Abstract:
Substituted 3-phenylpyrazoles of formula (I), where R1 is H, or a substituent; R2 is CN, CF¿3?, halogen; R?3¿ is H, alkyl, halogenalkyl; R4 is C1-C4 alkyl, C1-C4 halogenalkyl; R5 is H, NO¿2?, halogen, -COOR, optionally substituted aminocarbonyl (where R is H, a substituent); and Z is -O-, -S-, -SO-, -SO2-; and agriculturally usable salts thereof, for use as herbicides.
Abstract translation:式(I)的取代3-苯基吡唑,其中R1是H或取代基; R2是CN,CF 3,卤素; R 3是H,烷基,卤代烷基; R4是C1-C4烷基,C1-C4卤代烷基; R5是H,NO2,卤素,-COOR,任选取代的氨基羰基(其中R是H,取代基); Z是-O - , - S - , - SO - , - SO 2 - 和其农业上可用的盐,用作除草剂。
Abstract:
The invention concerns 3-(Hetero)aryl carboxylic acid derivatives of formula (I) in which R is a formyl group, a CO2H group or a group which can be hydrolysed to give a COOH group and the other substituents are as follows: R?2 and R3¿ are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, R14 being hydrogen or forming, together with R3, an alkylene or alkenylene chain in which each methylene group may be replaced by oxygen; R4 is optionally substituted phenyl or naphthyl or an optionally substituted five-membered or six-membered heteroaromatic ring containing one to three nitrogen atoms and/or a sulphur or oxygen atom; R5 is hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R6 is C1-C8 alkyl, C3-C6 alkenyl, C3-C6 alkinyl or C3-C8 cycloalkyl, whereby these groups may carry one or more substituents; Y is sulphur, oxygen or a single bond; Z is sulphur or oxygen; with the proviso that R6 be not unsubstituted C¿1?-C4 alkyl if R?4¿ is unsubstituted phenyl, Z is oxygen and, at the same time, R5 is methyl or hydrogen.
Abstract:
Substituted sulphonyl ureas have the general formula (I), in which n and m equal 0 or 1 and the substituents have the following meaning: R1 is hydrogen, alkyl, alkenyl or alkinyl; R2 is halogen or trifluoromethyl, when m equals 0 or, when m equals 1, R2 is alkyl, alkenyl or alkinyl, and when X stands for O or S and m equals 1, trifluoromethyl or chlorodifluoromethyl; X is O, S or N-R4, whereas R4 is hydrogen or alkyl; R3 is hydrogen, halogen, alkyl, halogenalkyl, alkoxy or halogenalkoxy; A is NO¿2?, NH2, OH, CN, SCN, S(O)oR?5, SO¿2NR?6R7, ER7¿, whereas E stands for O, S or NR9, the groups (a), (b) possibly substituted C¿1?-C4-alkyl or C2-C4-alkenyl; R?5¿ is a possibly substituted alkyl group, a possibly substituted cycloalkyl group, an alkenyl group or an alkinyl group; R6 is hydrogen, an alkoxy group, an alkyl group, or represents together with R7 a C4-C6-alkylene chain, wherein a methylene group may be substituted by an oxygen atom or a C1-C4-alkylimino group; R7 is a possibly substituted alkyl, alkenyl or alkinyl group, a cycloalkyl group and may also represent, when E = NR9, methyl sulphone, trifluoromethyl sulphone, ethylsulphone, possibly halogen-substituted acetyl, dimethylcarbamoyl, dimethylsulphamoyl; o equals 0, 1 or 2; p, q equal 0 and/or 1 (when p = 0, q = 0); R8 is hydrogen or halogen; R9 is hydrogen, methyl, ethyl; R10 is alkyl, halogenalkyl, alkoxyalkyl, alkenyl, cycloalkyl, halogenalkenyl or, when p = 1 and q = 0, it may also be alkylamino or dialkylamino. Also disclosed are their environmentally compatible salts, a process and intermediates for producing the compounds having the formula (I) and their use as herbicides.
