32.
    发明专利
    未知

    公开(公告)号:DE59400025D1

    公开(公告)日:1995-11-09

    申请号:DE59400025

    申请日:1994-01-05

    Applicant: BASF AG

    Abstract: Process for the preparation of alkyl 2-alkyl-4-fluoromethylthiazolecarboxylates of the formula I in which R is alkyl, R is difluoromethyl or trifluoromethyl and R is alkyl, by reacting thiocarboxamides of the formula II in which R has the abovementioned meaning with alkyl 2-chloro-4-fluoroacetoacetates of the formula III in which R and R have the abovementioned meanings, in an aprotic solvent at temperatures of below 100@C and reacting the product with a dehydrating agent at temperatures of below 80@C, if appropriate in the presence of bases.

    Carbamoyl carboxylic acid amide derivs.

    公开(公告)号:DE4407022A1

    公开(公告)日:1995-09-07

    申请号:DE4407022

    申请日:1994-03-03

    Applicant: BASF AG

    Abstract: Carbamoyl carboxylic acid amide derivs of formula (I) and their salts are new. R = 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl (each opt. partially or completely halogenated and opt. mono-, di- or tri-substd. by T gps.,etc., or W ,W C=N-; W = 1-8C alkyl (opt. partially or completely halogenated and opt. mono-, di- or tri-substd. by T gps. (excluding heteroaryl and alkoxy carbonyl)), 2-8C alkenyl or 2-8C alkynyl (these last 2 gps. opt. partially or completely halogenated) and opt. mono-, di- or tri-substd. by 1-4C alkyl or T gps. (except heteroaryl)),etc.;W = H or a gp. W ; R = H, 1-8C alkyl or 3-7C cycloalkyl (these last 2 gps. each opt. partially or completely halogenated); R = e.g. 1-8C alkyl;R = H or a gp. R ; or R and R , together with the C atom to which they are attached form a 4-8 membered ring which contains as ring members, in addn. to C atoms, 1 or 2 heteroatoms chosen from O, S and N,etc.; R = a gp. R ; X = H, 1-8C alkyl and/or 2-8C alkenyl,etc.; m = 0-2; A = e.g. 3-7C cycloalkyl; or if m = 1 or 2, A can also be =CY Y ; Y ,Y = H, 1-8C alkyl, 2-8C alkenyl, 3-7C cycloalkyl,etc.;Y = O, S, SO,etc.; R = e.g. aryl;T = CN, 1-4C alkoxyalkyl,etc.

    New O,N-di:acyl-para-hydroxy:aniline derivs.

    公开(公告)号:DE4338512A1

    公开(公告)日:1995-05-18

    申请号:DE4338512

    申请日:1993-11-11

    Applicant: BASF AG

    Abstract: 2,3-Disubstd. O,N-diacyl-p-hydroxyaniline derivs. of formula (I) and their salts are new. R = 6-15C bicycloalkyl or 7-15C bicycloalkenyl (both opt. partially or completely halogenated and/or opt. substd. by 1-5 of alkyl, haloalkyl, alkoxy, haloalkyl and Ar); R , R = halogen, alkyl, haloalkyl, alkoxy or haloalkoxy; R = (i) 1-6C alkyl or 2-6C alkenyl (both opt. partially or completely halogenated and/or opt. monosubstd. by alkoxy, haloalkoxy, alkylthio, 3-7C cycloalkyl, 5-7C cycloalkenyl or Ar'); (ii) 3-7C cycloalkyl or 5-7C cycloalkenyl (both opt. substd. by 1-3 of halogen, alkyl, haloalkyl and alkoxy); or (iii) Ar, OR or NR R ; R = as for R (i); as for R (ii); or Ar; R = H or 1-6C alkyl; Ar = aryl (opt. partially or completely halogenated and/or opt. substd. by 1-3 of NO2, CN, alkyl, haloalkyl, alkoxy, haloalkoxy and alkylthio); Ar = aryl (opt. substd. by 1-3 of NO2, CN, halogen, alkyl, haloalkyl, alkoxy, haloalkyloxy and alkylthio); unless specified otherwise, all alkyl moieties have 1-4C.

