CONTINUOUS PREPARATION OF NYLONS
    36.
    发明专利

    公开(公告)号:CA1222590A

    公开(公告)日:1987-06-02

    申请号:CA456616

    申请日:1984-06-14

    Applicant: BASF AG

    Abstract: - 10 - O.Z. 0050/36564 Nylons are prepared by a continuous process in which, in a precondensation zone, an aqueous solution of a salt of a dicarboxylic acid of 6 to 18 carbon atoms and a diamine of 6 to 18 carbon atoms is heated to 250-300.degree.C under superatmospheric pressure, with simultaneous vaporization of water and formation of a prepolymer, the prepolymer and the vapor are separated, and the former is fed into a polycondensation zone and condensed under superatmospheric pressure of from 1 to 10 bar and at from 250 to 300.degree.C, wherein the aqueous salt solution is condensed under superatmospheric pressure of from 1 to 10 bar in the first third of the tubular precondensation zone provided with baffles, until the degree of conversion is not less than 93%, and the prepolymer and the vapor phase are brought into intimate contact with one another in the remaining two thirds of the precondensation zone.

    POLYMERIZATION OF '-CAPROLACTAM
    37.
    发明专利

    公开(公告)号:CA1076743A

    公开(公告)日:1980-04-29

    申请号:CA266548

    申请日:1976-11-25

    Applicant: BASF AG

    Abstract: O.Z. 31,765 An improved process for the continuous polymerization of .epsilon.-capro-lactam in the presence of water as initiator in a vertical downward-flow tubular reactor, in which the .epsilon.-caprolactam is partially polymerized at elevated temperature in a first, mechanically agitated reaction zone and is further polymerized in further reaction zones to the desired degree of polymerization. Poly-.epsilon.-caprolactam is discharged in the form of a melt. The polymerization is carried out at a gauge pressure of from 0.2 to 0.9 bar, constant in all reaction zones. The temperature in the first reaction zone is from 260 to 295.degree.C whilst obeying the condition t ? 265 + 43 p .degree.C, wherep is the numerical value of the gauge pressure in bars.

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