公开(公告)号：US12187692B2

公开(公告)日：2025-01-07

申请号：US17285780

申请日：2019-09-19

Applicant: BASF SE

Inventor： Andrey Karpov ,  Marco Oskar Kennema ,  Nicolas Duyckaerts ,  Christian Walsdorff ,  Christian Bartosch ,  Juergen Zuehlke ,  Miguel Angel Romero Valle

IPC: C07D301/10 ,  B01J21/04 ,  B01J23/68 ,  B01J35/31 ,  B01J35/40 ,  B01J35/56 ,  B01J35/61 ,  B01J35/63 ,  B01J35/66

Abstract: A process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising: directing a feed comprising gaseous ethylene and gaseous oxygen through a packing of individual shaped catalyst bodies, under conditions conducive to obtain a reaction mixture containing at least 2.7 vol.-% of ethylene oxide, wherein each shaped catalyst body comprises silver deposited on a refractory support and is characterized by a content of at least 20 wt.-% of silver, relative to the total weight of the shaped catalyst body; a BET surface area in the range of 1.6 to 3.0 m2/g; a first face side surface, a second face side surface and a circumferential surface with a plurality of passageways extending from the first face side surface to the second face side surface; and a uniform multilobed cross-section; and a longest direct diffusion pathway d, with 2d being in the range of 0.7 to 2.4 mm, wherein the longest diffusion pathway d is defined as the shortest distance from the geometric surface of the shaped catalyst body to a point inside the structure of the shaped catalyst body for which point the shortest distance is the largest among all points. The process allows for increased activity and/or stability of the catalyst while maintaining or increasing selectivity at high productivity.

公开(公告)号：US09238217B2

公开(公告)日：2016-01-19

申请号：US14487383

申请日：2014-09-16

Applicant: BASF SE

Inventor： Cathrin Alexandra Welker-Nieuwoudt ,  Cornelia Katharina Dobner ,  Holger Borchert ,  Ulrich Hammon ,  Josef Macht ,  Andrey Karpov ,  Christian Walsdorff

IPC: C07C51/235 ,  B01J23/888 ,  B01J37/04 ,  B01J37/08 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J35/04 ,  C07C51/25 ,  B01J37/02 ,  B01J23/94 ,  B01J35/00 ,  B01J23/00 ,  B01J23/887

CPC classification number: B01J23/8885 ,  B01J23/002 ,  B01J23/8877 ,  B01J23/94 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/008 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1004 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0223 ,  B01J37/0232 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C51/25 ,  C07C51/252 ,  Y02P20/584 ,  Y10T428/13 ,  Y10T428/249953 ,  Y10T428/273 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  C07C57/04

Abstract: What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q ) ⁢ S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.

Abstract translation: 所描述的是通过α，bgr-不饱和醛的气相氧化制备α，β-不饱和羧酸的催化剂，其包括施加有活性组合物的成型载体，其中活性组合物覆盖率qq = Q（100-Q）S m为0.3mg / mm 2以下，其中，Q为催化剂的活性成分含量，重量％，Sm为成形体的比表面积，单位为mm2 / mg。 还描述了制备催化剂的方法和通过在包含催化剂床的固定催化剂床上气相氧化α，β-不饱和醛来制备α，β-不饱和羧酸的方法。 具有不断高的丙烯醛转化率的催化剂减少了对COx的过氧化，并增加了丙烯酸形成的选择性。

公开(公告)号：US09181169B2

公开(公告)日：2015-11-10

申请号：US13888542

申请日：2013-05-07

Applicant: BASF SE

Inventor： Cathrin Alexandra Welker-Nieuwoudt ,  Andrey Karpov ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel ,  Herbert Vogel ,  Alfons Drochner ,  Nina Blickhan ,  Nadine Duerr ,  Tim Jekewitz ,  Nadine Menning ,  Tina Petzold ,  Sabine Schmidt

IPC: C07C51/16 ,  B01J23/30 ,  B01J23/888 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  C01G39/00 ,  C01G41/00 ,  C08F220/06 ,  C07C51/25 ,  B01J37/03 ,  B01J23/00 ,  C07C51/235

CPC classification number: C07C51/16 ,  B01J23/002 ,  B01J23/30 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/0223 ,  B01J37/033 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  B01J2523/00 ,  C01G39/00 ,  C01G41/006 ,  C01P2002/72 ,  C01P2006/12 ,  C07C51/235 ,  C07C51/252 ,  C08F220/06 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/17 ,  C07C57/04

Abstract: A process for preparing (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of (meth)acrolein over a multimetal oxide composition which comprises the elements Mo, V and W and is obtained by a hydrothermal preparation route, and the multimetal oxide composition obtainable by this preparation route.

