SUBSTITUTED 3-PHENYLPYRAZOLES AS HERBICIDES
    31.
    发明公开
    SUBSTITUTED 3-PHENYLPYRAZOLES AS HERBICIDES 失效
    取代的3-苯基吡唑作为除草剂

    公开(公告)号:EP0763025A1

    公开(公告)日:1997-03-19

    申请号:EP95921788.0

    申请日:1995-05-31

    Abstract: Substituted 3-phenylpyrazoles (I) in which: R1 represents -C(R?8)=C(R7,R12¿), (a), -C(R?9,R10)-C(R8,R11,R12¿), (b), (c), -C(R9)=C(R8)-phenyl or -C(R?9,R10)-C(R8,R13¿)-phenyl; R2 represents CN, CF¿3?, halogen; R?3¿ represents H, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl; R?4¿ represents C¿1?-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl; R?5¿ represents H, NO¿2?, halogen, carboxylic acid/ester radical, substituted or unsubstituted aminocarbonyl; R?6¿ represents H, halogen; Y represents -O-, -S-, -CH¿2?-; Z represents 2- to 5-membered chain; R?7¿ represents CN, halogen, C¿1?-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, carboxylic acid/ester radical, substituted or unsubstituted aminocarbonyl; R?8, R9, R10, R13¿ represent H, CN, halogen, C¿1?-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, carboxylic acid/ester radical, substituted or unsubstituted -N(H)-CO-R?25¿, amino or aminocarbonyl: R11 represents CN, halogen, carboxylic acid/ester radical, substituted or unsubstituted amino or aminocarbonyl, azido, OH, (halo)alkoxy, alkenyloxy, alkylcarbonyloxy; R12 represents isoxazolidinylcarbonyl, carboxylic acid/ester radical, acid amide group, -CO-O-N=C(R31)-(C1-C6-alkyl), -CO-O-N=C(R31)-CO-O-(C¿1?-C6-alkyl), -CO-O-N=C(R31)-(C1-C4-alkyl)-CO-O-(C1-C4-alkyl)-CO-O-CH2-R?14¿, -CO-O-C(R14)-(C1-C4-alkyl), substituted or unsubstituted aminocarbonyl or aminothiocarbonyl, -CO-NH-SO2-(C1-C4-alkyl), -CO-R36, -CO-O-(C¿1?-C4-alkyl)-C(R?14¿)=N-O-(C¿1?-C4-alkyl), substituted or unsubstituted -CO-NH-CH(R?30¿)-(COOH/ester) substituted or unsubstituted cyclopentyliminooxy- or cyclohexyliminooxycarbonyl; R14 represents H, C¿1?-C4-alkyl, phenyl, benzyl; R?25, R30¿ represents H, C¿1?-C6-alkyl, C1-C6-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, substituted or unsubstituted C3-C7-cycloalkyl, phenyl or phenyl-C1-C6-alkyl; R?31¿ represents C¿1?-C6-alkyl, C1-C4-haloalkyl, C1-C6-alkoxy-C1-C4-alkyl, C1-C6-alkoxycarbonyl-C1-C4-alkyl, di-[C1-C6-alkoxycarbonyl]-C1-C4-alkyl, C3-C6-cycloalkyl, C1-C6-alkoxy, C1-C6-alkoxycarbonyl, 2-furyl, substituted or unsubstituted phenyl; R?36¿ represents H, halogen, C¿1?-C4-alkyl, C2-C4-alkenyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, are used as herbicides.

    SUBSTITUTED 2-PHENYLPYRIDINES WITH HERBICIDAL ACTION
    33.
    发明公开
    SUBSTITUTED 2-PHENYLPYRIDINES WITH HERBICIDAL ACTION 失效
    取代的2-苯基具有除草活性

