additive presence of a solid acidic cocatalyst.

公开(公告)号：JP2003137864A

公开(公告)日：2003-05-14

申请号：JP2002265641

申请日：2002-09-11

Applicant: BASF AG

Inventor： SCHAFER MARTIN ,  BOETTCHER ARND ,  KRAMER ANDREAS ,  HOEHN ARTHUR ,  KACZMAREK REINHARD ,  HENKES ERHARD

IPC: B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  C07B61/00 ,  C07D207/32 ,  C07D207/323 ,  C07D213/06 ,  C07D213/133 ,  C07D213/16

Abstract: PROBLEM TO BE SOLVED: To provide an improved method for producing a pyrrole and a pyridine. SOLUTION: This method for producing the pyrrole of formula (I) by dehydrogenating a pyrrolidine of formula (II), or producing the pyridine of formula (III) by dehydrogenating a piperidine of formula (VI), in the presence of a noble metal catalyst is substantially carried out in the presence of 1-50 wt.% water based on the total of the pyrrolidine and the water or the piperidine and the water respectively.

公开(公告)号：JP2002371064A

公开(公告)日：2002-12-26

申请号：JP2002157090

申请日：2002-05-30

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： BOETTCHER ARND ,  PINKOS ROLF DR ,  LORENZ RUDOLF ERICH ,  BECKER HEIKE

IPC: C07D201/16 ,  C07D223/10 ,  C08F2/38

CPC classification number: C07D223/10 ,  C07D201/16

Abstract: PROBLEM TO BE SOLVED: To provide a method for purifying N-vinyl-ε-caprolactam for producing an N-vinyl-ε-caprolactam hardly manifesting any sensibility for color changes, i.e., having high color stability higher than that of usual N-vinyl-ε-caprolactam obtained by distillation.
SOLUTION: N-vinyl-ε-caprolactam to be purified having at least 95 mass % purity is changed to a molten liquid, which is partially crystallized and the crystal is separated from the mother liquid.
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：提供一种N-乙烯基-ε-己内酰胺的纯化方法，用于制造几乎不表现出颜色变化的任何敏感性的N-乙烯基-ε-己内酰胺，即具有比通常的N-乙烯基 通过蒸馏获得的ε-己内酰胺。 解决方案：将具有至少95质量％纯度的待纯化的N-乙烯基-ε-己内酰胺改变为部分结晶并将晶体与母液分离的熔融液。

公开(公告)号：JP2002284728A

公开(公告)日：2002-10-03

申请号：JP2002003435

申请日：2002-01-10

Applicant: BASF AG

Inventor： LORENZ RUDOLF ERICH ,  BOETTCHER ARND ,  BECKER HEIKE ,  PINKOS ROLF DR

IPC: C07B63/04 ,  C07C41/46 ,  C07C43/16 ,  C07D223/10 ,  C08F2/00

Abstract: PROBLEM TO BE SOLVED: To obtain an alkenyl compound stabilized in a color number having a remarkably low color number for expressing no tendency to be colored after a storage of longer period of several months or extremely slight coloration with avoiding an expensive cost. SOLUTION: The color number of an alkenyl compound having a divalent or a trivalent heteroatom at α position to a double bond is stabilized and/or lowered mixing an oxidizing agent with the alkenyl compound.

公开(公告)号：JP2002136801A

公开(公告)日：2002-05-14

申请号：JP2001242326

申请日：2001-08-09

Applicant: BASF AG

Inventor： LORENZ RUDOLF ERICH ,  BOETTCHER ARND ,  PINKOS ROLF

IPC: B01D3/14 ,  C07B63/00 ,  C07C41/42 ,  C07C43/16 ,  C07C209/84 ,  C07C211/21 ,  C07D223/10 ,  C07D223/12 ,  C07D233/58 ,  C07D521/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for giving a purified alkenyl compound having a very low color number, without having defects described in detailed description of this invention and without incurring a high cost. SOLUTION: When an alkenyl compound having a divalent or trivalent heteroatom at α-position based on the double bond is purified, distillation is carried out at least two times and the purified compound is obtained from a vapor phase by condensation. The time between the first distillation after the synthesis of the alkenyl compound and at least one further distillation is at least one day, and the purified alkenyl compound has an APHA color number of

公开(公告)号：WO0230851A3

公开(公告)日：2002-10-31

申请号：PCT/EP0111649

申请日：2001-10-09

Applicant: BASF AG ,  BOETTCHER ARND ,  HENKELMANN JOCHEM ,  HAAKE MATHIAS ,  KAIBEL GERD

Inventor： BOETTCHER ARND ,  HENKELMANN JOCHEM ,  HAAKE MATHIAS ,  KAIBEL GERD

IPC: B01J23/46 ,  B01J23/40 ,  B01J23/56 ,  B01J35/04 ,  B01J37/02 ,  C07B35/02 ,  C07B61/00 ,  C07C5/10 ,  C07C13/18 ,  C07C209/72 ,  C07C211/35

CPC classification number: C07C209/72 ,  B01J23/40 ,  B01J23/462 ,  B01J23/56 ,  B01J35/04 ,  B01J37/0225 ,  C07B35/02 ,  C07C5/10 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2521/18 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/30 ,  C07C2523/46 ,  C07C2601/14 ,  C07C211/35

Abstract: The invention relates to a method for the hydrogenation of unsubstituted or at least monoalkyl substituted uni- or poly-nuclear aromatics by means of bringing the above at least one aromatic into contact with a gas containing hydrogen, in the presence of a catalyst comprising at least one metal of sub-group VIII of the periodic system as active metal, supported on a structured or monolithic support.