Abstract:
Ethers de cyclohexénone-oximes de formule (I), où: R1 = alkyle en C1-C6; W = chaîne alcylène en C2-C4 éventuellement substituée par un alkyle en C1-C3; X = NO2, CN, halogène, alkyle en C1-C4, halogénoalkyle en C1-C4; n = 0 à 3 ou 1 à 5, dans le cas où tous les X sont des halogènes; R2 = C1-C4-alkoxy-C1-C6-alkyle, C1-C4-alkylthio-C1-C6-alkyle, cycloalkyle en C3-C7 éventuellement substitué, cycloalcényle en C5-C7 éventuellement substitué, hétérocycle saturé à 5 chaînons, éventuellement substitué, portant 1 ou 2 atomes d'oxygène et/ou de soufre, hétéro-cycle à 6 ou 7 chaînons, éventuellement substitué, ayant 1 ou 2 atomes d'oxygène et/ou de soufre non voisins, pouvant être saturé ou une ou deux fois insaturé, groupe hétéro-aromatique à 5 chaînons, éventuellement substitué, renfermant 1 ou 2 atomes de N et un atome de 0 ou un atome de S, phényle ou pyridyle, les deux pouvant porter encore 1 à 3 substituants: halogène, NO2, CN, alkyle, alcoxy, alkylthio, halogénoalkyle, alcényloxy, alcinyloxy et/ou -NRaRb; Ra = H, alkyle, alcényle, ou alcinyle, et Rb = H, alkyle, alcényle, alcinyle, acyle, ou benzoyle éventuellement substitué; ainsi que les sels utilisables en agriculture et les esters d'acides carboxyliques en C1-C10 et d'acides anorganiques des composés (I).
Abstract translation:PCT号 PCT / EP93 / 00215秒。 371 8月11日,1994年二段。 102(e)中的日期1994年8月11日提交的PCT 1993年1月30日的PCT公布。 号 WO93 / 16063的PCT公布。 日期8月19日1993.Cyclohexenone肟醚I I R1 = C1-C6烷基; W = unsubstituiertem或C1-C3烷基取代的C2-C4亚烷基链; X = NO 2,CN,卤素,C1-C4烷基,C1-C4卤代烷基; N = 0-3或1-5个,如果所有的X是卤素; R2 = C1-C4烷氧基C1-C6烷基,C1-C4烷硫基C1-C6烷基,substituiertem奥德unsubstituiertem C3-C7环烷基,substituiertem奥德unsubstituiertem C5-C7环烯基,substituiertem奥德unsubstituiertem 5- 元饱和杂环含有1或2个氧和/或硫原子,substituiertem奥德unsubstituiertem 6-或7-元杂环具有1个或2个非相邻的氧和/或硫原子间隔,且是饱和的或单 - 或多二不饱和,substituiertem奥德unsubstituiertem 5元杂芳族含1个或2个N原子和一个O或S原子,苯基或吡啶基,这两者都是unsubstituiertem或承担1-3个卤素,NO2,CN,烷基,烷氧基,烷基硫代,卤代烷基,链烯氧基,炔氧基和 /或-NRaRb的取代基; RA = H,烷基,烯基或炔基和R b = H,烷基,烯基,炔基,酰基或substituiertem奥德unsubstituiertem苯甲酰基; 及其农业利用的盐和式I化合物与C 1 -C 10羧酸和无机酸的酯。
Abstract:
The invention pertains to novel herbicidally effective saccharin carboxylic acids or carboxylic acid esters of formula (Ia), in which the substituents are as follows: L, M are hydrogen, C1-C4 alkyl, C1-C4 alkoxy C1-C4 alkylthio, chlorine, cyano, methyl sulfonyl, nitro or trifluoromethyl; Z is hydrogen, C1-C4 alkyl, C3-C8 cycloalkyl, benzyl or phenyl, where the penyl rings can in each case be substituted by C1-C4 alkyl, and R is H, C1-C6 alkyl, with the proviso that if L and M are hydrogen, Z is not methyl, phenyl hydrogen or an alkali metal cation or silver cation, and also excepting 5-carboxy-7-methyl saccharin and 5-carboxy-4-chlorosaccharin.