    公开(公告)号:EP0708756A1

    公开(公告)日:1996-05-01

    申请号:EP94923720.0

    申请日:1994-07-11

    CPC classification number: C07D213/30 C07D213/61 C07D265/36 C07D409/12

    Abstract: Substituted 2-phenylpyridines have formula (I) wherein R1, R3 = H, halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO¿2?H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, CONH2, alkylaminocarbonyl, dialkylaminocarbonyl, pyrrolidinylcarbonyl, piperidylcarbonyl, morpholinylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R?2¿ = halogen, CN, NO¿2?, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio; or R?1 + R2 or R2 + R3¿ = trimethylene or tetramethylene chain; R4 = halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO¿2?H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R?5¿ = hydrogen or halogen; R6 = halogen, CN, NO¿2?, OH, CF3, C1-C6-alkyl, C1-C4-alkoxy; R?7¿ = various radicals; and the N-oxides of (I) and the agriculturally utilizable salts of (I) where these exist, excepting those compounds (I) where R2 is C1-C4-alkoxy and R1 and/or R3 is carboxyl or the salt, ester or amide thereof. Use: herbicides; desiccation/defoliation of plants.

    HERBIZIDE SULFONYLHARNSTOFFE, VERFAHREN UND ZWISCHENPRODUKTE ZU IHRER HERSTELLUNG
    35.
    发明授权
    HERBIZIDE SULFONYLHARNSTOFFE, VERFAHREN UND ZWISCHENPRODUKTE ZU IHRER HERSTELLUNG 失效
    磺酰脲类除草剂,过程和它们的中间产品。

    公开(公告)号:EP0600967B1

    公开(公告)日:1995-04-19

    申请号:EP92917618.8

    申请日:1992-08-25

    CPC classification number: C07D521/00

    Abstract: Substituted sulphonyl ureas have the general formula (I), in which n and m equal 0 or 1 and the substituents have the following meaning: R1 is hydrogen, alkyl, alkenyl or alkinyl; R2 is halogen or trifluoromethyl, when m equals 0 or, when m equals 1, R2 is alkyl, alkenyl or alkinyl, and when X stands for O or S and m equals 1, trifluoromethyl or chlorodifluoromethyl; X is O, S or N-R4, whereas R4 is hydrogen or alkyl; R3 is hydrogen, halogen, alkyl, halogenalkyl, alkoxy or halogenalkoxy; A is NO¿2?, NH2, OH, CN, SCN, S(O)oR?5, SO¿2NR?6R7, ER7¿, whereas E stands for O, S or NR9, the groups (a), (b) possibly substituted C¿1?-C4-alkyl or C2-C4-alkenyl; R?5¿ is a possibly substituted alkyl group, a possibly substituted cycloalkyl group, an alkenyl group or an alkinyl group; R6 is hydrogen, an alkoxy group, an alkyl group, or represents together with R7 a C4-C6-alkylene chain, wherein a methylene group may be substituted by an oxygen atom or a C1-C4-alkylimino group; R7 is a possibly substituted alkyl, alkenyl or alkinyl group, a cycloalkyl group and may also represent, when E = NR9, methyl sulphone, trifluoromethyl sulphone, ethylsulphone, possibly halogen-substituted acetyl, dimethylcarbamoyl, dimethylsulphamoyl; o equals 0, 1 or 2; p, q equal 0 and/or 1 (when p = 0, q = 0); R8 is hydrogen or halogen; R9 is hydrogen, methyl, ethyl; R10 is alkyl, halogenalkyl, alkoxyalkyl, alkenyl, cycloalkyl, halogenalkenyl or, when p = 1 and q = 0, it may also be alkylamino or dialkylamino. Also disclosed are their environmentally compatible salts, a process and intermediates for producing the compounds having the formula (I) and their use as herbicides.

    CYCLOHEXENONOXIMETHER, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ALS HERBIZIDE
    36.
    发明公开
    CYCLOHEXENONOXIMETHER, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ALS HERBIZIDE 失效
    环己,其制造方法相同,它们作为除草剂。

