Method for determining the presence of a chemical compound which is homogeneously distributed in a medium by means of cross-correlating a measuring spectrum with reference spectra

    公开(公告)号:NZ552904A

    公开(公告)日:2009-10-30

    申请号:NZ55290405

    申请日:2005-07-19

    Applicant: BASF AG

    Abstract: Disclosed is a method for determining the identity or non-identity of at least one chemical compound V' homogeneously distributed in a medium, by a) exposing the medium containing at least one homogeneously distributed chemical compound V' to analysis radiation with a variable wavelength (lambda), and b) determining the spectral measurement function I'(lambda) with the aid of the absorbed, reflected, emitted and/or scattered radiation, wherein a correlation function K(delta lambda,c',c) is determined according to Equation (I), in which K(delta lambda,c',c) denotes the correlation depending on the relative shift (delta lambda) of the functions I'(lambda,c') and I(lambda,c) and the concentrations c' and c of the at least one chemical compound V' and V, cÆ denotes the concentration of the at least one chemical compound V' homogeneously distributed in the medium, with a known or suspected identity, c denotes the concentration of the at least one chemical compound V homogeneously distributed in the medium, with a known identity, I'(lambda,c') denotes the measurement function of the at least one homogeneously distributed chemical compound V' in a medium containing the concentration c', I(lambda,c) denotes the comparison function of the at least one homogeneously distributed chemical compound V in a medium containing the concentration c, and N denotes a normalization factor, and identity or non-identity between the compounds V' and V is determined with the aid of the correlation function K(delta lambda,c',c), and the identity or non-identity of at least one chemical compound V' homogeneously distributed in a liquid or solid medium is determined. Also disclosed is the use of the above method wherein the at least one compound V and the at least one compound V' are tagging substances for mineral oils.

    PROCEDIMIENTO PARA DETERMINAR LA IDENTIDAD O NO IDENTIDAD DE POR LO MENOS UN COMPUESTO QUIMICO HOMOGENEAMENTE DISTRIBUIDO EN UN MEDIO

    公开(公告)号:PE05382006A1

    公开(公告)日:2006-07-04

    申请号:PE0007982005

    申请日:2005-07-08

    Applicant: BASF AG

    CPC classification number: G01N21/359 G01N33/2882 G01N2021/3196

    Abstract: QUE COMPRENDE: a) IRRADIACION DEL MEDIO, QUE CONTIENE UN COMPUESTO QUIMICO V', MEDIANTE EMISION DE RAYOS ANALITICOS DE LONGITUD DE ONDA VARIABLE L; Y, b) DETERMINACION DE LA FUNCION DE MEDIDA ESPECTRAL l'(L) POR MEDIO DE LA RADIACION ABSORBIDA, REFLEJADA, EMITIDA Y/O DISPERSADA; DETERMINANDOSE UNA FUNCION DE CORRELACION SEGUN LA ECUACION (I) DONDE: K(oL,c',c) SIGNIFICA UNA CORRELACION EN FUNCION DEL DESPLAZAMIENTO RELATIVO oL DE LAS FUNCIONES l'(L,c') Y l(L,c) Y LAS CONCENTRACIONES c' Y c DE, RESPECTIVAMENTE, UN COMPUESTO QUIMICO V' Y V; c' SIGNIFICA LA CONCENTRACION DEL COMPUESTO V' DE IDENTIDAD CONOCIDA O SUPUESTA; c SIGNIFICA LA CONCENTRACION DEL COMPUESTO V DE IDENTIDAD CONOCIDA; l'(L,c') REPRESENTA LA FUNCION DE MEDIDA DEL MEDIO QUE CONTIENE EL COMPUESTO V'; l(L,c) REPRESENTA LA FUNCION COMPARATIVA DEL MEDIO QUE CONTIENE V; Y, N ES EL FACTOR DE ESCALA, DETERMINANDOSE CON LA CORRELACION LA IDENTIDAD O NO ENTRE LOS COMPUESTOS V' Y V. EL MEDIO ES LIQUIDO, TAL COMO ACEITE MINERAL, O SOLIDO. LOS COMPUESTOS V Y V' SON SUSTANCIAS DE MARCACION PARA ACEITES MINERALES

    6.
    发明专利
    未知

    公开(公告)号:DE102004035948A1

    公开(公告)日:2006-03-16

    申请号:DE102004035948

    申请日:2004-07-23

    Applicant: BASF AG

    Abstract: The present invention relates to a method for determining the identity or non-identity of at least one chemical compound V' homogeneous y distributed in a medium, by a) exposing the medium containing at least one homogeneously distributed chemical compound V' to analysis radiation with a variable wavelength lambda, and b) determining the spectral measurement function I'(lambda) with the aid of the absorbed, reflected, emitted and/or scattered radiation, wherein a correlation function K(deltalambda,c',c) is determined according to Equation I K ⁡ ( delta ⁢ ⁢ lambda , c ' , c ) = 1 / N . ∫ - ∞ + ∞ ⁢ I ' ⁡ ( lambda , c ' ) . I ⁡ ( lambda + delta ⁢ ⁢ lambda , c ) ⁢ ⁢ ⅆ lambda ( I ) in which K(deltalambda,c',c) denotes the correlation depending on the relative shift deltalambda of the functions I'(lambda,c') and I(lambda,c) and the concentrations c' and c of the at least one chemical compound V' and V, c' denotes the concentration of the at least one chemical compound V' homogeneously distributed in the medium, with a known or suspected identity, c denotes the concentration of the at least one chemical compound V homogeneously distributed in the medium, with a known identity, I'(lambda,c') denotes the measurement function of the at least one homogeneously distributed chemical compound V' in a medium containing the concentration c', I(lambda,c) denotes the comparison function of the at least one homogeneously distributed chemical compound V in a medium containing the concentration c, and N denotes a normalization factor and identity or non-identity between the compounds V and V' is determined with the aid of the correlation function K(deltalambda,c',c).

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