Abstract translation: 一种通过非晶催化气相部分氧化（甲基）丙烯醛在多元氧化物组合物上制备（甲基）丙烯酸的方法，所述多元氧化物组合物包含元素Mo，V和W并通过水热制备途径得到，并且可获得多金属氧化物组合物 通过这条准备路线。

公开(公告)号：US08785344B2

公开(公告)日：2014-07-22

申请号：US13770449

申请日：2013-02-19

Applicant: BASF SE

Inventor： Andrey Karpov ,  Cornelia Katharina Dobner ,  Frank Rosowski ,  Mark Eichelbaum ,  Annettte Trunschke ,  Robert Schloegl

IPC: B01J27/228 ,  B01J21/00 ,  C07D307/34

CPC classification number: B01J27/198 ,  B01J23/002 ,  B01J23/22 ,  B01J35/0033 ,  B01J35/023 ,  B01J37/08 ,  C07D307/60

Abstract: A catalyst for the gas phase oxidation of organic hydrocarbons comprises a multielement oxide which comprises at least one transition meal such as vanadium, wherein the catalyst has a charge transport activation energy Ec at a temperature of 375 to 425° C. of less than 0 kJ/mol. The catalyst serves for preparation of maleic anhydride.

Abstract translation: 用于有机烃的气相氧化的催化剂包括多元素氧化物，其包含至少一种过渡膳食，例如钒，其中催化剂在375至425℃的温度下具有小于0kJ的电荷转移活化能Ec / mol。 催化剂用于制备马来酸酐。

公开(公告)号：US20130217896A1

公开(公告)日：2013-08-22

申请号：US13770449

申请日：2013-02-19

Applicant: BASF SE

Inventor： Andrey Karpov ,  Cornelia Katharina Dobner ,  Frank Rosowski ,  Mark Eichelbaum ,  Annette Trunschke ,  Robert Schloegl

IPC: B01J27/198 ,  C07D307/60

CPC classification number: B01J27/198 ,  B01J23/002 ,  B01J23/22 ,  B01J35/0033 ,  B01J35/023 ,  B01J37/08 ,  C07D307/60

Abstract: A catalyst for the gas phase oxidation of organic hydrocarbons comprises a multielement oxide which comprises at least one transition meal such as vanadium, wherein the catalyst has a charge transport activation energy Ec at a temperature of 375 to 425° C. of less than 0 kJ/mol. The catalyst serves for preparation of maleic anhydride.

Abstract translation: 用于有机烃的气相氧化的催化剂包括多元素氧化物，其包含至少一种过渡膳食，例如钒，其中催化剂在375至425℃的温度下具有小于0kJ的电荷转移活化能Ec / mol。 催化剂用于制备马来酸酐。

公开(公告)号：US20140018572A1

公开(公告)日：2014-01-16

申请号：US13888542

申请日：2013-05-07

Applicant: BASF SE

Inventor： Cathrin Alexandra WELKER-NIEUWOUDT ,  Andrey Karpov ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel ,  Herbert Vogel ,  Alfons Drochner ,  Nina Blickhan ,  Nadine Duerr ,  Tim Jekewitz ,  Nadine Menning ,  Tina Petzold ,  Sabine Schmidt

IPC: B01J23/888 ,  B01J23/30 ,  C07C51/16

CPC classification number: C07C51/16 ,  B01J23/002 ,  B01J23/30 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/0223 ,  B01J37/033 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  B01J2523/00 ,  C01G39/00 ,  C01G41/006 ,  C01P2002/72 ,  C01P2006/12 ,  C07C51/235 ,  C07C51/252 ,  C08F220/06 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/17 ,  C07C57/04

Abstract: A process for preparing (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of (meth)acrolein over a multimetal oxide composition which comprises the elements Mo, V and W and is obtained by a hydrothermal preparation route, and the multimetal oxide composition obtainable by this preparation route.

