公开(公告)号：US20150080605A1

公开(公告)日：2015-03-19

申请号：US14487383

申请日：2014-09-16

Applicant: BASF SE

Inventor： Cathrin Alexandra WELKER-NIEUWOUDT ,  Cornelia Katharina Dobner ,  Holger Borchert ,  Ulrich Hammon ,  Josef Macht ,  Andrey Karpov ,  Christian Walsdorff

IPC: B01J23/888 ,  B01J37/04 ,  C07C51/25 ,  B01J35/04

CPC classification number: B01J23/8885 ,  B01J23/002 ,  B01J23/8877 ,  B01J23/94 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/008 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1004 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0223 ,  B01J37/0232 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C51/25 ,  C07C51/252 ,  Y02P20/584 ,  Y10T428/13 ,  Y10T428/249953 ,  Y10T428/273 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  C07C57/04

Abstract: What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q )  S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.

Abstract translation: 所描述的是通过α，bgr-不饱和醛的气相氧化制备α，β-不饱和羧酸的催化剂，其包括施加有活性组合物的成型载体，其中活性组合物覆盖率qq = Q（100-Q）S m为至多0.3mg / mm 2，其中Q为催化剂的活性组成含量，重量％，Sm为成形载体的特定几何表面积，单位为mm2 / mg。 还描述了制备催化剂的方法和通过在包含催化剂床的固定催化剂床上气相氧化α，β-不饱和醛来制备α，β-不饱和羧酸的方法。 具有不断高的丙烯醛转化率的催化剂减少了对COx的过氧化，并增加了丙烯酸形成的选择性。

公开(公告)号：US20140343319A1

公开(公告)日：2014-11-20

申请号：US14277414

申请日：2014-05-14

Applicant: BASF SE

Inventor： Michael GOEBEL ,  Christian Walsdorff ,  Marco Hartmann ,  Nicolai Tonio Woerz ,  Tim Blaschke ,  Philipp Gruene

IPC: C07C51/377

CPC classification number: C07C51/377 ,  C07C51/353 ,  C07C57/04

Abstract: In a process for preparing acrylic acid, a reaction gas which comprises a gaseous formaldehyde source and gaseous acetic acid and in which the partial pressure of the formaldehyde source, calculated as formaldehyde equivalents, is at least 85 mbar and in which the molar ratio of the acetic acid to the formaldehyde source, calculated as formaldehyde equivalents, is at least 1 is contacted with a solid condensation catalyst. The space-time yield can be enhanced significantly by increasing the partial pressure of the reactants. The space-time yield remains high even after prolonged process duration.

Abstract translation: 在制备丙烯酸的方法中，包含气态甲醛源和气态乙酸的反应气体，其中以甲醛当量计算的甲醛源的分压为至少85毫巴，其中摩尔比 乙酸至甲醛源，以甲醛当量计算，至少1与固体缩合催化剂接触。 通过增加反应物的分压可以显着提高时空产率。 即使延长工艺持续时间，空时产量仍然很高。

公开(公告)号：US20140221683A1

公开(公告)日：2014-08-07

申请号：US14170816

申请日：2014-02-03

Applicant: BASF SE

Inventor： Cathrin Alexandra Welker-Nieuwoudt ,  Cornelia Katharina Dobner ,  Christian Walsdorff ,  Klaus Joachim Mueller-Engel ,  Josef Macht

IPC: B01J23/888 ,  C07C51/25

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/41 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/31 ,  B01J2523/24 ,  B01J2523/847 ,  B01J2523/56 ,  C07C57/04

Abstract: A process for producing a catalytically active composition being a mixture of a multielement oxide comprising the elements Mo and V and at least one oxide of molybdenum, in which spray drying of an aqueous solution or of an aqueous suspension of starting compounds comprising the elements of the multielement oxide produces a spray powder P, a pulverulent oxide of molybdenum and optionally shaping assistants are added thereto, shaped bodies are shaped from the resulting mixture and these are converted to the catalytically active composition by thermal treatment.

Abstract translation: 一种制备催化活性组合物的方法，该组合物是包含元素Mo和V的多元素氧化物和至少一种钼的氧化物的混合物，其中水溶液的喷雾干燥或起始化合物的含水悬浮液包含 多元素氧化物产生喷雾粉末P，钼的粉状氧化物和任选的成型助剂，从所得混合物成型体，并将它们通过热处理转化为催化活性组合物。

公开(公告)号：US20140163291A1

公开(公告)日：2014-06-12

申请号：US14097452

申请日：2013-12-05

Applicant: BASF SE

Inventor： Philipp Grüne ,  Wolfgang Rüttinger ,  Oliver Hammen ,  Christian Walsdorff

IPC: B01J23/887 ,  C07C5/48

CPC classification number: B01J23/8878 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/0223 ,  B01J37/038 ,  B01J37/08 ,  B01J37/088 ,  B01J2523/00 ,  C07C5/48 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/887 ,  Y02P20/52 ,  B01J2523/54 ,  B01J2523/67 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  C07C11/167

Abstract: The invention relates to a catalyst, in particular a coated catalyst, for the oxidative dehydrogenation of n-butenes to butadiene, its use and also a process for the oxidative dehydrogenation of n-butenes to butadiene.

