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公开(公告)号:FR1359997A
公开(公告)日:1964-04-30
申请号:FR932168
申请日:1963-04-20
Applicant: BASF AG
Inventor: LUETZEL GERHARD , ROHLAND WERNER
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公开(公告)号:FR1355847A
公开(公告)日:1964-03-20
申请号:FR927302
申请日:1963-03-08
Applicant: BASF AG
Inventor: GROSCH WALTER , LUETZEL GERHARD , ROHLAND WERNER
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33.
公开(公告)号:BE631586A
公开(公告)日:1963-11-18
申请号:BE631586
申请日:1963-04-26
Applicant: BASF AG
Inventor: DEHNERT JOHANNES , GROSCH WALTER , LUETZEL GERHARD , ROHLAND WERNER
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公开(公告)号:BE631511R
公开(公告)日:1963-11-18
申请号:BE631511
申请日:1963-04-25
Applicant: BASF AG
Inventor: DEHNERT JOHANNES , GROSCH WALTER , LUETZEL GERHARD , ROHNALD WERNER
IPC: D06P
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35.
公开(公告)号:BE631237A
公开(公告)日:1963-11-18
申请号:BE631237
申请日:1963-04-18
Applicant: BASF AG
Inventor: LUETZEL GERHARD , ROHLAND WERNER
IPC: D06L20060101 , D06P20060101 , D06P , D06L
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公开(公告)号:FR81211E
公开(公告)日:1963-08-16
申请号:FR885181
申请日:1962-01-18
Applicant: BASF AG
Inventor: ROHLAND WERNER , LUETZEL GERHARD
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公开(公告)号:GB932080A
公开(公告)日:1963-07-24
申请号:GB150362
申请日:1962-01-16
Applicant: BASF AG
Inventor: ROHLAND WERNER , LUETZEL GERHARD
IPC: D06P1/12
Abstract: Textile goods are dyed or printed by treating, if necessary at elevated temperatures, in the presence of strongly alkaline-reacting agents with azoic dye precursors which contain one or more reactive hydrogen atoms preferably attached by way of nitrogen, oxygen or sulphur or which are capable of forming such atoms during the process and with uncoloured polyfunctional compounds which contain two or more CH2 = CH-CO- groups attached by way of nitrogen or which are capable of forming such groups during the process and thereafter converting the azoic dye precursors to dyestuffs in the usual way. The dye precursors may be diazotizable aromatic amino compounds or compounds capable of coupling. Specified combinations are initial treatment with sulphanilic acid amide and coupling with C.I. Azoic coupling component 13 or treatment with 1-amino-8-hydroxy naphtalene-3,6-disulphonic acid or N,H-diethanolamino -3-methylbenzene and coupling with diazotized para-nitraniline. The specified polyfunctional compound is hexahydro-1,3,5-triacryloyl-s-triazine. The dye precursors may be fixed by steaming for 5 minutes at 100 DEG C. rior to conversion to dyestuffs. In fixing diazotizable aromatic amino compounds it may be advantageous to protect the diazotizable amino groups in a usual way such as acylation prior to fixation. Examples are given of dyeing fabrics of cotton and viscose staple fibres.
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公开(公告)号:FR1318627A
公开(公告)日:1963-02-22
申请号:FR877720
申请日:1961-11-02
Applicant: BASF AG
Inventor: LUETZEL GERHARD , ROHLAND WERNER , TARTTER ARNOLD , BARTS GUENTER , DIETRICH WERNER , FEDERKIEL WILHELM , MUELLER ROLAND
IPC: D06P1/00
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公开(公告)号:BE619906A
公开(公告)日:1963-01-07
申请号:BE619906
申请日:1962-07-06
Applicant: BASF AG
Inventor: LUETZEL GERHARD , ROHLAND WERNER , BECKE FRIEDRICH
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公开(公告)号:GB910385A
公开(公告)日:1962-11-14
申请号:GB1061060
申请日:1960-03-25
Applicant: BASF AG
Inventor: LANGE GUENTER , LUETZEL GERHARD , WIPPELL HANS GUENTER , WEIDINGER HANS , KRANZ JOACHIM
IPC: C07D285/12 , C07D285/135 , C08L75/04 , C09B29/033 , C09B35/34 , D06P1/02
Abstract: The invention comprises dyes of formula where R1 is alkylene or 2-6 C atoms, chloroalkylene of 3-4 C atoms or cyanoalkylene of 4 C atoms, R2 is alkyl of 1-6 C atoms, cyanoalkyl of 2-4 C atoms, chloroalkyl of 1-4 C atoms or R5OY where R5 has the values of R1 and Y is H, alkyl of 1-3 C atoms, hydroxyalkyl of 2-3 C atoms or cyanoalkyl of 2-4 C atoms, R3 is H, Me, Et, Cl, CF3 or CH3CONH, R4 is H, OMe or OEt, X is H, alkyl of 1-3 C atoms, hydroxyalkyl of 2-3 C atoms and cyanoalkyl of 2-4 C atoms and, when R1 is alkylene, R2 alkyl or hydroxyalkyl and R3 H, Me, Et, Cl or CF3, X may also be an acyl residue of an aliphatic monocarboxylic acid of 1-4 C atoms and R6 is Me, Et, C6H5, cyclohexyl, tolyl, chlorphenyl, nitrophenyl or where R1, R2, R3 and R4 and X are as above and R7 is ethylene or phenylene. The dyes are made by diazotising an appropriate aminothiadiazole and coupling with the required substituted aniline component. Diazotisation and coupling are effected in nonaqueous solvents, mixtures of anhydrous acetic and propionic acid being preferred, diazotisation being effected with nitrosyl sulphuric acid in sulphuric acid. Preferably the diazo component is formed by treating a 1-acyl-thiosemicarbazide with sulphuric acid and diazotised and coupled without isolation. The dyes colour textile materials of cellulose2 1/2 - and tri-acetate, synthetic polyamides and polyesters, polymers and copolymers of acrylonitrile and polyvinyl chloride. Examples are provided of the preparation of the dyes and their use in dyeing cellulose acetate and synthetic polyamides and polyesters in shades of red, orange and bluish-red. Specifications 856,899 and 877,293 are referred to.
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