Abstract translation: 本发明涉及一种用于未取代的氢化或通过所述气体的至少一个芳族与周期系第VIII。分组的在催化剂的存在下，包含作为活性金属含氢至少一种金属接触与至少一个烷基或多核芳族化合物取代一次， 施加到结构化的或整体式载体，其包括

公开(公告)号：WO02100538A8

公开(公告)日：2003-11-20

申请号：PCT/EP0206348

申请日：2002-06-10

Applicant: BASF AG ,  BOETTCHER ARND ,  VANOPPEN DOMINIC ,  ARNDT JAN-DIRK

Inventor： BOETTCHER ARND ,  VANOPPEN DOMINIC ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J37/18 ,  C07B61/00 ,  C07D303/30 ,  C08G59/14 ,  C08G59/24 ,  C07C5/10 ,  C07D303/02

CPC classification number: B01J37/18 ,  B01J21/08 ,  B01J23/462 ,  C07D303/30 ,  C08G59/1405 ,  C08G59/24

Abstract: A method for the production of cycloaliphatic compounds (I) having side chains with expoxy groups by heterogenous-catalytic hydrogenation of a compound (II) having at least one carbocyclic, aromatic group and at least one side chain with at least one epoxy group, on a ruthenium catalyst, characterized in that the ruthenium catalyst is obtained by i) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200 DEG C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350 DEG C, wherein step ii) is carried out directly after step i).

Abstract translation: 一种用于脂环族化合物（I）的制备方法中，侧链具有环氧基包括由Vebindung（II）的非均相-katalische氢化，具有至少一个碳环芳族基团和具有至少一个环氧基团的至少一个侧链，在钌催化剂 其特征在于，钌催化剂是通过以下步骤获得：基于无定形二氧化硅具有低分子量的钌化合物的无卤素的水溶液中，然后在低于200℃的温度下干燥所述处理过的载体材料i）一种或多种处理的载体材料; ii）降低）固体Wasserstof第（i中得到的产物在100至350℃，该方法包括执行步骤的温度范围（ⅱ）紧接步骤（i）。

公开(公告)号：WO02100538A2

公开(公告)日：2002-12-19

申请号：PCT/EP0206348

申请日：2002-06-10

Applicant: BASF AG ,  BOETTCHER ARND ,  VANOPPEN DOMINIC ,  ARNDT JAN-DIRK

Inventor： BOETTCHER ARND ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J37/18 ,  C07B61/00 ,  C07D303/30 ,  C08G59/14 ,  C08G59/24 ,  C07C5/10 ,  C07D303/02

CPC classification number: B01J37/18 ,  B01J21/08 ,  B01J23/462 ,  C07D303/30 ,  C08G59/1405 ,  C08G59/24

Abstract: A method for the production of cycloaliphatic compounds (I) having side chains with expoxy groups by heterogenous-catalytic hydrogenation of a compound (II) having at least one carbocyclic, aromatic group and at least one side chain with at least one epoxy group, on a ruthenium catalyst, characterized in that the ruthenium catalyst is obtained by i) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200 DEG C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350 DEG C, wherein step ii) is carried out directly after step i).

Abstract translation: Verfha​​ren为脂环族化合物（I）的制备中，侧链具有环氧基包括由Vebindung（II）的非均相-katalische氢化，具有至少一个碳环芳族基团和具有至少一个环氧基团的至少一个侧链，在钌催化剂 ，其特征在于，所获得的钌催化剂是通过：基于无定形二氧化硅具有低分子量的钌化合物的无卤素的水溶液，然后干燥，在低于200℃的温度下处理过的载体材料i）一种或多种处理的载体材料; ii）降低）固体Wasserstof第（i中得到的产物在100至350℃，该方法包括执行步骤的温度范围（ⅱ）紧接步骤（i）。

公开(公告)号：DE102004038109A1

公开(公告)日：2006-03-16

申请号：DE102004038109

申请日：2004-08-05

Applicant: BASF AG

Inventor： HOEFER FRANK ,  BRAND ALEXANDRA ,  BOETTCHER ARND ,  KLAS KATRIN ,  VOGELSANG REGINA

IPC: C07B43/00 ,  C07B43/06 ,  C07D207/263

公开(公告)号：AU2002218222A8

公开(公告)日：2005-09-15

申请号：AU2002218222

申请日：2001-10-09

Applicant: BASF AG

Inventor： BOETTCHER ARND ,  HENKELMANN JOCHEM ,  HAAKE MATHIAS ,  KAIBEL GERD

IPC: B01J23/46 ,  B01J23/40 ,  B01J23/56 ,  B01J35/04 ,  B01J37/02 ,  C07B35/02 ,  C07B61/00 ,  C07C5/10 ,  C07C13/18 ,  C07C209/72 ,  C07C211/35

Abstract: A process for the hydrogenation of a monocyclic or polycyclic aromatic which may be unsubstituted or substituted by at least one aikyi group comprises bringing the aromatic into contact with a hydrogen-containing gas in the presence of a catalyst comprising at least one metal of transition group VIII of the Periodic Table as active metal applied to a structured or monolithic support.