Abstract translation: 本发明涉及用于将丁烯氧化脱氢成丁二烯的催化剂，特别是涂覆的催化剂，其用途以及正丁烯氧化脱氢为丁二烯的方法。

公开(公告)号：US20140163290A1

公开(公告)日：2014-06-12

申请号：US14097416

申请日：2013-12-05

Applicant: BASF SE

Inventor： Philipp Grüne ,  Wolfgang Rüttinger ,  Christian Walsdorff

IPC: C07C5/48

CPC classification number: C07C5/48 ,  B01J23/882 ,  B01J23/94 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/031 ,  B01J37/08 ,  B01J38/02 ,  B01J38/12 ,  B01J38/14 ,  B01J2523/00 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/18 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/887 ,  Y02P20/584 ,  C07C11/167 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/67 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845

Abstract: The invention relates to a process for the oxidative dehydrogenation of n-butenes to butadiene, which comprises two or more production steps (i) and at least one regeneration step (ii), in which (i) in one production step, a starting gas mixture comprising n-butenes is mixed with an oxygen-comprising gas and brought into contact with a multimetal oxide catalyst which comprises at least molybdenum and a further metal and is arranged in a fixed catalyst bed in a fixed-bed reactor at a temperature of from 220 to 490° C., and, before the relative decrease in conversion at constant temperature is >25%, (ii) in a regeneration step, the multimetal oxide catalyst is regenerated by passing an oxygen-comprising regeneration gas mixture at a temperature of from 200 to 450° C. over the fixed catalyst bed and burning off the carbon deposited on the catalyst, where a regeneration step (ii) is carried out between two production steps (i), wherein from 2 to 50% by weight of the carbon deposited on the catalyst is burnt off per regeneration step (ii).

Abstract translation: 本发明涉及一种将丁烯氧化脱氢成丁二烯的方法，其包括两个或多个制备步骤（i）和至少一个再生步骤（ii），其中（i）在一个制备步骤中，将起始气体 将包含正丁烯的混合物与含氧气体混合并与至少包含钼和另外的金属的多金属氧化物催化剂接触，并且在固定床反应器中的固定催化剂床中以 220至490℃，并且在恒温下的转化率相对降低> 25％之前，（ii）在再生步骤中，通过使含氧再生气体混合物在 在固定的催化剂床上200至450℃，并将沉积在催化剂上的碳烧掉，其中在两个生产步骤（i）之间进行再生步骤（ii），其中按重量计为2-50％ 碳沉积在t上 在每个再生步骤（ii）中催化剂被烧掉。

公开(公告)号：US20130109563A1

公开(公告)日：2013-05-02

申请号：US13661706

申请日：2012-10-26

Applicant: BASF SE

Inventor： Nils Bottke ,  Markus Schubert ,  Markus Ruf ,  Christian Walsdorff

IPC: B01J23/83 ,  C22B59/00 ,  B01J23/745

CPC classification number: B01J37/031 ,  B01J23/002 ,  B01J23/83 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0036 ,  B01J2523/00 ,  C01F17/0018 ,  C07D233/32 ,  C07D487/04 ,  C22B59/00 ,  B01J2523/13 ,  B01J2523/3712 ,  B01J2523/842

Abstract: The invention relates to a process for preparing cerium(III) compounds which comprises the steps of a) contacting a starting composition A comprising cerium dioxide and at least one further metal oxide selected from the group consisting of iron oxide, silicon dioxide, molybdenum oxide, lanthanum oxide, magnesium oxide and calcium oxide with at least one acid S and at least one iron component E comprising iron in the oxidation state 0 and/or II at a temperature ranging from 40 to 160° C. and at a pH of not more than 2 to obtain a solution L comprising cerium in the oxidation state III; b) adding at least one basic compound C to said solution L to obtain a solid F comprising at least one cerium(III) compound; c) separating off said solid F comprising at least one cerium(III) compound.

Abstract translation: 本发明涉及一种制备铈（III）化合物的方法，其包括以下步骤：a）使包含二氧化铈和至少一种另外的金属氧化物的起始组合物A与氧化铁，二氧化硅，氧化钼， 氧化镧，氧化镁和氧化钙与至少一种酸S和至少一种含有氧化态0和/或II的铁的铁组分E在40至160℃的温度和不超过pH 以获得包含处于氧化态III的铈的溶液L; b）向所述溶液L中加入至少一种碱性化合物C以获得包含至少一种铈（III）化合物的固体F; c）分离包含至少一种铈（III）化合物的所述固体F。