Abstract:
The present invention relates to a method for producing polyurethane moulded articles, according to which method the following is mixed to form a reaction mixture: a) organic polyisocyanates; b) polyol, containing polyesterols; c) optionally propellants; d) chain-lengthening agents and/or cross-linking agents; e) amine catalyst (optionally including further catalysts); f) ionic fluid; g) carbodiimide of general formula Z-N=C=N-Z, where Z is an organic group and the nitrogen atom of the carbodiimide group -N=C=N- is bound either to a tertiary carbon atom or to a carbon atom of an aromatic system which, at the ring positions in the aromatic system that are adjacent to the C-N bond, bears an organic group bound via a secondary or tertiary carbon atom to the aromatic system; and optionally h) other auxiliary agents and/or additives. The mixture is put into a mould and allowed to react to form a polyurethane foam moulded article. The molar ratio of ionic fluid to amine catalyst is 0.1:1 to 3.0:1. The present invention further relates to polyurethane moulded articles that can be obtained according to such a method and to the use of these polyurethane moulded articles as shoe soles, particularly for safety shoes.
Abstract translation:生产聚氨酯模塑制品包括将有机多异氰酸酯与包含聚酯多元醇,任选的发泡剂,扩链剂和/或交联剂,胺催化剂,离子液体,碳二亚胺化合物(I)和任选的助剂和/或 添加剂以获得反应混合物,将反应混合物引入模具并使其反应以获得聚氨酯模制品。 离子液体和胺催化剂的摩尔比为0.1:1-3:1。 生产聚氨酯模制品包括将有机多异氰酸酯与包含聚酯多元醇,任选的发泡剂,扩链剂和/或交联剂的多元醇混合,胺催化剂,离子液体,式(ZN = C = NZ)的碳二亚胺化合物 I)和任选的助剂和/或添加剂以获得反应混合物,将反应混合物引入模具中并使其反应以获得聚氨酯模制品。 离子液体和胺催化剂的摩尔比为0.1:1-3:1。 Z:有机基团,其中-N = C = N-的氮原子与叔碳原子键合或与芳族体系的碳原子键合,芳香体系中与CN键相邻的环位置上带有有机基团 其通过仲碳原子或叔碳原子与芳族体系结合。 对于通过上述方法可获得的聚氨酯模制品,还包括独立权利要求。
Abstract:
The invention provides a thermoplastic polyurethane having at least one plasticizer, with at least one first plasticizer (i) being based on a glycerol, and at least one hydroxyl group of the glycerol being esterified with a monocarboxylic acid (ii) which contains 1, 2, 3, 4, 5 or 6 carbon atoms, more preferably 2, 3 or 4 carbon atoms and very preferably 2 carbon atoms. The invention further encompasses a process for preparing the thermoplastic polyurethane having the plasticizer (i), a method for coating products with this thermoplastic polyurethane, the use of the thermoplastic polyurethane, and the use of plasticizers based on glycerol for thermoplastic polyurethane.
Abstract:
A composite article has an increased peel strength and includes a first layer including a low surface energy polymer. The composite article also includes a poly(meth)acrylate layer, an epoxide layer, and a polyurethane elastomer layer. The poly(meth)acrylate layer is disposed on and in direct contact with the first layer. Moreover, the poly(meth)acrylate layer includes a poly(meth)acrylate that includes the reaction product of at least one (meth)acrylate that is polymerized in the presence of an organoborane initiator. The epoxide layer is disposed on and in direct contact with the poly(meth)acrylate layer. The polyurethane elastomer layer is disposed on and in direct contact with the epoxide layer. The composite article has a 90° peel strength of at least 50 pli measured using ASTM D6862.
Abstract:
The present invention is concerned with a process for producing polyurethane foam moldings having a density of 200 to 500 g/dm3, wherein (a) polyisocyanate prepolymer obtainable by reacting at least one organic polyisocyanate (a1), at least one first polyesterol (a2) and at least one polyetherol (a3) obtained from the alkoylation of a starter molecule with alkylenoxide comprising ethylene oxide wherein the polyetherol (a3) has a hydroxyl number in the range of 20 to 65 mg KOH/g, a number average molecular weight of 2000 to 6000, a functionality of 1.7 to 3.0 and a content of ethylenoxide units in the range of 13 to 30 % by weight based on the total weight of the polyetherol (a3) and wherein the content of the polyetherol (a3), based on the total weight of the organic polyisocyanate prepolymer (a), is in the range of 3 to 15 % by weight, is mixed with (b) at least one second polyesterol, (c) blowing agent and optionally (d) chain extender and/or crosslinker, (e) catalyst and (f) other auxiliaries and/or additives to form a reaction mixture, the latter is introduced into a mold and allowed to react to form a polyurethane foam molding. The present invention further concerns a polyurethane foam moldings obtained from a process according to the invention and the use of a polyurethane foam moldings according to the invention as shoe sole.
Abstract:
The invention relates to a method for producing polyurethane-coated line elements, in which (a) aliphatic polyisocyanate is mixed with (b) compounds containing at least two isocyanate-reactive hydrogen atoms, (c) catalyst, and (d) optionally, other auxiliary agents and/or additives, to obtain a first reaction mixture, and said reaction mixture is directly or indirectly applied to a tube and is allowed to finish reacting to obtain a polyurethane layer, wherein the compound containing at least two isocyanate-reactive hydrogen atoms contains a compound that is based on an alkoxylation product of an aromatic starter molecule. The invention further relates to line elements obtainable according to a method of this kind.