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    32.
    发明专利
    未知

    公开(公告)号：FI915969A0

    公开(公告)日：1991-12-18

    申请号：FI915969

    申请日：1991-12-18

    Applicant: BASF AG

    Inventor： DOTZAUER BERNHARD ,  WISTUBA ECKEHARDT ,  SCHWARTZ MANFRED ,  PETRI ROLF ,  BECHERT BERTOLD ,  DENU HANS-JUERGEN

    IPC: C04B41/48 ,  C04B41/62 ,  C04B41/63 ,  C09D133/06 ,  C04B

    Abstract: A concrete tile (I) is claimed, which is coated with a copolymer (A) with Tg -25 to +30 deg.C, derived from (a) 0.1-10 wt.% monomer of formula R1CH=CR2-CO-X-R3-Z-CHR4R5 (III), (b) 85-99.9 wt.% at least 2 monomers of the type (1-24C alkyl) (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, 3-6C unsatd. nitriles, vinyl halides and/or 2-8C non-aromatic hydrocarbons with olefinic double bond(s), and (c) 0-10 wt.% other Sn-free comonomers; R1, R2 = H or 1-4C alkyl; R3 = 1-20C bridging gp.; R4 = -COR6, -COOR6 or CN; R5 = H, -COR9, -COOR9 or CN; X = O or NR7; Z = single bond, CH2, O, NR8 or -OCO-; (with R6-R9 = H, or 1-12C alkyl, aryl, alkaryl or aralkyl). Also claimed is a process for the prodn. of (I), by application of an aq. prepn. contg. (A) to at least one surface of the green concrete, and drying the prepn. by hardening the concrete. More specifically, monomer (a) is acetylacetoxyethyl (meth)acrylate, acetylacetoxybutyl (meth)acrylate, cyanoacetoxyethyl (meth)acrylate, 1,1-dibenzoyl-2-(meth)acrylamidoethane, 1-benzoyl-1-acetyl-2- (meth)acrylamidoethane, or ethyl alpha-benzoyl-beta-(meth) acrylamidopropionate, and (b) are vinylaromatics or (1-8C alkyl) (meth)acrylates; (I) is coated with a prepn. contg. copolymer (A) and up to 450 wt.% mineral additives (B) and/or colour pigments (C) (w.r.t. amt. of A); another layer of the aq. prepn. is applied to the hardened tile and dried; the amt. of prepn. used is such that the total amt. of dry coating is 50-500 g/m2.

    AQUEOUS SYNTHETIC RESIN FORMULATIONS
    35.
    发明专利
    AQUEOUS SYNTHETIC RESIN FORMULATIONS 未知

    公开(公告)号：AU6247790A

    公开(公告)日：1991-03-21

    申请号：AU6247790

    申请日：1990-09-12

    Applicant: BASF AG

    Inventor： REHMER GERD ,  RAU MARIA GYOPAR ,  WISTUBA ECKEHARDT ,  BAECHER REINHARD ,  MATTHAEI LOTHAR

    IPC: C08K3/00 ,  C08F2/22 ,  C08K5/07 ,  C08K5/132 ,  C08L31/02 ,  C08L31/04 ,  C08L33/04 ,  C08L33/06 ,  C09D131/02 ,  C09D131/04 ,  C09D133/06 ,  C09J131/02 ,  C09J131/04 ,  C08L33/08 ,  C08L25/14 ,  C08K3/26

    Abstract: Aqueous synthetic resin formulations essentially contain A) from 3 to 75% by weight of one or more synthetic resins which are composed of a) from 50 to 99.9% by weight of one or more unsaturated carboxylic or vinyl esters, b) from 0.1 to 12% by weight of one or more alpha , beta -monoethylenically unsaturated monobasic or dibasic acids or their ahydrides, c) from 0 to 10% by weight of one or more monoethylenically unsaturated acetophenone or benzophenone derivatives, d) from 0 to 35% by weight of one or more other copolymerizable monoethylenically unsaturated monomers, in polymerized form, B) one or more metal cations having a charge of from 2 to 4, in water-soluble form, C) from 0 to 10% by weight, based on the synthetic resin A, or benezophenones or acetophenones which are not monoethylenically unsaturated, D) effective amounts of emulsifiers or protective colloids or a mixture of these active ingredients, E) not less than 5% by weight of water and F) from 0 to 85% by weight of finely divided fillers, and the total amount of the cations B is such that it is capable of neutralizing from 0.2 to 6 times the amount, corresponding to the amount of acid functions incorporated in the form of the monomers b in the synthetic resin A, of their conjugated bases. These synthetic resin formulations are suitable for coating, adhesive bonding, sealing or impregnating.

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