Abstract translation: 一种通过非晶催化气相部分氧化（甲基）丙烯醛在多元氧化物组合物上制备（甲基）丙烯酸的方法，所述多元氧化物组合物包含元素Mo，V和W并通过水热制备途径得到，并且可获得多金属氧化物组合物 通过这条准备路线。

公开(公告)号：US12121881B2

公开(公告)日：2024-10-22

申请号：US17285799

申请日：2019-09-19

Applicant: BASF SE

Inventor： Andrey Karpov ,  Marco Oskar Kennema ,  Nicolas Duyckaerts ,  Christian Walsdorff ,  Christian Bartosch ,  Juergen Zuehlke ,  Miguel Angel Romero Valle

IPC: B01J23/68 ,  B01J21/04 ,  B01J35/40 ,  B01J35/56 ,  B01J35/61 ,  B01J35/63 ,  B01J35/64 ,  B01J35/66 ,  B01J37/02 ,  B01J37/08 ,  C07D301/04

CPC classification number: B01J23/688 ,  B01J21/04 ,  B01J35/40 ,  B01J35/56 ,  B01J35/612 ,  B01J35/633 ,  B01J35/635 ,  B01J35/651 ,  B01J35/653 ,  B01J35/657 ,  B01J35/695 ,  B01J37/0213 ,  B01J37/082 ,  C07D301/04

Abstract: A shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising silver deposited on a porous refractory support, the shaped catalyst body having a first face side surface, a second face side surface and a circumferential surface, characterized by a content of at least 20 wt.-% of silver, relative to the total weight of the shaped catalyst body; a multilobe structure; a plurality of passageways extending from the first face side surface to the second face side surface, outer passageways being arranged around a central passageway with one outer passageway being assigned to each lobe, wherein neighboring outer passageways are arranged essentially equidistantly to each other and the outer passageways are arranged essentially equidistantly to the central passageway; a minimum wall thickness A between two neighboring passageways in the range of 0.6 to 1.3 mm; a minimum wall thickness B between each outer passageway and the circumferential surface in the range of 1.1 to 1.8 mm; and a BET surface area in the range of 1.6 to 3.0 m2/g. The shaped catalyst bodies allow for a favorable balance between mechanical stability, pressure drop and selectivity. The invention also relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of a shaped catalyst body as defined above. The invention further relates to a process for preparing a shaped catalyst body as above, comprising i) impregnating a refractory support having a BET surface area in the range of 1.4 to 2.5 m2/g with a silver impregnation solution; and ii) subjecting the impregnated refractory support to a calcination process; wherein steps i) and ii) are optionally repeated.

公开(公告)号：US20150080605A1

公开(公告)日：2015-03-19

申请号：US14487383

申请日：2014-09-16

Applicant: BASF SE

Inventor： Cathrin Alexandra WELKER-NIEUWOUDT ,  Cornelia Katharina Dobner ,  Holger Borchert ,  Ulrich Hammon ,  Josef Macht ,  Andrey Karpov ,  Christian Walsdorff

IPC: B01J23/888 ,  B01J37/04 ,  C07C51/25 ,  B01J35/04

CPC classification number: B01J23/8885 ,  B01J23/002 ,  B01J23/8877 ,  B01J23/94 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/008 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1004 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0223 ,  B01J37/0232 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C51/25 ,  C07C51/252 ,  Y02P20/584 ,  Y10T428/13 ,  Y10T428/249953 ,  Y10T428/273 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  C07C57/04

Abstract: What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q )  S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.

Abstract translation: 所描述的是通过α，bgr-不饱和醛的气相氧化制备α，β-不饱和羧酸的催化剂，其包括施加有活性组合物的成型载体，其中活性组合物覆盖率qq = Q（100-Q）S m为至多0.3mg / mm 2，其中Q为催化剂的活性组成含量，重量％，Sm为成形载体的特定几何表面积，单位为mm2 / mg。 还描述了制备催化剂的方法和通过在包含催化剂床的固定催化剂床上气相氧化α，β-不饱和醛来制备α，β-不饱和羧酸的方法。 具有不断高的丙烯醛转化率的催化剂减少了对COx的过氧化，并增加了丙烯酸形成的选择性。