Method for determining the presence of a chemical compound which is homogeneously distributed in a medium by means of cross-correlating a measuring spectrum with reference spectra

    公开(公告)号:AU2005266512A1

    公开(公告)日:2006-02-02

    申请号:AU2005266512

    申请日:2005-07-19

    Applicant: BASF AG

    Abstract: The present invention relates to a method for determining the identity or non-identity of at least one chemical compound V' homogeneous y distributed in a medium, by a) exposing the medium containing at least one homogeneously distributed chemical compound V' to analysis radiation with a variable wavelength lambda, and b) determining the spectral measurement function I'(lambda) with the aid of the absorbed, reflected, emitted and/or scattered radiation, wherein a correlation function K(deltalambda,c',c) is determined according to Equation I K ⁡ ( delta ⁢ ⁢ lambda , c ' , c ) = 1 / N . ∫ - ∞ + ∞ ⁢ I ' ⁡ ( lambda , c ' ) . I ⁡ ( lambda + delta ⁢ ⁢ lambda , c ) ⁢ ⁢ ⅆ lambda ( I ) in which K(deltalambda,c',c) denotes the correlation depending on the relative shift deltalambda of the functions I'(lambda,c') and I(lambda,c) and the concentrations c' and c of the at least one chemical compound V' and V, c' denotes the concentration of the at least one chemical compound V' homogeneously distributed in the medium, with a known or suspected identity, c denotes the concentration of the at least one chemical compound V homogeneously distributed in the medium, with a known identity, I'(lambda,c') denotes the measurement function of the at least one homogeneously distributed chemical compound V' in a medium containing the concentration c', I(lambda,c) denotes the comparison function of the at least one homogeneously distributed chemical compound V in a medium containing the concentration c, and N denotes a normalization factor and identity or non-identity between the compounds V and V' is determined with the aid of the correlation function K(deltalambda,c',c).

    CONCENTRADOS DE ADITIVOS PARA CARBURANTES Y LUBRICANTES, QUE CONTIENEN POR LO MENOS UN DERIVADO DE ANTRAQUINONA COMO SUSTANCIA MARCADORA

    公开(公告)号:PE20051059A1

    公开(公告)日:2006-01-20

    申请号:PE2005000012

    申请日:2005-01-03

    Applicant: BASF AG

    Abstract: ABARCANDO EL DERIVADO DE ANTRAQUINONA LOS COMPUESTOS DE FORMULA (I), DE FORMULA (II) Y DE FORMULA (III), DONDE: Z1 y Z2 SON H, HIDROXI, OR, NHR o NR2; R1 y R2 SON R o COR; X ES H, CIANO, NITRO, HIDROXI, OR, AMINO, NHR, R o CH(R9)(R10); n y m SON 0, 1, 2, 3 o 4, SIENDO PRECISO QUE CUANDO n o m SON MAYORES DE 1, LOS RADICALES R o X SEAN IGUALES O DIFERENTES; R9 y R10 SON CIANO, COOH o COOR; R3 a R8 SON H, R o NHR; y R ES ALQUILO C1-C20 OPCIONALMENTE INTERRUMPIDO POR 1 A 4 ATOMOS DE OXIGENO EN FUNCION DE ETER, CICLOALQUILO C5-C7 SUSTITUIDO POR UNO O VARIOS DE DICHO ALQUILO, UN RADICAL SATURADO HETEROCICLICO DE 5 o 6 MIEMBROS SUSTITUIDO POR UNO O VARIOS DE DICHO ALQUILO, ARILO C6-C10 SUSTITUIDO POR UNO O VARIOS HALOGENOS, CIANO, NITRO, HIDROXI, AMINO O DICHO ALQUILO TAMBIEN INTERRUMPIDO CON ALCOXI C1-C20, ALQUILAMINO C1-C20 o DIALQUILAMINO C1-20, HETEROARILO C3-C12 SUSTITUIDO POR UNO O VARIOS DE DICHO ALQUILO TAMBIEN INTERRUMPIDO CON ALCOXI C1-C20, ALQUILAMINO C1-C20 o DIALQUILAMINO C1-20, ARIL C6-C10-ALQUILO C1-C4 DONDE EL ARIL ES EL ANTES MENCIONADO, Y HETEROARILALQUILO C1-C4 CON C3-C12 EN EL ATOMO HETEROARILO SIMILAR AL ANTES MENCIONADO. LOS CONCENTRADOS SE UTILIZAN PARA LA ADITIVACION DE ACEITES MINERALES

    Alkyne compounds
    36.
    发明专利

    公开(公告)号:AU2003232510A8

    公开(公告)日:2003-11-17

    申请号:AU2003232510

    申请日:2003-04-25

    Applicant: BASF AG

    Abstract: The present invention relates to alkyne compounds of the formula I P 1 -Y 1 -A 1 -Y 3 -(T 1 -B 1 -) m -T 3 -C≡C-T 4 -(B 2 -T 2 -) n -Y 4 -A 2 -Y 2 -P 2 (I) in which P 1 , P 2 are each, independently of one another, hydrogen, C 1 -C 12 -alkyl, a polymerizable group or a group suitable for polymerization or a radical which carries a polymerizable group or a group suitable for polymerization, Y 1 , Y 2 , Y 3 , Y 4 are each, independently of one another, a linking unit, B 1 , B 2 are each, independently of one another, -C≡C- or a linking group as defined for Y 1 to Y 4 , A 1 , A 2 are each, independently of one another, a single chemical bond or a spacer having from one to 30 carbon atoms, T 1 , T 2 , T 3 , T 4 are each, independently of one another, a divalent saturated or unsaturated carbocyclic or heterocyclic radical, and m, n are each, independently of one another, 0 or 1, with the proviso that at least one of the linking units Y 3 or Y 4 is a group -O-CO-O-, -O-CO-N(R)-, -(R)N-CO-O- or -(R)N-CO-N(R)-. The invention further relates to nonpolymerizable and polymerizable liquid-crystalline compositions comprising at least one alkyne compound of the formula I according to the invention, the use of these nonpolymerizable and polymerizable liquid-crystalline compositions for producing optical components, the use of the polymerizable liquid-crystalline compositions for printing or coating substrates, for preparing dispersions and emulsions, for producing films and pigments and optical components, printed or coated substrates, dispersions and emulsions, films and pigments of this type.

    Azoxy dyes and their cu complexes
    39.
    发明专利

    公开(公告)号:AU3425500A

    公开(公告)日:2000-10-04

    申请号:AU3425500

    申请日:2000-02-28

    Applicant: BASF AG

    Abstract: Azoxy dyes of the general formula I in the form of the free acid where n is 0 or 1, each R 1 is selected from the group consisting of methoxy, hydroxyl and carboxyl, each R 2 is selected from the group consisting of carboxyl, amino, C 1 -C 4 -alkylamino, allylamino, benzylamino and methoxycarbonylmethylamino, and the phenyl rings A may additionally be substituted by C 1 -C 8 -alkyl, unsubstituted or methyl- or halogen-substituted phenyl, hydroxyl, amino, nitro, halogen, carboxyl, N-benzylcarbamoyl, unsubstituted or nitro-, halogen-, C 1 -C 4 -alkoxy- or acetoxy-substituted phenylcarbamoyl and naphthylcarbamoyl or be benzofused, their copper complexes, a process for preparing the copper complex dyes, azoxy dyes of the formula I in their partially or completely deacylated form, their copper complexes, colorants comprising these azoxy dyes and/or their copper complexes and also their use for dyeing and printing natural or synthetic substrates.

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