    36.
    发明专利
    未知

    公开(公告)号:DE4308395A1

    公开(公告)日:1994-09-22

    申请号:DE4308395

    申请日:1993-03-17

    Applicant: BASF AG

    Abstract: Process for controlling pests which involves treating the pests or the plants at threat from infestation by pests with a 2-anilinopyridine of the formula I in which R is alkyl, alkenyl, alkynyl, haloalkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl, substituted cycloalkyl, alkoxy, haloalkoxy, substituted alkyl, alkenyloxy, alkynyloxy, halogen, CN, SCN, formyl, CH=NOR , CH=NR or CH NHR , R is hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, COR or substituted or unsubstituted phenyl, R is hydrogen, alkyl, substituted or unsubstituted cycloalkyl, alkenyl, alkynyl or substituted or unsubstituted phenyl, R is alkyl, alkenyl, alkynyl, haloalkyl or cycloalkyl, R is hydrogen, CN, S(O)nR or COR , R is alkyl or substituted phenyl, R is hydrogen, alkyl, haloalkyl, cycloalkyl, phenyl or benzyl, and R is hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or cyano and 2-anilinopyridines, and also the use of the compounds for the production of pesticides.

    37.
    发明专利
    未知

    公开(公告)号:DE4301356A1

    公开(公告)日:1994-07-21

    申请号:DE4301356

    申请日:1993-01-20

    Applicant: BASF AG

    Abstract: Process for the preparation of alkyl 2-alkyl-4-fluoromethylthiazolecarboxylates of the formula I in which R is alkyl, R is difluoromethyl or trifluoromethyl and R is alkyl, by reacting thiocarboxamides of the formula II in which R has the abovementioned meaning with alkyl 2-chloro-4-fluoroacetoacetates of the formula III in which R and R have the abovementioned meanings, in an aprotic solvent at temperatures of below 100@C and reacting the product with a dehydrating agent at temperatures of below 80@C, if appropriate in the presence of bases.

    PLANT PROTECTING PREPARATIVES CONTAINING BETA-PICOLINE DERIVATIVES AND PROCESS FOR PRODUCING SAID ACTIVE SUVBSTANCES

    公开(公告)号:HU911896D0

    公开(公告)日:1991-12-30

    申请号:HU189691

    申请日:1991-06-06

    Applicant: BASF AG

    Abstract: Beta-picoline derivs. (I) and their N-oxides and addn. salts are new. In (I), A = CR1R2; R1, R2 = H, 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; or R1+R2 = 2-6C n-alkylene; B = CH2, CHOR3, CHR4 or C=NOR5; R3 = H, 1-6C alkyl, 1-6C haloalkyl, 3-8C cycloalkyl, 3-6C alkenyl, 2-6C acyl or phenyl, benzyl or benzoyl opt. mono-, di- or tri-substd. in the ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, halogen, cyano or nitro; R4 = H, F, Cl, Br or I; R5 = H, 1-6C alkyl, 1-6C haloalkyl, 3-7C cycloalkyl, 3-6C alkenyl or aryl-1-4C alkyl opt. mono-, di- or tri-substd. in the aryl ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, halogen, cyano or nitro; Ar = phenyl or naphthyl opt. mono-, di- or tri-substd. by halogen, 1-6C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, phenyl, phenoxy, halophenyl, halophenoxy or benzyloxy; except 1-phenyl-3-(3-pyridyl) propan-1-one (IA). The use of cpd. (IA), which is known from J. Org. Chem. 43 (1978), 3396 and Arch. Pharm. 307 (1974), 550, for the control of fungi is also claimed. Further, intermediates (II) are claimed except where A = CH2 or CH(CH3). 3 Cpds. (I), e.g., 2-ethyl-1-(4-fluorophenyl) -2-(pyridyl-3-methyl)butan-1-ol, are specifically claimed.

    SYNERGETIC FUNGICIDAL MIXTURE AND ITS USE

    公开(公告)号:HU222565B1

    公开(公告)日:2003-08-28

    申请号:HU9801112

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

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