    公开(公告)号:EP0625975A1

    公开(公告)日:1994-11-30

    申请号:EP93917360.0

    申请日:1993-01-30

    Abstract: Ethers de cyclohexénone-oximes de formule (I), où: R1 = alkyle en C1-C6; W = chaîne alcylène en C2-C4 éventuellement substituée par un alkyle en C1-C3; X = NO2, CN, halogène, alkyle en C1-C4, halogénoalkyle en C1-C4; n = 0 à 3 ou 1 à 5, dans le cas où tous les X sont des halogènes; R2 = C1-C4-alkoxy-C1-C6-alkyle, C1-C4-alkylthio-C1-C6-alkyle, cycloalkyle en C3-C7 éventuellement substitué, cycloalcényle en C5-C7 éventuellement substitué, hétérocycle saturé à 5 chaînons, éventuellement substitué, portant 1 ou 2 atomes d'oxygène et/ou de soufre, hétéro-cycle à 6 ou 7 chaînons, éventuellement substitué, ayant 1 ou 2 atomes d'oxygène et/ou de soufre non voisins, pouvant être saturé ou une ou deux fois insaturé, groupe hétéro-aromatique à 5 chaînons, éventuellement substitué, renfermant 1 ou 2 atomes de N et un atome de 0 ou un atome de S, phényle ou pyridyle, les deux pouvant porter encore 1 à 3 substituants: halogène, NO2, CN, alkyle, alcoxy, alkylthio, halogénoalkyle, alcényloxy, alcinyloxy et/ou -NRaRb; Ra = H, alkyle, alcényle, ou alcinyle, et Rb = H, alkyle, alcényle, alcinyle, acyle, ou benzoyle éventuellement substitué; ainsi que les sels utilisables en agriculture et les esters d'acides carboxyliques en C1-C10 et d'acides anorganiques des composés (I).

    Abstract translation: PCT号 PCT / EP93 / 00215秒。 371 8月11日,1994年二段。 102(e)中的日期1994年8月11日提交的PCT 1993年1月30日的PCT公布。 号 WO93 / 16063的PCT公布。 日期8月19日1993.Cyclohexenone肟醚I I R1 = C1-C6烷基; W = unsubstituiertem或C1-C3烷基取代的C2-C4亚烷基链; X = NO 2,CN,卤素,C1-C4烷基,C1-C4卤代烷基; N = 0-3或1-5个,如果所有的X是卤素; R2 = C1-C4烷氧基C1-C6烷基,C1-C4烷硫基C1-C6烷基,substituiertem奥德unsubstituiertem C3-C7环烷基,substituiertem奥德unsubstituiertem C5-C7环烯基,substituiertem奥德unsubstituiertem 5- 元饱和杂环含有1或2个氧和/或硫原子,substituiertem奥德unsubstituiertem 6-或7-元杂环具有1个或2个非相邻的氧和/或硫原子间隔,且是饱和的或单 - 或多二不饱和,substituiertem奥德unsubstituiertem 5元杂芳族含1个或2个N原子和一个O或S原子,苯基或吡啶基,这两者都是unsubstituiertem或承担1-3个卤素,NO2,CN,烷基,烷氧基,烷基硫代,卤代烷基,链烯氧基,炔氧基和 /或-NRaRb的取代基; RA = H,烷基,烯基或炔基和R b = H,烷基,烯基,炔基,酰基或substituiertem奥德unsubstituiertem苯甲酰基; 及其农业利用的盐和式I化合物与C 1 -C 10羧酸和无机酸的酯。

    SUBSTITUTED 2-PHENYLPYRIDINES WITH HERBICIDAL ACTION
    37.
    发明授权
    SUBSTITUTED 2-PHENYLPYRIDINES WITH HERBICIDAL ACTION 失效
    取代的2-苯基具有除草活性

    公开(公告)号:EP0708756B1

    公开(公告)日:2005-06-01

    申请号:EP94923720.0

    申请日:1994-07-11

    CPC classification number: C07D213/30 C07D213/61 C07D265/36 C07D409/12

    Abstract: Substituted 2-phenylpyridines have formula (I) wherein R1, R3 = H, halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO¿2?H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, CONH2, alkylaminocarbonyl, dialkylaminocarbonyl, pyrrolidinylcarbonyl, piperidylcarbonyl, morpholinylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R?2¿ = halogen, CN, NO¿2?, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio; or R?1 + R2 or R2 + R3¿ = trimethylene or tetramethylene chain; R4 = halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO¿2?H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, NO2, NH2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R?5¿ = hydrogen or halogen; R6 = halogen, CN, NO¿2?, OH, CF3, C1-C6-alkyl, C1-C4-alkoxy; R?7¿ = various radicals; and the N-oxides of (I) and the agriculturally utilizable salts of (I) where these exist, excepting those compounds (I) where R2 is C1-C4-alkoxy and R1 and/or R3 is carboxyl or the salt, ester or amide thereof. Use: herbicides; desiccation/defoliation of plants.

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